Issue 30, 2021

A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Abstract

Charge-neutral [Na2Fe10O6(OH)4(isobutyrate)14(MeO)2(MeCN)2] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {FeIII33-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na2Fe10O6(OH)4(isobutyrate)14(bpy)(MeO)2(MeCN)2]·MeOH}n in which the dodecanuclear cluster units are bpy-bridged into 1D chains.

Graphical abstract: A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Supplementary files

Article information

Article type
Communication
Submitted
10 juin 2021
Accepted
19 juil. 2021
First published
20 juil. 2021

CrystEngComm, 2021,23, 5153-5156

A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

D. Podgornii, J. van Leusen, V. Ch. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2021, 23, 5153 DOI: 10.1039/D1CE00777G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements