Issue 4, 2016

Phosphorus Lewis acids: emerging reactivity and applications in catalysis

Abstract

Part of the renaissance in main group chemistry has been a result of the focus on reactivity. This has led to the development of applications in stoichiometric reactivity and catalysis. In this tutorial review, we focus attention on the role of phosphorus-based Lewis acids in such advances. While early literature recognizes the role of P(III) and P(V) electrophiles in coordination chemistry, it has generally been more recent studies that have focused on applications of this Lewis acidity. Applications of these novel P-based Lewis acids in stoichiometric reactivity, Lewis acid catalysis and frustrated Lewis pair (FLP) reactivity are reviewed. These advances demonstrate that P-based Lewis acids are a powerful tool for further developments in metal-free catalysis.

Graphical abstract: Phosphorus Lewis acids: emerging reactivity and applications in catalysis

Article information

Article type
Tutorial Review
Submitted
03 juil. 2015
First published
10 août 2015

Chem. Soc. Rev., 2016,45, 765-774

Author version available

Phosphorus Lewis acids: emerging reactivity and applications in catalysis

J. M. Bayne and D. W. Stephan, Chem. Soc. Rev., 2016, 45, 765 DOI: 10.1039/C5CS00516G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements