Issue 2, 2017

Rh(0)/Rh(iii) core–shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis

Abstract

Rh(0)/Rh(III) core–shell nanoparticles were prepared by surface oxidation of Rh nanoparticles with N-bromosuccinimide. They were employed as heterogeneous catalysts for cyclic carbonate synthesis from propylene oxide and CO2, and exhibited high activity and excellent recyclability due to Lewis acidic Rh(III) species on the shells.

Graphical abstract: Rh(0)/Rh(iii) core–shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis

Supplementary files

Article information

Article type
Communication
Submitted
15 oct. 2016
Accepted
02 déc. 2016
First published
02 déc. 2016

Chem. Commun., 2017,53, 384-387

Rh(0)/Rh(III) core–shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis

Y. Jung, T. Shin, K. Kim, H. Byun, S. J. Cho, H. Kim and H. Song, Chem. Commun., 2017, 53, 384 DOI: 10.1039/C6CC08318H

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