Issue 22, 2020

Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

Abstract

The structural characterization of a hardly-isolatable molybdenum–dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.

Graphical abstract: Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
16 déc. 2019
Accepted
22 avr. 2020
First published
23 avr. 2020

Phys. Chem. Chem. Phys., 2020,22, 12368-12372

Author version available

Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

A. Yamamoto, K. Arashiba, S. Naniwa, K. Kato, H. Tanaka, K. Yoshizawa, Y. Nishibayashi and H. Yoshida, Phys. Chem. Chem. Phys., 2020, 22, 12368 DOI: 10.1039/C9CP06761B

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