Issue 17, 2009

Reactions of Ar′CrCrAr′ with N2O or N3(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

Abstract

Reaction of Ar′CrCrAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2) with heterocumulene reagents N2O or N3(1-Ad) resulted in Ar′Cr(μ-O)2Cr(O)Ar′ or Ar′Cr(μ213-N3(1-Ad))CrAr′ which have no metal–metal bonding.

Graphical abstract: Reactions of Ar′CrCrAr′ with N2O or N3(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

Supplementary files

Article information

Article type
Communication
Submitted
23 janv. 2009
Accepted
06 mars 2009
First published
25 mars 2009

Chem. Commun., 2009, 2332-2334

Reactions of Ar′CrCrAr′ with N2O or N3(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

C. Ni, B. D. Ellis, G. J. Long and P. P. Power, Chem. Commun., 2009, 2332 DOI: 10.1039/B901494B

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