β-MnO2 nanoparticles as heterogenous catalysts for aerobic oxidative transformation of alcohols to carbonyl compounds, nitriles, and amides

Keigo Kamata, Nanami Kinoshita, Maki Koutani, Ryusei Aono, Eri Hayashi and Michikazu Hara

Catal. Sci. Technol., 2022, 12, 6219
DOI: 10.1039/D2CY01476A

Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water

Kang-kang Sun, Jia-lin Sun, Guo-Ping Lu and Chun Cai

Green Chem., 2019, 21, 4334
DOI: 10.1039/C9GC01893J

The ammoxidation of alcohols over heterogeneous catalysts for the green synthesis of nitriles

Zhijie Qi, Chaoning Hu, Youwei Zhong, Chun Cai and Guo-Ping Lu

Org. Chem. Front., 2021, 8, 3137
DOI: 10.1039/D1QO00275A

Copper catalyzed cyanation through CC bond cleavage of gem-aryl dibromide followed by second cyanation of iodoarene by a released CN unit

Pintu Maity, Debasish Kundu, Tubai Ghosh and Brindaban C. Ranu

Org. Chem. Front., 2018, 5, 1586
DOI: 10.1039/C8QO00108A

Synergistic catalysis: cobalt-catalyzed cascade reaction for the oxidative cleavage of olefins to access esters

Xiangzhu Yu, Zhengjia Zhao, Shangzhi Tan, Lina Zhu, Weiru Fu, Yue An and Lianyue Wang

Chem. Commun., 2024, 60, 8063
DOI: 10.1039/D1CC01596F

Stable and reusable nanoscale Fe2O3-catalyzed aerobic oxidation process for the selective synthesis of nitriles and primary amides

Kathiravan Murugesan, Thirusangumurugan Senthamarai, Manzar Sohail, Muhammad Sharif, Narayana V. Kalevaru and Rajenahally V. Jagadeesh

Green Chem., 2018, 20, 266
DOI: 10.1039/C7GC02627G

Recent advances in metal-free heteroatom-doped carbon heterogonous catalysts

Yalda Rangraz and Majid M. Heravi

RSC Adv., 2021, 11, 23725
DOI: 10.1039/D1RA03446D

Selectivity-tunable amine aerobic oxidation catalysed by metal-free N,O-doped carbons

Yingguang Li, Sensen Shang, Lianyue Wang, Ying Lv, Jingyang Niu and Shuang Gao

Chem. Commun., 2019, 55, 12251
DOI: 10.1039/C9CC06793K

Thermo-/photo-catalysts for aerobic oxidative cyanation of diverse oxygen-containing feedstocks

Jie He, Peng Zhou, Shiying Zhang, Jason Chun-Ho Lam, Yuhe Liao and Zehui Zhang

Green Chem., 2024, 26, 1831
DOI: 10.1039/D3GC04548J

Low-temperature ammoxidation of aldehydes enabled by metal-free porous N-doped carbon nanosheets via nitrogen species engineering

Zhaoxi Cai, Long Tao, Kongqian Liang, Jinpeng Liang, Sitong Chen, Na Wang, Zhiwei Jiang and Jinliang Song

Journal of Catalysis, 2026, 453, 116511
DOI: 10.1016/j.jcat.2025.116511

Carbonization of camphor sulfonic acid and melamine to N,S-co-doped carbon for sulfamethoxazole degradation via persulfate activation: Nonradical dominant pathway

Wei Sun, Kangfeng Pang, Feng Ye, Mengjie Pu, Chengzhi Zhou, Haiming Huang, Qichun Zhang and Junfeng Niu

Separation and Purification Technology, 2021, 279, 119723
DOI: 10.1016/j.seppur.2021.119723

Carbon Materials as Catalytic Tools for Oxidative Dehydrogenations and Couplings in Liquid Phase

Anna Lenarda, Tom Wirtanen and Juho Helaja

Synthesis, 2023, 55, 45
DOI: 10.1055/a-1931-0749

Single-Atom Catalysts across the Periodic Table

Selina K. Kaiser, Zupeng Chen, Dario Faust Akl, Sharon Mitchell and Javier Pérez-Ramírez

Chem. Rev., 2020, 120, 11703
DOI: 10.1021/acs.chemrev.0c00576

Nanoarchitectonics of Sulfonated Boron Nitride for Catalytic Synthesis of Aromatic Nitriles under Mild Conditions

Priyanka Choudhary, Shivangi Singh Chauhan, Devendra Sharma, Sahil Kumar and Venkata Krishnan

Chemical Engineering Journal, 2023, 475, 146055
DOI: 10.1016/j.cej.2023.146055

Synthesis of Functionalized Nitriles by Microwave‐Promoted Fragmentations of Cyclic Iminyl Radicals

Mary M. Jackman, Siyeon Im, Seth R. Bohman, Concordia C. L. Lo, Amanda L. Garrity and Steven L. Castle

Chemistry A European J, 2018, 24, 594
DOI: 10.1002/chem.201705728

A Transition‐Metal‐Free One‐Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2

Ying Jiang, Bing Sun, Wan‐Yin Fang and Hua‐Li Qin

Eur J Org Chem, 2019, 2019, 3190
DOI: 10.1002/ejoc.201900478

Recent progress of carbon-based metal-free materials in thermal-driven catalysis

Shuchang Wu, Linhui Yu, Guodong Wen, Zailai Xie and Yangming Lin

Journal of Energy Chemistry, 2021, 58, 318
DOI: 10.1016/j.jechem.2020.10.011

Redox Induced Fluorescence On–Off Switching Based on Nitrogen Enriched Graphene Quantum Dots for Formaldehyde Detection and Bioimaging

Hui-Jun Li, Xiong Sun, FengFeng Xue, Nanquan Ou, Bo-Wen Sun, Dong-Jin Qian, Meng Chen, Ding Wang, JunHe Yang and XianYing Wang

ACS Sustainable Chem. Eng., 2018, 6, 1708
DOI: 10.1021/acssuschemeng.7b02941

Highly dispersed Co species in N-doped carbon enhanced the aldehydes ammoxidation reaction activity

Liuming Pan, Wenqian Fu, Lei Zhang, Siming Wang and Tiandi Tang

Molecular Catalysis, 2022, 518, 112087
DOI: 10.1016/j.mcat.2021.112087

Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles

Kangkang Sun, Hongbin Shan, Helfried Neumann, Guo-Ping Lu and Matthias Beller

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-29074-1

Direct Reductive Amination from Ketones, Aldehydes to Synthesize Amines Using N, S-Dual Doped Co/C Catalyst

Hongwei Zhang, Ying Liu, Ling Zhang, Xiong Wang, He Sun, Chengyu Liu, Jinxing Ye and Ruihua Cheng

Catal Lett, 2022, 152, 3586
DOI: 10.1007/s10562-021-03911-2

Fe-based N-doped dendritic catalysts for catalytic ammoxidation of aromatic aldehydes to aromatic nitriles

Hong Zhao, Xun Sun, Dan Xu, Qian Zhu, Yangyang Zhu and Zhengping Dong

Journal of Colloid and Interface Science, 2020, 565, 177
DOI: 10.1016/j.jcis.2019.12.133

Heteroatom‐Enhanced Metal‐Free Catalytic Performance of Carbocatalysts for Organic Transformations

Sen S. Shang and Shuang Gao

ChemCatChem, 2019, 11, 3730
DOI: 10.1002/cctc.201900336

Identification of an Active NiCu Catalyst for Nitrile Synthesis from Alcohol

Yunzhu Wang, Shinya Furukawa and Ning Yan

ACS Catal., 2019, 9, 6681
DOI: 10.1021/acscatal.9b00043

Earth-Abundant Bimetallic Nanoparticle Catalysts for Aerobic Ammoxidation of Alcohols to Nitriles

Tomohiro Yasukawa, Xi Yang and Shu Kobayashi

J. Org. Chem., 2020, 85, 7543
DOI: 10.1021/acs.joc.0c00670

N and P co-doped graphene-like carbon nanosheet as metal-free catalyst for selective oxidation of methacrolein to methacrylic acid: High methacrylic acid selectivity

Xiangjie Zeng, Yandong Chong, Miao Qi, Chenlin Zhang, Lilong Zhou, Zhengjie Li, Lidong Zhao, Haoyu Yao and Jimmy Yun

Applied Surface Science, 2024, 644, 158759
DOI: 10.1016/j.apsusc.2023.158759

Zinc Oxide/Graphene Oxide as a Robust Active Catalyst for Direct Oxidative Synthesis of Nitriles from Alcohols in Water

Iraj Sarvi and Ehsan Zahedi

Catal Lett, 2022, 152, 1895
DOI: 10.1007/s10562-021-03779-2

Pyridinic/pyrrolic-N sites in nitrogen-doped carbon boosting intermolecular hydrogen transfer in MPV-type reaction for atom-economical synthesis of amides

Lei Zhang, Huimeng He, Yulin Wang, Yongqi Sun, Yupei Zhao, Wenqian Fu and Tiandi Tang

Journal of Catalysis, 2026, 454, 116539
DOI: 10.1016/j.jcat.2025.116539

Nitrogen‐Doped Carbon as a Highly Active Metal‐Free Catalyst for the Selective Oxidative Dehydrogenation of N‐Heterocycles

Xun Li, Ziliang Yuan, Yi Liu, Hanmin Yang, Jiabao Nie, Guanghui Wang and Bing Liu

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202200753

Aerobic oxidative cleavage of 1,2-diols catalyzed by atomic-scale cobalt-based heterogeneous catalyst

Huihui Luo, Lianyue Wang, Sensen Shang, Jingyang Niu and Shuang Gao

Commun Chem, 2019, 2
DOI: 10.1038/s42004-019-0116-5

Organonitrogen Chemicals from Oxygen-Containing Feedstock over Heterogeneous Catalysts

Yunzhu Wang, Shinya Furukawa, Xinpu Fu and Ning Yan

ACS Catal., 2020, 10, 311
DOI: 10.1021/acscatal.9b03744

Nitrogen-Doped Carbon-Modified Cobalt-Nanoparticle-Catalyzed Oxidative Cleavage of Lignin β-O-4 Model Compounds under Mild Conditions

Huihui Luo, Lianyue Wang, Guosong Li, Sensen Shang, Ying Lv, Jingyang Niu and Shuang Gao

ACS Sustainable Chem. Eng., 2018, 6, 14188
DOI: 10.1021/acssuschemeng.8b02802

Metal-organic framework-derived nanomaterials: Promising green catalysts for industrially relevant oxidation and hydrogenation

Siqi Liu, Zhixiang Cheng, Dandan Jia, Hongyi Gao, Tian Li, Juan Chen, Jitti Kasemchainan, Guoqing An, Ge Wang and Xingtian Shu

Nano Today, 2023, 52, 101960
DOI: 10.1016/j.nantod.2023.101960

Well Dispersed Small Lanthanum Oxide Nanoparticles on BAPDA Modified Graphene Oxide: A Robust Catalyst for the Direct Oxidative Synthesis of Nitriles from Alcohols and Aldehydes in Water

H. Hassani and E. Sabouri

Russ J Org Chem, 2023, 59, S56
DOI: 10.1134/S1070428023130055

Solvent-Free Ammoxidation of Biomass Alcohols to Nitriles over the Nitrogen-Doped Carbon-Supported Iron Catalyst

Qingqing Pu, Yongqiang Yao, Longfei Wang, Dan Fan, Yuqi Yao, Yong Guo, Zhenyu Sun, Yongsheng Li and Zhengang Ke

ACS Sustainable Chem. Eng., 2025, 13, 12188
DOI: 10.1021/acssuschemeng.5c04497

Defect‐Rich Core‐Shell Carbon Derived from Ionic Liquid for Direct Synthesis of Imines

Peipei He, Ying Lv, Sensen Shang, Bo Chen, Hongliang Liang, Jingyang Niu and Wen Dai

ChemistrySelect, 2021, 6, 5961
DOI: 10.1002/slct.202100763

Nitrogen-doped mesoporous carbon as metal-free catalysts for the aerobic oxidation of alcohols

Xiangzhu Yu, Ling Ni, Enshuang Bai, Meng Miao, Xinyue Tang and Lianyue Wang

Molecular Catalysis, 2024, 569, 114526
DOI: 10.1016/j.mcat.2024.114526

Pd1.5H2@PdO Nanoparticles Nanoconfined in Nitrogen‐Doped Carbon for the Aerobic Oxidation Benzaldehydes to Arylnitriles

Anzheng Zhang, Juan Meng, Yihui Li, Chunmin Xu, Youan Chen, Long Cheng and Hengfei Qin

Advanced Sustainable Systems, 2026, 10
DOI: 10.1002/adsu.70435

Tridoped Mesoporous Carbon as a Metal-Free Catalyst for Ammoxidation of (Hetero)Aromatic Alcohols to Nitriles

Weitao Wang, Liqiong Ma, Huan Wang, Xulu Jiang, Zhen-Hong He, Kuan Wang, Yang Yang, Lu Li and Zhao-Tie Liu

ACS Appl. Nano Mater., 2023, 6, 15193
DOI: 10.1021/acsanm.3c02877

Heterogeneous M-N-C Catalysts for Aerobic Oxidation Reactions: Lessons from Oxygen Reduction Electrocatalysts

Jason S. Bates, Mathew R. Johnson, Fatemeh Khamespanah, Thatcher W. Root and Shannon S. Stahl

Chem. Rev., 2023, 123, 6233
DOI: 10.1021/acs.chemrev.2c00424

State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols

Pengfei Wu, Xiaomin Zhang, Jifeng Pang, Guoqiang Wei, Mingyuan Zheng and Tao Zhang

ACS Catal., 2024, 14, 14436
DOI: 10.1021/acscatal.4c04460

Oxidative degradation of pharmaceutical losartan potassium with N-doped hierarchical porous carbon and peroxymonosulfate

Júlia Resende de Andrade, Melissa Gurgel Adeodato Vieira, Meuris Gurgel Carlos da Silva and Shaobin Wang

Chemical Engineering Journal, 2020, 382, 122971
DOI: 10.1016/j.cej.2019.122971

Practical CuCl/DABCO/4-HO-TEMPO-catalyzed oxidative synthesis of nitriles from alcohols with air as oxidant

Yongke Hu, Lei Chen and Bindong Li

Chinese Chemical Letters, 2018, 29, 464
DOI: 10.1016/j.cclet.2017.10.036

Nitrogen-Doped Carbon Quantum Dots for Biosensing Applications: The Effect of the Thermal Treatments on Electrochemical and Optical Properties

Francesco Ghezzi, Riccardo Donnini, Antonio Sansonetti, Umberto Giovanella, Barbara La Ferla and Barbara Vercelli

Molecules, 2022, 28, 72
DOI: 10.3390/molecules28010072

Metal‐ and Additive‐Free Aerobic Dehydrogenation of N‐Heterocycles and Hydrocarbons by N‐Doped Carbon

Sensen Shang, Yingguang Li, Ying Lv and Wen Dai

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200126

Heterogeneous Metal‐Free Nitrogen and Phosphorus Co‐Doped Carbons for Acids Synthesis from Tertiary Alcohol via Oxidative Cleavage of C─C Bonds

Nian Liu, Huihui Luo, Ge Xu and Wen Dai

ChemCatChem, 2026, 18
DOI: 10.1002/cctc.202501175