Issue 18, 2019

Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

Abstract

We report the first molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand. By employing several spectroscopic methods we are able to pinpoint the pentaphosphine environment and evaluate the activation of the dinitrogen ligand. Furthermore, we conduct protonation experiments and obtain spectroscopic evidence for the formation of a hydrazido-species.

Graphical abstract: Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

Supplementary files

Article information

Article type
Paper
Submitted
30 nov. 2018
Accepted
29 janv. 2019
First published
31 janv. 2019

Dalton Trans., 2019,48, 6019-6025

Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

T. Weyrich, J. Krahmer, T. A. Engesser, C. Näther and F. Tuczek, Dalton Trans., 2019, 48, 6019 DOI: 10.1039/C8DT04738C

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