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Regulating electrode/electrolyte interfacial chemistry enables 4.6 V ultra-stable fast charging of commercial LiCoO2

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MOF-modified dendrite-free gel polymer electrolyte for zinc-ion batteries

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Molecularly engineered linear organic carbonates as practically viable nonflammable electrolytes for safe Li-ion batteries

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Insights into solvent molecule design for advanced electrolytes in lithium metal batteries

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A multifunctional zeolite film enables stable high-voltage operation of a LiCoO2 cathode

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Low-temperature lithium-ion batteries: challenges and progress of surface/interface modifications for advanced performance

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Advanced electrolyte systems with additives for high-cell-voltage and high-energy-density lithium batteries

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Nonflammable single-solvent electrolyte towards highly stable Li-rich Mn-based cathode materials

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Cosolvent occupied solvation tuned anti-oxidation therapy toward highly safe 4.7 V-class NCM811 batteries

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Recent advances in electrolyte molecular design for alkali metal batteries

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Molten salt electrolytes with enhanced Li+-transport kinetics for fast-cycling of high-temperature lithium metal batteries

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Energy Environ. Sci., 2025, 18, 1696
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A flame-retardant local high-concentration electrolyte for high-voltage lithium-ion batteries

Luo Zhang, Haodong Zhao, Donglai Xiao, Haibo Tian, Haibo Zhang, Xinghua Zhu and Dingyu Yang

Nanoscale, 2025, 17, 27482
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Phytate lithium as a multifunctional additive stabilizes LiCoO2 to 4.6 V

Fangchang Zhang, Ning Qin, Yingzhi Li, Hao Guo, Qingmeng Gan, Chun Zeng, Zhiqiang Li, Zhenyu Wang, Ruo Wang, Guiyu Liu, Shuai Gu, He Huang, Zelin Yang, Jun Wang, Yonghong Deng and Zhouguang Lu

Energy Environ. Sci., 2023, 16, 4345
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A functional electrolyte additive enabling robust interphases in high-voltage Li‖LiNi0.8Co0.1Mn0.1O2 batteries at elevated temperatures

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Solvation structure modulation via dipole–dipole interactions for high-rate lithium metal batteries exceeding 400 Wh kg−1

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Chem. Sci., 2025, 16, 13774
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Insights into the solvation chemistry in liquid electrolytes for lithium-based rechargeable batteries

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Concurrent electrode–electrolyte interfaces engineering via nano-Si3N4 additive for high-rate, high-voltage lithium metal batteries

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Energy Environ. Sci., 2025, 18, 3148
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Nonafluorobutyl ether enhancing the stability of fluorobenzene-based diluted high-concentration electrolytes in high-voltage lithium metal batteries

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Recent progress in nonflammable electrolytes and cell design for safe Li-ion batteries

Zi Ye, Jiayao Li and Zhejun Li

J. Mater. Chem. A, 2023, 11, 15576
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Stable electrode/electrolyte interfaces regulated by dual-salt and localized high-concentration strategies for high-voltage lithium metal batteries

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Electrolyte engineering promoting high-specific-energy lithium batteries in low-temperature environments

Qichao Wang, Junyi Gan, Yao Zhao, Chenyu Yang, Gongle Zhu, Nana Wang, Chaofeng Zhang, Jianping Yang and Tengfei Zhou

EES Batteries, 2025, 1, 672
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Bromide-based nonflammable electrolyte for safe and long-life sodium metal batteries

Changjian Zuo, Dejian Dong, Huwei Wang, Yue Sun and Yi-Chun Lu

Energy Environ. Sci., 2024, 17, 791
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Molecular tailoring of electrolyte solvents for high-performance lithium–metal batteries beyond temperature and voltage boundaries

Dejie Qu, Youlong Sun, Tao Liu, Guicun Li, Yuewei Yan, Tiantian Dong, Lang Huang, Gaojie Xu, Aobing Du, Lei Hu, Shanmu Dong, Bo Tang and Guanglei Cui

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Alloy-assisted stabilization of thin Li metal anodes in pouch-type cells

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Computational approaches to electrolyte design for advanced lithium-ion batteries

Shuang Wan, Shunshun Zhao, Weiting Ma and Shimou Chen

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Loosely coordinating diluted highly concentrated electrolyte toward −60 °C Li metal batteries

Han Zhang, Ziqi Zeng, Qiang Wu, Xinlan Wang, Mingsheng Qin, Sheng Lei, Shijie Cheng and Jia Xie

Journal of Energy Chemistry, 2024, 90, 380
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Advances in Anion Chemistry in the Electrolyte Design for Better Lithium Batteries

Hecong Xiao, Xiang Li and Yongzhu Fu

Nano-Micro Lett., 2025, 17
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Temperature-dependent interphase formation and Li+ transport in lithium metal batteries

Suting Weng, Xiao Zhang, Gaojing Yang, Simeng Zhang, Bingyun Ma, Qiuyan Liu, Yue Liu, Chengxin Peng, Huixin Chen, Hailong Yu, Xiulin Fan, Tao Cheng, Liquan Chen, Yejing Li, Zhaoxiang Wang and Xuefeng Wang

Nat Commun, 2023, 14
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Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi0.8Co0.1Mn0.1O2 Cathode

Jinxing Li, Yujuan Zhang, Xinping Chen, Lisi Lu, Hao Liu, Fei Gao, Shengli An, Xindong Wang and Xinping Qiu

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Origin of dendrite-free lithium deposition in concentrated electrolytes

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Stable Operation of Lithium Metal Batteries with Aggressive Cathode Chemistries at 4.9 V

Zhihong Piao, Hong‐Rui Ren, Gongxun Lu, Kai Jia, Junyang Tan, Xinru Wu, Zhaofeng Zhuang, Zhiyuan Han, Chuang Li, Runhua Gao, Xinyong Tao, Guangmin Zhou and Hui‐Ming Cheng

Angew Chem Int Ed, 2023, 62
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All-climate carbonate electrolyte with 2-sulfobenzoic anhydride additive leads the way to high-performance commercial pouch sodium-ion batteries

Zujia Lu, Shufeng Li, Zetao Huang, Kaiyuan Wang, Weizhen Fan, Jingwei Zhao, Fei Wang and Zhuo Zeng

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Recent Progress in Liquid Electrolytes for High‐Energy Lithium–Metal Batteries: From Molecular Engineering to Applications

Nan Li, Xue Han, Xinke Cui, Chaohe Xu, Chong Mao, Xiaobing Dai and Weijiang Xue

Adv Funct Materials, 2025, 35
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Wide Temperature Electrolytes for Lithium Batteries: Solvation Chemistry and Interfacial Reactions

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Small Methods, 2024, 8
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Strong Lewis-acid coordinated PEO electrolyte achieves 4.8 V-class all-solid-state batteries over 580 Wh kg−1

Hanwen An, Menglu Li, Qingsong Liu, Yajie Song, Jiaxuan Liu, Zhihang Yu, Xingjiang Liu, Biao Deng and Jiajun Wang

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Eco‐Friendly Tetrahydropyran Enables Weakly Solvating “4S” Electrolytes for Lithium‐Metal Batteries

Yaqi Liao, Mengyuan Zhou, Lixia Yuan, Kai Huang, Donghai Wang, Yan Han, Jintao Meng, Yun Zhang, Zhen Li and Yunhui Huang

Advanced Energy Materials, 2023, 13
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Combined Effect of Fluoride Enables the Stable Charging–Discharging Cycle of Carbonate-Based Li-Ion Pouch Cells at −30 °C

Hao Huang, Yiyang Zhao, Jingang Zheng, Weichen Han, Hongxu Zhou, Hongyang Li, Hongquan Chai, Lixiang Li, Hongwei Zhao, Han Zhang, Baigang An and Chengguo Sun

ACS Materials Lett., 2025, 7, 1321
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The role of flame-retardant electrolytes in lithium-ion batteries: Custom design for improved battery-level safety

Yaxuan Fu, Xiaozhi Jiang, Chenyang Shi, Long Chen, Zhendong Yang, Mengran Wang, Bo Hong, Faping Zhong and Yanqing Lai

Chinese Chemical Letters, 2026, 37, 110972
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Intermolecular Interactions Mediated Nonflammable Electrolyte for High‐Voltage Lithium Metal Batteries in Wide Temperature

Yeguo Zou, Gang Liu, Yuqi Wang, Qian Li, Zheng Ma, Dongming Yin, Yao Liang, Zhen Cao, Luigi Cavallo, Hun Kim, Limin Wang, Husam N. Alshareef, Yang‐Kook Sun and Jun Ming

Advanced Energy Materials, 2023, 13
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Regulating Ni 3d‐O 2p Orbital Interaction with Position‐Isomer Organic Lithiation Additive for High‐Voltage LiNi0.8Co0.1Mn0.1O2 Cathode

Xinyu Zhang, Xianshu Wang, Yuanpeng Cao, Chao Zhao, Wenhui Tu, Yun Zhao, Peng Dong, Yingjie Zhang, Zhongyuan Luo, Ding Wang, Baohua Li, Zhenyu Guo, Maria‐Magdalena Titirici and Jianguo Duan

Advanced Energy Materials, 2026, 16
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Electrolyte Design Principles for Fast Charging in High-Voltage Lithium Batteries

Yanchen Piao, Yusheng Ye, Yongxin Zhang, Feng Wu, Jingmei Lyu and Renjie Chen

ACS Energy Lett., 2026, 11, 2636
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Tuning the FEC‐Related Electrolyte Solvation Structures in Ether Solvents Enables High‐Performance Lithium Metal Anode

Yaru Zhang, Fan Li, Yu Cao, Min Yang, Xinpeng Han, Yi Ji, Kuizhi Chen, Lixin Liang, Jie Sun and Guangjin Hou

Adv Funct Materials, 2024, 34
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Highly Efficient Organosulfur and Lithium‐Metal Hosts Enabled by C@Fe3N Sponge

Jiarui He, Amruth Bhargav, Hyunki Sul and Arumugam Manthiram

Angewandte Chemie, 2023, 135
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Wide-temperature and high-voltage Li||LiCoO2 cells enabled by a nonflammable partially-fluorinated electrolyte with fine-tuning solvation structure

Cheng Chen, Shu Zhang, Caili Xu, Jian Yang, Youzuo Hu, Lingchao Yu, Pengyu Li, Bing Qu and Mengqiang Wu

Journal of Energy Chemistry, 2025, 101, 608
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Nonflammable F-rich high-entropy electrolytes with manipulated solvent coordination for intrinsically safe and high-energy lithium metal batteries

Zhiwei Ni, Yuan Li, Zhengran Wang, Suyun Liu, Junjie Liu, Chen Yang, Huizi Zhang, Juan Geng, Chenghui Zhang, Shenglin Xiong, Baojuan Xi and Jinkui Feng

Energy Storage Materials, 2026, 84, 104885
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A Weakly Solvating Ether Electrolyte Enables Fast-Charging and Wide-Temperature Lithium-Ion Pouch Cells

Yaqi Liao, Wenjie Lin, Yangqian Zhang, Jiayi Yang, Zhen Li, Yang Ren, Donghai Wang, Yunhui Huang and Lixia Yuan

ACS Nano, 2024, 18, 20762
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Diethyl Sulfide as a Multifunctional Electrolyte Additive for Enhancing Electrochemical Performance of Lithium Metal Batteries

Wenjie Zhang, Xiaosong Xiong, Run Xu, Guangyao Xiang, Tao Wang, Xu Liu, Yong Wang, Lili Liu and Yuping Wu

Adv Funct Materials, 2026
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Highly Oxidation‐Resistant Electrolyte for 4.7 V Sodium Metal Batteries Enabled by Anion/Cation Solvation Engineering

Daxiong Wu, Chunlei Zhu, Mingguang Wu, Huaping Wang, Junda Huang, Dongliang Tang and Jianmin Ma

Angewandte Chemie, 2022, 134
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Amphiphilic Polymer Electrolyte Blocking Lattice Oxygen Evolution from High‐Voltage Nickel‐rich Cathodes for Ultra‐Thermal Stabile Batteries

Jialiang Chen, Yan Lin, Qiang Li, Hao Ren, Linchen Zhang, Yuanyuan Sun, Siyu Zhang, Xinchao Shang, Weidong Zhou, Mingbo Wu and Zhongtao Li

Angew Chem Int Ed, 2024, 63
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Stable Operation of Lithium Metal Batteries with Aggressive Cathode Chemistries at 4.9 V

Zhihong Piao, Hong‐Rui Ren, Gongxun Lu, Kai Jia, Junyang Tan, Xinru Wu, Zhaofeng Zhuang, Zhiyuan Han, Chuang Li, Runhua Gao, Xinyong Tao, Guangmin Zhou and Hui‐Ming Cheng

Angewandte Chemie, 2023, 135
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Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode

Jiale Zheng, Mei Chen, Huadong Yuan, Jianmin Luo, Yao Wang, Jianwei Nai, Xinyong Tao and Yujing Liu

Chinese Chemical Letters, 2024, 35, 108812
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Recent Progress on Natural Clay Minerals for Lithium‐Sulfur Batteries

Liu Yang, Xin Yang, Feng Xia, Yifei Gong, Faxue Li, Jianyong Yu, Tingting Gao and Yiju Li

Chemistry An Asian Journal, 2023, 18
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Interfacial fluoride engineering enabled robust LiF-rich solid electrolyte interphase to reduce active lithium loss in rechargeable lithium battery

Tianqi Jia, Geng Zhong, Sirong Lu, Xiaolong Ren, Yao Lv, Nanrui Li, Rui Yin, Guohuang Kang, Kangning Cai, Feiyu Kang and Yidan Cao

Chemical Engineering Journal, 2023, 454, 140397
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Asymmetrically Fluorinated Alkoxysilane Single‐Solvent Electrolytes Enable High‐Voltage and Long‐Cycling Lithium Metal Batteries

Wei Sun, Qian Yu, Haoran Tian, Qian Qiu, Shen Qiu, Jose Fernando Florez Gomez, Irfan Ullah, Longqing Huang, Xianyong Wu, Lan Xia and Xinping Ai

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Designing bifunctional cosolvent-based electrolyte to optimize anion-cation associations for a stable electrode-electrolyte interphase in high-nickel li-metal batteries

Jae Bin Park, Taewoong Lee, Seongwook Chae, Ah Reum Choi, Yewon Park, Seonhee Jo, Pilgun Oh, Sung Hyun Kwon, Ji-Hoon Baik, Byung Gon Kim and Jin Hong Lee

Chemical Engineering Journal, 2025, 506, 160012
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In Situ Fabricated Non‐Flammable Quasi‐Solid Electrolytes for Li‐Metal Batteries

Jiwei Zhao, Mengjie Li, Hai Su, Yuansheng Liu, Panxing Bai, Hang Liu, Lanhua Ma, Weiyang Li, Jie Sun and Yunhua Xu

Small Methods, 2023, 7
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Weakly Solvating Electrolytes for Lithium and Post‐Lithium Rechargeable Batteries: Progress and Outlook

Xue Li, Fei Luo, Naigen Zhou, Henry Adenusi, Shan Fang, Fanglin Wu and Stefano Passerini

Advanced Energy Materials, 2025, 15
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Structure Regulation of Electric Double Layer via Hydrogen Bonding Effect to Realize High‐Stability Lithium‐Metal Batteries

Sheng Liu, Chaozhu Shu, Yu Yan, Dayue Du, Longfei Ren, Ting Zeng, Xiaojuan Wen, Haoyang Xu, Xinxiang Wang, Guilei Tian and Ying Zeng

Energy & Environ Materials, 2024, 7
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Electrolytes in Lithium-Ion Batteries: Advancements in the Era of Twenties (2020's)

Sana Kainat, Junaid Anwer, Abdul Hamid, Nafisa Gull and Shahzad Maqsood Khan

Materials Chemistry and Physics, 2024, 313, 128796
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Mechanically and Thermally Stable Cathode Electrolyte Interphase Enables High‐temperature, High‐voltage Li||LiCoO2 Batteries

Daxiong Wu, Chunlei Zhu, Huaping Wang, Junda Huang, Gaoxue Jiang, Yulu Yang, Gaojing Yang, Dongliang Tang and Jianmin Ma

Angewandte Chemie, 2024, 136
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The role of active passivated interface in poly (ethylene oxide) electrolyte for 4.2 V solid-state lithium metal batteries

Zhao Zhang, Jianli Wang, Hangjun Ying, Shunlong Zhang, Pengfei Huang, Zhihao Zhang, Haijiao Xie, Gaorong Han and Wei-Qiang Han

Chemical Engineering Journal, 2023, 451, 138680
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A persistent-range hydrogen-bonded gel polymer electrolyte enabling wide-temperature and recyclable lithium metal batteries

Zhangqin Shi, Mingming Fang, Jing Zhang, Qinghui Zeng, Wei Hao, Yongteng Dong, Zhu Liu, Xubing Dong, Xinyang Yue and Zheng Liang

Sci. Adv., 2026, 12
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Interphase Engineering for Stabilizing Ni‐Rich Cathode in Lithium‐Ion Batteries by a Nucleophilic Reaction‐Based Additive

Wei‐Chen Zheng, Zheng Huang, Chen‐Guang Shi, Yaping Deng, Zi‐Hao Wen, Zhen Li, Hui Chen, Zhongwei Chen, Ling Huang and Shi‐Gang Sun

ChemSusChem, 2023, 16
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Side Reactions/Changes in Lithium‐Ion Batteries: Mechanisms and Strategies for Creating Safer and Better Batteries

Hao Du, Yadong Wang, Yuqiong Kang, Yun Zhao, Yao Tian, Xianshu Wang, Yihong Tan, Zheng Liang, John Wozny, Tao Li, Dongsheng Ren, Li Wang, Xiangming He, Peitao Xiao, Eryang Mao, Naser Tavajohi, Feiyu Kang and Baohua Li

Advanced Materials, 2024, 36
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Jellyfish-inspired gel polymer electrolyte with dual-interfaces stability for 4.7 V high-voltage lithium-ion batteries

Jiali Huang, Shaopan Qin, Yanli Qi and Yurong Ren

Chemical Engineering Journal, 2025, 525, 170152
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Bioinspired interfacial nanofluidic layer enabling high-rate and dendrite-free lithium metal negative electrodes

Chunlei Song, Lyuming Pan, Junxiu Wu, Lu Chen, He Zhao, Hongji Pan, Shumin Wu, Liu Yang, Yanxin Jiang, Yiju Li, Jun Lu and Tianshou Zhao

Nat Commun, 2025, 16
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Cathode Electrolyte Interface Engineering by Gradient Fluorination for High‐Performance Lithium Rich Cathode

Lu Di, Chen Yufang, Sun Weiwei, Xie Wei, Yi Shuaiyu, Luo Shiqiang, Zuo Lanlan, Zhao Yanshuang, Yang Tianyan, Xiao Peitao and Zheng Chunman

Advanced Energy Materials, 2023, 13
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A review on localized high concentration electrolytes for advanced Li metal batteries

Feng Hai, Yuyu Ban, Zhenxin Huang, Weichen Xue, Yunxiao Yang, Wentao Yan, Weibo Hua, Mingtao Li, Wei Tang and Shanqing Zhang

Energy Storage Materials, 2025, 81, 104534
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A Novel Potassium Salt Regulated Solvation Chemistry Enabling Excellent Li‐Anode Protection in Carbonate Electrolytes

Shenghang Zhang, Xiangchun Zhuang, Xiaofan Du, Xiaohu Zhang, Jiedong Li, Gaojie Xu, Zhongqin Ren, Zili Cui, Lang Huang, Shitao Wang, Fun Sun, Lixin Qiao, Shanmu Dong and Guanglei Cui

Advanced Materials, 2023, 35
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Electrically Coupled Electrolyte Engineering Enables High Interfacial Stability for High‐Voltage Sodium‐Ion Batteries

Jialin Lin, Honghui Peng, Pei Huang, Tuoya Naren, Chaoping Liang, Guichao Kuang, Libao Chen, Chunxiao Zhang and Weifeng Wei

Adv Funct Materials, 2023, 33
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Hydrogen Bond Boosted Ferroelectric Polarization Enables High Rate Capability Lithium Metal Batteries

Wenran Wang, Li Ma, Baolei Xu, Hai Zhu, Chunxiao Zhang, Libao Chen and Weifeng Wei

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Amphiphilic Polymer Electrolyte Blocking Lattice Oxygen Evolution from High‐Voltage Nickel‐rich Cathodes for Ultra‐Thermal Stabile Batteries

Jialiang Chen, Yan Lin, Qiang Li, Hao Ren, Linchen Zhang, Yuanyuan Sun, Siyu Zhang, Xinchao Shang, Weidong Zhou, Mingbo Wu and Zhongtao Li

Angewandte Chemie, 2024, 136
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Evolution effect of -CF2- group amount in hydrofluoroether on the solvation structure and high voltage cycle performance of Ether-based localized High-concentration electrolytes

Pan Luo, Jun Yang, Ying Zhang, Li Liao, Qiu Chen, Bo Yu, Bingshu Guo, Mingshan Wang, Junchen Chen, Zhiyuan Ma, Yun Huang, Jiangtao Liu and Xing Li

Chemical Engineering Journal, 2023, 469, 144012
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Dual-salt-additive reinforced commercial carbonate-based electrolytes for 4.7 V high-voltage practical Li-ion and Li-metal batteries

Wei Sun, Qian Yu, Shuai Wang, Wenjun Zhang, Zhongxue Chen, He Miao, Jinliang Yuan and Lan Xia

Energy Storage Materials, 2025, 82, 104627
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Additive-induced interfacial chemistry: The key to next-generation lithium metal batteries

Lei Sun, Gongxun Lu, Qingyue Han, Hongyan Li, Ouwei Sheng and Chengbin Jin

Energy Storage Materials, 2025, 82, 104650
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Advanced Poly (Ether Ether Ketone) Separator for Lithium Metal Battery

Xingyan Zeng, Yi Chen, Hui Nie, Yufei Yang, Jie Chen, Huijie Pei, Xuyang Wang, Yanchao Yang, Jinhui Pang, Xingping Zhou, Guibin Wang and Xiaolin Xie

Small, 2025, 21
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Dual‐Salt Electrolyte Additive Enables High Moisture Tolerance and Favorable Electric Double Layer for Lithium Metal Battery

Zuxin Wen, Wenqiang Fang, Fenglin Wang, Hong Kang, Shuoqing Zhao, Shaojun Guo and Gen Chen

Angew Chem Int Ed, 2024, 63
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Molecular Engineering of Electrolyte Solvents for Lithium Metal Batteries: Strategies, Challenges, and Prospects

Xiao Zhu and Xiaoli Dong

Batteries & Supercaps, 2025, 8
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Perspectives on the Practicability of Li‐Rich NMC Layered Oxide Cathodes

Biao Li, Kun Zhang, Yali Yang, Yuxuan Zuo, Xiang Li and Dingguo Xia

Advanced Materials, 2024, 36
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Synergistic Additives Enabling Stable Cycling of Ether Electrolyte in 4.4 V Ni‐Rich/Li Metal Batteries

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Electrolyte Engineering via Nucleophilic Anion Design: Lithium Pentafluoropropionate Enabling Dendrite-Free High-Performance Lithium Metal Batteries

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Unveiling decaying mechanism of non-flammable all-fluorinated carbonate electrolytes in lithium metal batteries with 4.6-V LiCoO2 cathodes at elevated temperatures

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Multifunctional Silicon‐Based Composite Electrolyte Additive Enhances the Stability of the Lithium Metal Anode/Electrolyte Interface

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