Issue 76, 2020

Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML

Abstract

The present study reports the first example of a proton-promoted disproportionation reaction of a non-heme iron(V)-imido TAML (1) complex to give an iron(V)-imido TAML cation radical (2) and an iron(IV) TAML (3) upon addition of acids. Detailed mechanistic investigations revealed that two molecules of 1 react with one proton to yield 2 and [FeIV(NHTs)(TAML)] (4), followed by the reaction of 4 with another proton to afford 3 and NH2Ts.

Graphical abstract: Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML

Supplementary files

Article information

Article type
Communication
Submitted
28 juil. 2020
Accepted
13 août 2020
First published
14 août 2020

Chem. Commun., 2020,56, 11207-11210

Proton-promoted disproportionation of iron(V)-imido TAML to iron(V)-imido TAML cation radical and iron(IV) TAML

X. Lu, Y. Lee, M. S. Seo and W. Nam, Chem. Commun., 2020, 56, 11207 DOI: 10.1039/D0CC05145D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements