Organo-mediator enabled electrochemical transformations

Weimei Zeng, Yanwei Wang, Chengyi Peng and Youai Qiu

Chem. Soc. Rev., 2025, 54, 4468
DOI: 10.1039/D4CS01142B

Deep oxidization of glucose driven by 4-acetamido-TEMPO for a glucose fuel cell at room temperature

Gangyong Li, Yuchao Wang, Feng Yu, Yongpeng Lei and Zongqian Hu

Chem. Commun., 2021, 57, 4051
DOI: 10.1039/D0CC08381J

Robust non-covalent and covalent anchored N,N,N′,N’-tetramethyl-p-phenylenediamine derivative on electrode surface via spontaneous physical immobilization and in situ generated aryldiazonium ion electro-grafting: implication for on-surface chemistry and electro-catalytic determinations

Mahsa Taleghan Ghafari, Fahimeh Varmaghani, Babak Karimi and Vahid Khakyzadeh

Analyst, 2020, 145, 596
DOI: 10.1039/C9AN01628G

Vertically ordered silica mesochannel films: electrochemistry and analytical applications

Fei Yan, Xingyu Lin and Bin Su

Analyst, 2016, 141, 3482
DOI: 10.1039/C6AN00146G

Organic chemistry at anodes and photoanodes

Lacey M. Reid, Tengfei Li, Yang Cao and Curtis P. Berlinguette

Sustainable Energy Fuels, 2018, 2, 1905
DOI: 10.1039/C8SE00175H

Heterogeneous cobalt catalysts for selective oxygenation of alcohols to aldehydes, esters and nitriles

Fei Mao, Zhengliang Qi, Haipeng Fan, Dejun Sui, Rizhi Chen and Jun Huang

RSC Adv., 2017, 7, 1498
DOI: 10.1039/C6RA27073E

Comparison of homogeneous and heterogeneous catalysts in dye-sensitised photoelectrochemical cells for alcohol oxidation coupled to dihydrogen formation

D. F. Bruggeman, S. Mathew, R. J. Detz and J. N. H. Reek

Sustainable Energy Fuels, 2021, 5, 5707
DOI: 10.1039/D1SE01275D

Catalytic oxidation of carbohydrates into organic acids and furan chemicals

Zehui Zhang and George W. Huber

Chem. Soc. Rev., 2018, 47, 1351
DOI: 10.1039/C7CS00213K

Sol–gel process immobilization of TEMPO catalysts on multi-walled carbon nanotubes for electrocatalytic alcohol oxidation

Hichem Ichou, Garen Suna, Stéphane Diring, Clément Maheu and Fabrice Odobel

Chem. Commun., 2025, 61, 5325
DOI: 10.1039/D5CC00330J

Selective electrosynthesis of aldehydes at industrially relevant current densities via tandem electrochemical–chemical catalysis

Ting Lin, Menglu Cai, Huijie Chen and Yiming Mo

Green Chem., 2024, 26, 11290
DOI: 10.1039/D4GC04536J

An efficient clean methodology for the C–S coupling to aryl thioethers and S–S homocoupling to aromatic disulfides catalyzed over a Ce(iv)-leucine complex immobilized on mesoporous MCM-41

Hojat Veisi, Taibeh Tamoradi and Bikash Karmakar

New J. Chem., 2019, 43, 10343
DOI: 10.1039/C9NJ02270H

Banana peel derived nitrogen-doped porous carbon with enhanced electrocatalytic activity for complete oxidation of methanol under room temperature

Cuixing Xu, Gangyong Li, Yongyue Ning, Ming Zhou and Zongqian Hu

Sensors and Actuators B: Chemical, 2021, 344, 130112
DOI: 10.1016/j.snb.2021.130112

Waste‐free oxidation of alcohols at the surface of catalytic electrodes: What is required for industrial uptake?

Rosaria Ciriminna, Mina Ghahremani, Babak Karimi and Mario Pagliaro

Electrochemical Science Adv, 2022, 2
DOI: 10.1002/elsa.202100124

4‐OH‐TEMPO/TCQ/TBN/HCl: A Metal‐Free Catalytic System for Aerobic Oxidation of Alcohols under Mild Conditions

Yanli Dong, Xiaomei Zhao and Renhua Liu

Chin. J. Chem., 2015, 33, 1019
DOI: 10.1002/cjoc.201500357

Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene–TEMPO Conjugate

Amit Das and Shannon S. Stahl

Angew Chem Int Ed, 2017, 56, 8892
DOI: 10.1002/anie.201704921

Structurally MMO Active Site‐Like Ruthenium Complex for Catalytic Oxidation of Olefins to Aldehydes

Fei Xie, Sheng Zhang, Xiaoqiang Yu, Xiujuan Feng and Ming Bao

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500201

Lignin-derived platform molecules through TEMPO catalytic oxidation strategies

Samira Gharehkhani, Yiqian Zhang and Pedram Fatehi

Progress in Energy and Combustion Science, 2019, 72, 59
DOI: 10.1016/j.pecs.2019.01.002

Silver Nanoparticles Densely Grafted with Nitroxides as a Recyclable Green Catalyst in the Selective Oxidation of Alcohols

Agnieszka Krogul-Sobczak, Natalia Pisarek, Piotr Cieciórski and Elżbieta Megiel

Nanomaterials, 2022, 12, 2542
DOI: 10.3390/nano12152542

Electrochemical alcohols oxidation mediated by N-hydroxyphthalimide on nickel foam surface

Leila Behrouzi, Robabeh Bagheri, Mohammad Reza Mohammadi, Zhenlun Song, Petko Chernev, Holger Dau, Mohammad Mahdi Najafpour and Babak Kaboudin

Sci Rep, 2020, 10
DOI: 10.1038/s41598-020-75397-8

Boosting Aerobic Oxidation of Alcohols via Synergistic Effect between TEMPO and a Composite Fe3O4/Cu-BDC/GO Nanocatalyst

Hassan Alamgholiloo, Sadegh Rostamnia, Kaiqiang Zhang, Tae Hyung Lee, Yoon-Sik Lee, Rajender S. Varma, Ho Won Jang and Mohammadreza Shokouhimehr

ACS Omega, 2020, 5, 5182
DOI: 10.1021/acsomega.9b04209

A green and template-free electropolymerization of imipramine. The decoration of sponge-like polymer film with gold nanoparticles

Zahra Souri, Saber Alizadeh, Davood Nematollahi, Mohammad Mazloum-Ardakani and Abbas Karami

Journal of Electroanalytical Chemistry, 2021, 894, 115340
DOI: 10.1016/j.jelechem.2021.115340

Preparation of TEMPO-modified PEDOT electrode via click reaction and its electrocatalytic properties for HMF oxidation

Haochen Wang, Xin Liu, Chenyang Ling, Zhenlu Shen and Meichao Li

Reactive and Functional Polymers, 2025, 214, 106300
DOI: 10.1016/j.reactfunctpolym.2025.106300

2,2,6,6‐Tetramethylpiperidinyloxyl (TEMPO) Radical Mediated Electro‐Oxidation Reactions: A Review

Nishitha Prakash, Rijo Rajeev, Anjali John, Ajesh Vijayan, Louis George and Anitha Varghese

ChemistrySelect, 2021, 6, 7691
DOI: 10.1002/slct.202102346

Synthesis of new zirconium complex supported on MCM‐41 and its application as an efficient catalyst for synthesis of sulfides and the oxidation of sulfur containing compounds

Taiebeh Tamoradi, Arash Ghorbani‐Choghamarani and Mohammad Ghadermazi

Applied Organom Chemis, 2018, 32
DOI: 10.1002/aoc.4340

2,2,6,6-Tetramethyl piperidine-1-oxyl mediated electrocatalytic oxidation of ethylene glycol in water and dichloromethane

Wenbin Zhang, Zhixing Xiong, Zhangcai Zhang and Hang Gao

International Journal of Hydrogen Energy, 2017, 42, 2134
DOI: 10.1016/j.ijhydene.2016.11.165

