Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang and Wenbin Yi
Chem. Sci., 2024,15, 20171-20176
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2024 Chemical Science Covers
Abstract
The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
Norbert Baris, Martin Dračínský, Luca Julianna Tóth, Blanka Klepetářová and Petr Beier
Org. Chem. Front., 2025,12, 5610-5615
Abstract
Photocatalytically generated triplet trifluoromethyl nitrene reacts with sulfides to afford new N-trifluoromethylsulfilimines.
Yi Yang, Nathalie Saffon-Merceron, Julien C. Vantourout and Anis Tlili
Chem. Sci., 2023,14, 3893-3898
Abstract
We disclosed herein a straightforward strategy for the synthesis of unprecedented N-((trifluoromethyl)thio), N-(trifluoromethyl) amines using a combination of isothiocyanates, a fluoride source and an electrophilic trifluoromethylthiolation reagent.
Xiaowei Liu, Shuang Wang, Chi Gao, Wei Guan and Mang Wang
Org. Chem. Front., 2022,9, 4549-4553
Abstract
An unprecedented hydrolyzation-triggered ring opening and recyclization cascade to construct biologically interesting nicotinaldehydes.
Olga Bakhanovich, Blanka Klepetářová and Petr Beier
Org. Biomol. Chem., 2023,21, 7924-7927
Abstract
N-(Per)fluoroalkyl indoles are accessed by rhodium(II)-catalyzed transannulation of 4-cyclohexenyl 1,2,3-triazoles, followed by oxidation of the intermediate indolines.