Issue 19, 2023

Structural, vibrational, photoelectrochemical, and optical properties of two-dimensional Ruddlesden–Popper perovskite BA2PbI4 crystals

Abstract

Two-dimensional organic–inorganic hybrid Ruddlesden–Popper perovskites have attracted a lot of attention due to their unique photochemical properties and enhanced stability towards photoluminescence devices. Compared with three-dimensional materials, two-dimensional perovskites show great potential for photoelectric applications due to their tunable band gap, great excitation binding energy, and large crystal anisotropy. Although the synthesis and optical properties of BA2PbI4 crystals have been extensively studied, the role of their microstructure in photoelectric applications, their electronic structure, and their electron–phonon interaction are still poorly understood. In this paper, based on the preparation of BA2PbI4 crystals, the electronic structure, phonon dispersion, and vibrational properties of BA2PbI4 crystals were revealed in detail with the help of density functional theory. The BA2PbI4 stability diagram of formation enthalpy was calculated. The crystal structure of the BA2PbI4 crystals was characterized and calculated with the aid of Rietveld refinement. A contactless fixed-point lighting device was designed based on the principle of an electromagnetic induction coil, and the points with different thicknesses of BA2PbI4 crystal were tested. It is proved that the excitation peak of the bulk is 564 nm, and the surface luminescence peak is 520 nm. Phonon dispersion curves and the total and partial phonon densities of states have been calculated for the BA2PbI4 crystals. The calculated results are in good agreement with the experimental Fourier infrared spectra. Besides the basic characterization of the BA2PbI4 crystals, the photoelectrochemical properties of the materials were also studied, which further proves the excellent photoelectric properties of the BA2PbI4 crystals and the broad application prospect.

Graphical abstract: Structural, vibrational, photoelectrochemical, and optical properties of two-dimensional Ruddlesden–Popper perovskite BA2PbI4 crystals

Supplementary files

Article information

Article type
Paper
Submitted
08 déc. 2022
Accepted
06 avr. 2023
First published
28 avr. 2023

Nanoscale, 2023,15, 8675-8684

Structural, vibrational, photoelectrochemical, and optical properties of two-dimensional Ruddlesden–Popper perovskite BA2PbI4 crystals

A. Du, D. Shen, W. Zhao, Y. Liu, X. Qin, Z. Lin, Y. Ye, E. Chen, S. Xu and T. Guo, Nanoscale, 2023, 15, 8675 DOI: 10.1039/D2NR06860E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements