Issue 15, 2023

Piezoelectrically enhanced photocatalysis of KxNa1−xNbO3 (KNN) microstructures for efficient water purification

Abstract

As a kind of excellent multifunctional metal oxide semiconductor, KxNa1−xNbO3 (KNN) has been widely applied in a variety of fields such as photocatalysis and energy harvesting due to its excellent piezoelectric, dielectric and photovoltaic properties in recent decades. In this report, octahedron-shaped K0.4Na0.6NbO3 (KNN-6) microstructures assembled by cubic nanoparticles with {010} exposed facets were synthesized via a one-pot hydrothermal reaction. Due to the accumulation of electrons on the exposed facets, which was conducive to the separation of photo-generated electron–hole pairs, the microstructures could achieve a highly efficient photocatalytic performance for wastewater degradation. In addition, owing to the piezoelectric effect of KNN crystals, the degradation efficiency could be further enhanced by introducing ultrasonic vibration. Using methylene blue (MB) as the organic dye to evaluate their wastewater degradation efficiency, the KNN microstructures achieved their best catalytic performance when the atomic ratio of KOH to NaOH in the reactant was set at 4 : 6 (KNN-6). Under the synergistic effect of light irradiation and ultrasonic vibration, MB could almost be completely (99%) degraded within 40 minutes by KNN-6 microstructures, which was several times more efficient than that of pure NaNbO3 or KNbO3 in previous reports. This work demonstrated that the K0.4Na0.6NbO3 (KNN-6) microstructure could be a prominent candidate for wastewater purification. The formation mechanism of KNN crystals and the role of the piezoelectric effect in the photocatalytic process were also discussed.

Graphical abstract: Piezoelectrically enhanced photocatalysis of KxNa1−xNbO3 (KNN) microstructures for efficient water purification

Supplementary files

Article information

Article type
Paper
Submitted
31 déc. 2022
Accepted
01 mars 2023
First published
01 mars 2023
This article is Open Access
Creative Commons BY-NC license

Nanoscale, 2023,15, 6920-6933

Piezoelectrically enhanced photocatalysis of KxNa1−xNbO3 (KNN) microstructures for efficient water purification

R. Guo, M. Liu, Y. Xing, T. Bai, C. Zhao, H. Huang and H. Zhang, Nanoscale, 2023, 15, 6920 DOI: 10.1039/D2NR07311K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements