Issue 7, 2016

Visible-light-driven CO2 reduction on a hybrid photocatalyst consisting of a Ru(ii) binuclear complex and a Ag-loaded TaON in aqueous solutions

Abstract

A hybrid photocatalyst consisting of a Ru(II) binuclear complex and a Ag-loaded TaON reduced CO2 by visible light even in aqueous solution. The distribution of the reduction products was strongly affected by the pH of the reaction solution. HCOOH was selectively produced in neutral conditions, whereas the formation of HCOOH competed with H2 evolution in acidic conditions. Detailed mechanistic studies revealed that the photocatalytic CO2 reduction proceeded via ‘Z-schematic’ electron transfer with step-by-step photoexcitation of TaON and the photosensitizer unit in the Ru(II) binuclear complex. The maximum turnover number for HCOOH formation was 750 based on the Ru(II) binuclear complex under visible-light irradiation, and the optimum external quantum efficiency of the HCOOH formation was 0.48% using 400 nm monochromic light with ethylenediaminetetraacetic acid disodium salt as a sacrificial reductant. Even in aqueous solution, the hybrid could also convert visible-light energy into chemical energy (ΔG0 = +83 kJ mol−1) by the reduction of CO2 to HCOOH with methanol oxidation.

Graphical abstract: Visible-light-driven CO2 reduction on a hybrid photocatalyst consisting of a Ru(ii) binuclear complex and a Ag-loaded TaON in aqueous solutions

Supplementary files

Article information

Article type
Edge Article
Submitted
06 févr. 2016
Accepted
23 mars 2016
First published
23 mars 2016
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2016,7, 4364-4371

Visible-light-driven CO2 reduction on a hybrid photocatalyst consisting of a Ru(II) binuclear complex and a Ag-loaded TaON in aqueous solutions

A. Nakada, T. Nakashima, K. Sekizawa, K. Maeda and O. Ishitani, Chem. Sci., 2016, 7, 4364 DOI: 10.1039/C6SC00586A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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