Issue 32, 2016

Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

Abstract

Three novel AIEgens with low-lying LUMO energy levels are developed from p-π conjugated 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles. It is found that intramolecular interactions lower the molecular conformational changes, giving rise to broad 1H NMR peaks and decreased AIE activity.

Graphical abstract: Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

Supplementary files

Article information

Article type
Communication
Submitted
01 juil. 2016
Accepted
24 juil. 2016
First published
25 juil. 2016

J. Mater. Chem. C, 2016,4, 7541-7545

Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

B. Chen, H. Nie, R. Hu, A. Qin, Z. Zhao and B. Z. Tang, J. Mater. Chem. C, 2016, 4, 7541 DOI: 10.1039/C6TC02738E

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