Issue 71, 2020

Diboration of 3-substituted propargylic alcohols using a bimetallic catalyst system: access to (Z)-allyl, vinyldiboronates

Abstract

The diboration of substituted propargylic alcohols has been achieved using a bimetallic Pd/Cu catalyst system. The in situ formation of a pentrafluoroboronic acid intermediate sufficiently activates the C–O bond towards dual catalysis affording (Z)-allyl, vinyldiboronates stereoselectively.

Graphical abstract: Diboration of 3-substituted propargylic alcohols using a bimetallic catalyst system: access to (Z)-allyl, vinyldiboronates

Supplementary files

Article information

Article type
Communication
Submitted
19 mai 2020
Accepted
24 juil. 2020
First published
27 juil. 2020

Chem. Commun., 2020,56, 10313-10316

Author version available

Diboration of 3-substituted propargylic alcohols using a bimetallic catalyst system: access to (Z)-allyl, vinyldiboronates

C. L. Peck, J. Nekvinda and W. L. Santos, Chem. Commun., 2020, 56, 10313 DOI: 10.1039/D0CC03563G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements