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Chem. Sci., 2025, 16, 13042
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Sulfur-based mixed ylides: unlocking new reactivity paradigms in modern organic synthesis

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Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent to access 2-(difluoromethyl)naphthalene

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Photoredox-Catalyzed [2 + 1 + 2] Cyclization of Alkenes, Carbyne Equivalents, and Nitriles

Xingda Zhao, Jialin Huang, Zhanyong Tang, Xiaoqiang Ma and Depeng Zhao

ACS Catal., 2025, 15, 10166
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Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides

Josep Esteve Guasch, Debasis Pal and Marcos G. Suero

J. Am. Chem. Soc., 2025, 147, 31444
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Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid

Lu‐Jie Liu, Meng‐Yang Tian, Zhi‐Yu Lang, Yong‐Li Wang, Chun‐Yang He, Yong‐Zheng Chen and Wen‐Yong Han

Angewandte Chemie, 2025, 137
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Rh-Catalyzed Atroposelective Single-Carbon Insertion

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J. Am. Chem. Soc., 2025, 147, 24206
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Visible‐Light‐Driven Multicomponent Reactions of Diazosulfonium Triflates with Amines and CS2 or CO2: Direct Synthesis of Bis‐Dithiocarbamates/Carbamates

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Spiro-C(sp 3 )-atom transfer: Creating rigid three-dimensional structures with Ph 2 SCN 2

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Introducing the Cis‐2,3‐Bis(trifluoromethyl)cyclopropyl Chemotype: Late‐Stage Installation and Stereoelectronic Properties

Daniel Gaviña, Zeyu Feng, David Herrero, Martin Simon, Christopher Golz and Manuel Alcarazo

ChemistryEurope, 2026, 4
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Visible Light‐Induced Single‐Atom Insertion of Indenes via Aerobic Ring Scission–Condensation–Rearomatization

Guohui Zeng, Zeyuan Fu, Biaolin Yin and Liangbin Huang

Chemistry A European J, 2025, 31
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Recent Applications of Sulfonium Salts in Synthesis and Catalysis

Sven Timmann, Zeyu Feng and Manuel Alcarazo

Chemistry A European J, 2024, 30
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Trifluoromethylcarbinolation of (hetero)arenes enabled by trifluoromethyl carbyne

Meng-Yang Tian, Yong-Chao Shao, Wen-Wen Zhao, Zhi-Yu Lang, Jian-Fei Zhao, Yong-Jian Lu, Chun-Yang He, Yong-Zheng Chen and Wen-Yong Han

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Generation of Stereocenters via Single-Carbon-Atom Doping Using N-Isocyanides

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J. Am. Chem. Soc., 2025, 147, 8138
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A Diazo-free Equivalent of the Unsubstituted Carbyne Cation: Straightforward Synthesis of Naphthalenes and Pyridines via [12/13CH]+ Insertion

Nicola S. Wenzel, Philipp C. Brehm, Maike Mücke, Monish A. Ansari, Brigitte Worbs, Martin Simon, Christopher Golz, Ricardo A. Mata and Manuel Alcarazo

J. Am. Chem. Soc., 2026, 148, 3852
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Bisnucleophilic Substitution of α‐Diazo Sulfonium Salts for Glycine Derivatives via a Dicationic Intermediate Enabled by an Umpolung Strategy

Si‐Yu Yan, Chang‐Long Rong, Zi‐Qiang Zhang, Si‐Fu Gao, Tian‐Yu Du, Hao Wang, Zi‐Hao Zhang, Xiao‐Yu Mei, Qiang‐Qiang Li and Jun Xuan

Helvetica Chimica Acta, 2025, 108
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Skeleton Editing of Indenes With Metal Carbenes to Access 1,2‐Dihydronaphthalenes

Wenjie Zhang, Xiaolong Zhang, Zhaohong Liu, Ge Yin, Xiangru Shen, Wei Song, Hongru Zhang, Paramasivam Sivaguru and Xihe Bi

Angewandte Chemie, 2026, 138
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Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid

Lu‐Jie Liu, Meng‐Yang Tian, Zhi‐Yu Lang, Yong‐Li Wang, Chun‐Yang He, Yong‐Zheng Chen and Wen‐Yong Han

Angew Chem Int Ed, 2025, 64
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Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates

Tatsuya Morimoto, Yoshio Nishimoto, Taku Suzuki-Osborne, Su-Gi Chong, Kazuhiro Okamoto, Tomoki Yoneda, Azusa Kikuchi, Daisuke Yokogawa, Mahito Atobe and Naoki Shida

J. Am. Chem. Soc., 2025, 147, 25635
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Dibenzothiophenium Salts: Practical Alternatives to Hypervalent I(III)-Based Reagents

Manuel Alcarazo

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A Photocatalytic Approach to Radical 1-(Trifluoromethyl)cyclopropanation

Sven Timmann, Moritz T. H. Dilchert, Jörg Dietzel, Verena S. Pöltl, Marc R. Wennekamp, Christopher Golz and Manuel Alcarazo

ACS Catal., 2025, 15, 7232
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Making, Using, and Understanding Molecular Systems: The 57th Bürgenstock Conference

Martina Letizia Contente and Oliver Dumele

Angew Chem Int Ed, 2024, 63
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Skeletal Editing of Hydroxyl Oxindoles via Organoiodine‐Catalyzed Oxygen Atom Insertion Reaction

Yang Wang, Xin‐Zhi Zhou, Xin‐Yan Ke, Yue Wang, Shao‐Fei Ni and Feng Shi

Angewandte Chemie, 2026, 138
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Skeleton Editing of Indenes With Metal Carbenes to Access 1,2‐Dihydronaphthalenes

Wenjie Zhang, Xiaolong Zhang, Zhaohong Liu, Ge Yin, Xiangru Shen, Wei Song, Hongru Zhang, Paramasivam Sivaguru and Xihe Bi

Angew Chem Int Ed, 2026, 65
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An Overview of 2,2,2‐Trifluoroethyl Sulfonium Salts: Preparation and Synthetic Applications

Jiang‐Yu Li, Yu‐Fei Yao, Meng‐Zhu Xu, Wen‐Jin Xu and Cheng‐Pan Zhang

Eur J Org Chem, 2026, 29
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Iron-catalysed synthesis of sulfonamides and sulfonic esters: Greener sulfonation of amines and alcohols under mechanical grinding conditions

Pandeeshwaran Santhoshkumar, Thangapandiyan Kanagaraj and Palaniswamy Suresh

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Annulation of α-Diazo Sulfonium Salts with α-Vinylanilines via a Dicationic Intermediate toward Quinolines

Zi-Qiang Zhang, Xing Li, Si-Fu Gao, Bao-Gui Cai, Qiang-Qiang Li and Jun Xuan

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Molekulare Systeme herstellen, nutzen und verstehen: Die 57. Bürgenstock Konferenz

Martina Letizia Contente and Oliver Dumele

Angewandte Chemie, 2024, 136
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Skeletal Editing of Hydroxyl Oxindoles via Organoiodine‐Catalyzed Oxygen Atom Insertion Reaction

Yang Wang, Xin‐Zhi Zhou, Xin‐Yan Ke, Yue Wang, Shao‐Fei Ni and Feng Shi

Angew Chem Int Ed, 2026, 65
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Asymmetric multi-component trifunctionalization reactions with α-Halo Rh-carbenes

Xiaoyan Yang, Xiaoyu Zhou, Wenhao Hu and Yu Qian

Nat Commun, 2025, 16
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Chemo- and diastereoselective four-component reactions with Rh carbynoids

Mengchu Zhang, Xiaoyan Yang, Xiang Fu, Xiaoyu Zhou, Yu Qian and Wenhao Hu

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Single-Carbon Insertion into Single C–C Bonds with Diazirines

Valero G. Alfonso, Karen de la Vega-Hernández and Marcos G. Suero

J. Am. Chem. Soc., 2025, 147, 57
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Tandem N-H insertion/C-H functionalization-SN1 reaction to access unnatural amino esters and the concise synthesis of Streptindole and Arsindoline B

Dingding Xia, Chundong Huang, Zhimin Hu, Zhiyong Leng, Miaomiao Zhuo, Shoubhik Das, Shaofei Ni, Yu Zhang and Weidong Zhang

Chinese Chemical Letters, 2025, 112224
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