Issue 48, 2015

Carbon nanotube–polyaniline core–shell nanostructured hydrogel for electrochemical energy storage

Abstract

Conductive polymer hydrogels, which synergize the advantageous features of hydrogels and conductive materials, have been utilized in many electrochemical energy storage applications. Here, we introduce phytic acid as (1) a dispersing agent for pristine multi-walled carbon nanotubes (MWNTs) in aqueous solution containing aniline and as (2) a gelator to form polyaniline (PANI)-based hydrogels after polymerization. The PANI-based hydrogels exhibit nanowire-based mesoporous networks with high surface area and electrical conductivity. The nanostructured core (MWNT)–shell (PANI) hydrogels show an improvement on the electrical conductivity from 0.21 to 1.54 S cm−1 as the loading of MWNTs increases from 0 to 5.0 wt%. The conducting nanowire-based networks with MWNT loadings of 3.0 wt% in the hydrogel provide efficient electron transport pathways that exhibit a maximal specific capacity of 609 F g−1. The scalable and facile synthesis demonstrates excellent electrochemical performance, rendering it attractive for sensing, energy conversion, and energy storage applications.

Graphical abstract: Carbon nanotube–polyaniline core–shell nanostructured hydrogel for electrochemical energy storage

Supplementary files

Article information

Article type
Paper
Submitted
15 févr. 2015
Accepted
14 avr. 2015
First published
14 avr. 2015

RSC Adv., 2015,5, 37970-37977

Author version available

Carbon nanotube–polyaniline core–shell nanostructured hydrogel for electrochemical energy storage

P. Chen, N. Dorval Courchesne, M. N. Hyder, J. Qi, A. M. Belcher and P. T. Hammond, RSC Adv., 2015, 5, 37970 DOI: 10.1039/C5RA02944A

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