Nitridation-driven construction of Ru/WNO catalysts enables highly selective cellulose to C2 alcohols hydrogenolysis

Abstract

Nitrogen-controlled nitridation of WOx yields Ru/WNO catalysts with tunable acidity, vacancy density, and Ru electronic structure. An optimally formed Ru/WNO/W interface enables selective retro-aldol scission and hydrogenation, affording 77.4% C2 alcohols selectivity from cellulose, whereas over-nitridation generates an inactive Ru–W alloy.

Graphical abstract: Nitridation-driven construction of Ru/WNO catalysts enables highly selective cellulose to C2 alcohols hydrogenolysis

Supplementary files

Article information

Article type
Communication
Submitted
17 Dec 2025
Accepted
02 Feb 2026
First published
03 Feb 2026

Chem. Commun., 2026, Advance Article

Nitridation-driven construction of Ru/WNO catalysts enables highly selective cellulose to C2 alcohols hydrogenolysis

W. Jia, N. Zhai, H. Wang, D. Wang, Y. Cui, G. Ren and X. Yang, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC07174G

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