Issue 17, 2021

Rational assembly of metal-oxo clusters into molecular materials via a “wheel mounting” mode

Abstract

We devised a new self-assembly method towards the construction of molecular materials via a “wheel mounting” mode of [Ti3M] (M = Co or Zn) clusters. Assembly of these clusters was designable and customizable into desirable size, shape, and properties. An optical-driven molecular transition was realized with the stimulus–response of photochromism. This work not only provides an approach towards predictable and designable clusters, it also establishes a cluster-based structural model of molecular materials.

Graphical abstract: Rational assembly of metal-oxo clusters into molecular materials via a “wheel mounting” mode

Supplementary files

Article information

Article type
Research Article
Submitted
22 juin 2021
Accepted
22 juil. 2021
First published
23 juil. 2021

Inorg. Chem. Front., 2021,8, 4102-4106

Rational assembly of metal-oxo clusters into molecular materials via a “wheel mounting” mode

H. Fu, X. Wu, W. Fang, L. Zhang, F. Wang and J. Zhang, Inorg. Chem. Front., 2021, 8, 4102 DOI: 10.1039/D1QI00779C

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