Issue 28, 2019

Efficiency vs. stability: dopant-free hole transporting materials towards stabilized perovskite solar cells

Abstract

In the last decade, perovskite solar cells have been considered a promising and burgeoning technology for solar energy conversion with a power conversion efficiency currently exceeding 24%. However, although perovskite solar cells have achieved high power conversion efficiency, there are still several challenges limiting their industrial realization. The actual bottleneck for real uptake in the market still remains the cost-ineffective components and instability, to which doping-induced degradation of charge selective layers may contribute significantly. This article overviews the highest performance molecular and polymeric doped and dopant-free HTMs, showing how small changes in the molecular structure such as different atoms and different functional groups and changes in substitution positions or the length of the π-conjugated systems can affect photovoltaic performance and long-term stability of perovskite solar cells.

Graphical abstract: Efficiency vs. stability: dopant-free hole transporting materials towards stabilized perovskite solar cells

Article information

Article type
Minireview
Submitted
09 mars 2019
Accepted
17 mai 2019
First published
20 mai 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2019,10, 6748-6769

Efficiency vs. stability: dopant-free hole transporting materials towards stabilized perovskite solar cells

K. Rakstys, C. Igci and M. K. Nazeeruddin, Chem. Sci., 2019, 10, 6748 DOI: 10.1039/C9SC01184F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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