Green tea extract–modified silica gel decorated with palladium nanoparticles as a heterogeneous and recyclable nanocatalyst for Buchwald-Hartwig C–N cross-coupling reactions

Hojat Veisi, Taiebeh Tamoradi, Bikash Karmakar and Saba Hemmati

Journal of Physics and Chemistry of Solids, 2020, 138, 109256
DOI: 10.1016/j.jpcs.2019.109256

Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions

Jordan E. Nutting, Mohammad Rafiee and Shannon S. Stahl

Chem. Rev., 2018, 118, 4834
DOI: 10.1021/acs.chemrev.7b00763

Design and engineering of heterogeneous nitroxide-mediated catalytic systems for selective oxidation: Efficiency and sustainability

Tianyou Chen, Wei Xiao, Zihao Wang, Ting Xie, Changfeng Yi and Zushun Xu

Materials Today Chemistry, 2022, 24, 100872
DOI: 10.1016/j.mtchem.2022.100872

Synthesis of SBA-15@3,4,5-tri Hydroxyphenyl Acetic@ Tb for the Facile Synthesis of 5-Substituted 1 H-tetrazoles

Mohammad Ghadermazi and Somayeh Molaei

Catal Surv Asia, 2023, 27, 139
DOI: 10.1007/s10563-022-09375-7

Improved adhesion and performance of vertically-aligned mesoporous silica-nanochannel film on reduced graphene oxide for direct electrochemical analysis of human serum

Fengna Xi, Lingli Xuan, Lili Lu, Jie Huang, Fei Yan, Jiyang Liu, Xiaoping Dong and Peng Chen

Sensors and Actuators B: Chemical, 2019, 288, 133
DOI: 10.1016/j.snb.2019.02.115

Palladium pincer complex incorporation onto the Fe3O4-entrapped cross-linked multilayered polymer as a high loaded nanocatalyst for oxidation

Nasrin Zohreh, Seyed Hassan Hosseini, Maryam Tavakolizadeh, Cristina Busuioc and Raluca Negrea

Journal of Molecular Liquids, 2018, 266, 393
DOI: 10.1016/j.molliq.2018.06.076

Reaction and transport co-intensification enhanced continuous flow electrocatalytic aminoxyl-mediated oxidation of sterol intermediates by 3D porous framework electrode

Suiqin Li, Chun Li, Kai Li, Xiang Sun, Xing Zhong, Jiahui He, Zaixiang Xu, Xin Liu, Jiefeng Zhang, Fangjun Shao, Meichao Li, Zhengbin Zhang, Xiaonian Li and Jianguo Wang

Chemical Engineering Journal, 2022, 446, 136659
DOI: 10.1016/j.cej.2022.136659

Recent progress on functional mesoporous materials as catalysts in organic synthesis

Yong Wu, Yuanteng Zhang, Jing Zhou and Dong Gu

emergent mater., 2020, 3, 247
DOI: 10.1007/s42247-020-00086-1

Fabrication of molybdenum disulphide / carbon paste (MoS2/CP) nanocomposite as a modified platinum electrode for electrocatalytic oxidation of benzyl alcohol in biphasic electrolysis

G. Savari Susila, A. John Bosco and S. Joseph Selvaraj

Journal of the Indian Chemical Society, 2024, 101, 101202
DOI: 10.1016/j.jics.2024.101202

Co-Ni based hybrid transition metal oxide nanostructures for cost-effective bi-functional electrocatalytic oxygen and hydrogen evolution reactions

G. Mohan Kumar, P. Ilanchezhiyan, C. Siva, A. Madhankumar, T.W. Kang and D.Y. Kim

International Journal of Hydrogen Energy, 2020, 45, 391
DOI: 10.1016/j.ijhydene.2019.10.104

Selective Electro-oxidation of Alcohols to the Corresponding Aldehydes in Aqueous Solution via Cu(III) Intermediates from CuO Nanorods

Zhiyong Fang, Peili Zhang, Mei Wang, Fusheng Li, Xiujuan Wu, Ke Fan and Licheng Sun

ACS Sustainable Chem. Eng., 2021, 9, 11855
DOI: 10.1021/acssuschemeng.1c03691

Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene–TEMPO Conjugate

Amit Das and Shannon S. Stahl

Angewandte Chemie, 2017, 129, 9018
DOI: 10.1002/ange.201704921

TEMPO-Functionalized Nanoporous Au Nanocomposite for the Electrochemical Detection of H2O2

Dongxiao Wen, Qianrui Liu, Ying Cui, Huaixia Yang and Jinming Kong

International Journal of Analytical Chemistry, 2018, 2018, 1
DOI: 10.1155/2018/1710438

Integration of vertically-ordered mesoporous silica-nanochannel film with electro-activated glassy carbon electrode for improved electroanalysis in complex samples

Lingli Xuan, Wenyan Liao, Meifang Wang, Huaxu Zhou, Yao Ding, Fei Yan, Jiyang Liu, Hongliang Tang and Fengna Xi

Talanta, 2021, 225, 122066
DOI: 10.1016/j.talanta.2020.122066

Nitrogen-doped reduced graphene oxide-supported Mn3O4: An efficient heterogeneous catalyst for the oxidation of vanillyl alcohol to vanillin

Ziliang Yuan, Shaohua Chen and Bing Liu

J Mater Sci, 2017, 52, 164
DOI: 10.1007/s10853-016-0318-5

A Transition‐Metal‐Free Homogeneous TEMPO‐Based Catalyst: Aerobic Oxidation of Alcohols in Aqueous Media

Mohammad Sadegh Laeini and Ahmad Shaabani

ChemistrySelect, 2017, 2, 9084
DOI: 10.1002/slct.201701428

Preparation of poly(carbazole-TEMPO) electrode and its electrochemical performance

Pengfei Niu, Haitong Huang, Lingmin Zhao, Chao Zhang, Zhenlu Shen and Meichao Li

Journal of Electroanalytical Chemistry, 2021, 894, 115352
DOI: 10.1016/j.jelechem.2021.115352

Biomass derived worm-like nitrogen-doped-carbon framework for trace determination of toxic heavy metal lead (II)

Cuixing Xu, Jingju Liu, Yanni Bi, Chongbo Ma, Jing Bai, Zongqian Hu and Ming Zhou

Analytica Chimica Acta, 2020, 1116, 16
DOI: 10.1016/j.aca.2020.04.033

Improving education in electrochemistry via a modeling approach and focusing on green chemistry applications

Rosaria Ciriminna, Mina Ghahremani, Fahimeh Varmaghani, Babak Karimi and Mario Pagliaro

Sustainable Chemistry and Pharmacy, 2023, 31, 100931
DOI: 10.1016/j.scp.2022.100931

Polyoxometalate-based covalent organic frameworks: The next generation of heterogeneous catalysts

Arash Ebrahimi, Lukáš Krivosudský, Saeed Khodabakhshi, Masoud Khaleghiabbasabadi, Masoud Sadeghi and Martin Motola

Coordination Chemistry Reviews, 2026, 548, 217201
DOI: 10.1016/j.ccr.2025.217201

A review on photo-, electro- and photoelectro- catalytic strategies for selective oxidation of alcohols

Duoyue Tang, Guilong Lu, Zewen Shen, Yezi Hu, Ling Yao, Bingfeng Li, Guixia Zhao, Baoxiang Peng and Xiubing Huang

Journal of Energy Chemistry, 2023, 77, 80
DOI: 10.1016/j.jechem.2022.10.038

Electrochemically Assisted Self-Assembly Technique for the Fabrication of Mesoporous Metal–Organic Framework Thin Films: Composition of 3D Hexagonally Packed Crystals with 2D Honeycomb-like Mesopores

Saber Alizadeh and Davood Nematollahi

J. Am. Chem. Soc., 2017, 139, 4753
DOI: 10.1021/jacs.6b12564

A green methodology for thioether formation reaction and synthesis of symmetrical disulfides over new heterogeneous Cu attached to bifunctionalized mesoporous MCM-41

Somayeh Molaei and Mohammad Ghadermazi

Microporous and Mesoporous Materials, 2021, 319, 110990
DOI: 10.1016/j.micromeso.2021.110990

Synthesis of large-sized mesoporous silica spheres by pseudomorphic transformation of commercial silica spheres

Xitong Li, Di Wu, Jingxuan Wang, Wenjie Zhu, Yongming Luo, Caiyun Han, Wenhui Ma and Sufang He

Microporous and Mesoporous Materials, 2016, 226, 309
DOI: 10.1016/j.micromeso.2016.02.010

TEMPO in Chemical Transformations: From Homogeneous to Heterogeneous

Hazi Ahmad Beejapur, Qi Zhang, Kecheng Hu, Li Zhu, Jianli Wang and Zhibin Ye

ACS Catal., 2019, 9, 2777
DOI: 10.1021/acscatal.8b05001

Bifunctionalized ordered mesoporous organosilica synthesized in deep eutectic solvent for extraction of triazine herbicides from watermelon

Zan Li, Jun Jia, Mingwei Wang, Hua Zhang, Hongyuan Yan and Fengxia Qiao

Journal of Chromatography A, 2017, 1529, 50
DOI: 10.1016/j.chroma.2017.10.074

Heterogeneous Electrocatalysts for Electrochemical Cross‐Coupling Reactions

Deepak K. K. Kori and Apurba K. Das

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202401491

Electrografting of amino-TEMPO on graphene oxide and electrochemically reduced graphene oxide for electrocatalytic applications

Baiqing Yuan, Chunying Xu, Daojun Zhang, Renchun Zhang, Huimin Su, Pei Guan, Jiajia Nie and Carlos Fernandez

Electrochemistry Communications, 2017, 81, 18
DOI: 10.1016/j.elecom.2017.05.016

Silica Nanochannel Membranes for Electrochemical Analysis and Molecular Sieving: A Comprehensive Review

Ping Zhou, Lina Yao, Kexin Chen and Bin Su

Critical Reviews in Analytical Chemistry, 2020, 50, 424
DOI: 10.1080/10408347.2019.1642735

One-pot Synthesis of Pyranoquinoline Derivatives Using a New Nanomagnetic Catalyst Supported on Functionalized 4-Aminopyridine (AP) Silica

Amir Shabanloo, Ramin Ghorbani-Vaghei and Sedigheh Alavinia

Organic Preparations and Procedures International, 2020, 52, 402
DOI: 10.1080/00304948.2020.1779566

New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol

Babak Karimi, Mina Ghahremani, Rosaria Ciriminna and Mario Pagliaro

Org. Process Res. Dev., 2018, 22, 1298
DOI: 10.1021/acs.oprd.8b00156

Slow-release persulfate candle-assisted electrochemical oxidation of 2-methylnaphthalene: Effects of chloride, sulfate, and bicarbonate

Ardie Septian and Won Sik Shin

Journal of Hazardous Materials, 2020, 400, 123196
DOI: 10.1016/j.jhazmat.2020.123196

Oxidation in Flow Using an Ionic Immobilized TEMPO Catalyst on an Ion Exchange Resin

Johannes Gmeiner and Gerrit Luinstra

Catalysts, 2024, 14, 542
DOI: 10.3390/catal14080542

A comprehensive electrochemical study of 2-mercaptobenzoheterocyclic derivatives. Air-assisted electrochemical synthesis of new sulfonamide derivatives

Nesa Youseflouei, Saber Alizadeh, Mahmood Masoudi-Khoram, Davood Nematollahi and Hojjat Alizadeh

Electrochimica Acta, 2020, 353, 136451
DOI: 10.1016/j.electacta.2020.136451

Ultrathin Sulfonated Mesoporous Silica Film with Well-Ordered Perpendicular Mesochannels: In-Situ Preparation, Characterization and Permselectivity

Anxin Feng, Ying Liu, Shuai Tang, Lujian Lin and Xia Sun

NANO, 2021, 16
DOI: 10.1142/S1793292021501162

Surface modification using TEMPO and its derivatives

Elżbieta Megiel

Advances in Colloid and Interface Science, 2017, 250, 158
DOI: 10.1016/j.cis.2017.08.008