Purine-substituted imidazolium mesomeric betaines and their tautomeric N-heterocyclic carbenes. Formation of a cyclic borane adduct

Jiaxi Zhang, Eike G. Hübner, Jan C. Namyslo, Martin Nieger and Andreas Schmidt

Org. Biomol. Chem., 2018, 16, 6801
DOI: 10.1039/C8OB01916A

A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent

Zachary R. McCarty, Dominika N. Lastovickova and Christopher W. Bielawski

Chem. Commun., 2016, 52, 5447
DOI: 10.1039/C6CC01376G

Stabilization of the Pd–NHC framework with 1,2,4-triazol-5-ylidene ligands toward decomposition in alkaline media

Andrey Yu. Chernenko, Alexander V. Astakhov, Vadim V. Kutyrev, Evgeniy G. Gordeev, Julia V. Burykina, Mikhail E. Minyaev, Victor N. Khrustalev, Victor M. Chernyshev and Valentine P. Ananikov

Inorg. Chem. Front., 2021, 8, 3382
DOI: 10.1039/D1QI00453K

Boron–boron, carbon–carbon and nitrogen–nitrogen bonding in N-heterocyclic carbenes and their diazaboryl and triazole analogues: Wanzlick equilibrium revisited

K. Młodzikowska, A. A. Rajkiewicz, K. Grela and B. Trzaskowski

New J. Chem., 2018, 42, 6183
DOI: 10.1039/C8NJ00296G

Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

Torsten Roth, Vladislav Vasilenko, Callum G. M. Benson, Hubert Wadepohl, Dominic S. Wright and Lutz H. Gade

Chem. Sci., 2015, 6, 2506
DOI: 10.1039/C4SC03966A

Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMesCO2−ligand

Dmitry A. Valyaev, Marina A. Uvarova, Alina A. Grineva, Vincent César, Sergei N. Nefedov and Noël Lugan

Dalton Trans., 2016, 45, 11953
DOI: 10.1039/C6DT02060G

Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications

Sophie Hameury, Pierre de Frémont and Pierre Braunstein

Chem. Soc. Rev., 2017, 46, 632
DOI: 10.1039/C6CS00499G

Labile dioxy-functionalised zwitterionic imidazolinium salt: access to zwitterionic and neutral imidazolidin-2-ylidene derivatives and π-acceptor properties of imidazolidine-2-selones

Vivek Gupta, Vedhagiri Karthik and Ganapathi Anantharaman

RSC Adv., 2015, 5, 87888
DOI: 10.1039/C5RA15333F

N-Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent

Cécile Barthes, Carine Duhayon, Yves Canac and Vincent César

Chem. Commun., 2020, 56, 3305
DOI: 10.1039/D0CC00477D

Coinage Metal Complexes of the Carbenic Tautomer of a Conjugated Mesomeric Betaine Akin to Nitron

Charlotte Thie, Clemens Bruhn, Michael Leibold and Ulrich Siemeling

Molecules, 2017, 22, 1133
DOI: 10.3390/molecules22071133

Stable and Persistent Acyclic Diaminocarbenes with Cycloalkyl Substituents and Their Transformation to β‐Lactams by Uncatalysed Carbonylation with CO

Lars Wallbaum, Daniel Weismann, Dennis Löber, Clemens Bruhn, Pascal Prochnow, Julia E. Bandow and Ulrich Siemeling

Chemistry A European J, 2019, 25, 1488
DOI: 10.1002/chem.201805307

Betaine–N‐Heterocyclic Carbene Interconversions of Quinazolin‐4‐One Imidazolium Mesomeric Betaines. Sulfur, Selenium, and Borane Adduct Formation

Sergey Deev, Sviatoslav Batsyts, Ekaterina Sheina, Tatyana S. Shestakova, Igor Khalimbadzha, Mikhail A. Kiskin, Valery Charushin, Oleg Chupakhin, Alexander S. Paramonov, Zakhar O. Shenkarev, Jan C. Namyslo and Andreas Schmidt

Eur J Org Chem, 2020, 2020, 450
DOI: 10.1002/ejoc.201901622

Sydnonmethide – fast vergessene Mesoionen als Vorläufermoleküle von anionischen N‐heterocyclischen Carbenen

Sebastian Mummel, Felix Lederle, Eike G. Hübner, Jan C. Namyslo, Martin Nieger and Andreas Schmidt

Angewandte Chemie, 2021, 133, 19032
DOI: 10.1002/ange.202107495

Zwitterionic Mixed‐Carbene Coinage Metal Complexes: Synthesis, Structures, and Photophysical Studies

Florian Chotard, Alexander S. Romanov, David L. Hughes, Mikko Linnolahti and Manfred Bochmann

Eur J Inorg Chem, 2019, 2019, 4234
DOI: 10.1002/ejic.201900573

N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt

Andreas A. Danopoulos, Thomas Simler and Pierre Braunstein

Chem. Rev., 2019, 119, 3730
DOI: 10.1021/acs.chemrev.8b00505

Insights into the Catalytic Activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPrCl, IPrBr) Complexes in the Suzuki–Miyaura Reaction

Frédéric Izquierdo, Caroline Zinser, Yury Minenkov, David B. Cordes, Alexandra M. Z. Slawin, Luigi Cavallo, Fady Nahra, Catherine S. J. Cazin and Steven P. Nolan

ChemCatChem, 2018, 10, 601
DOI: 10.1002/cctc.201701279

Stable Di‐ and Tri‐coordinated Carbon(II) Supported by an Electron‐Rich β‐Diketiminate Ligand

Vianney Regnier, Yoan Planet, Curtis E. Moore, Jacques Pecaut, Christian Philouze and David Martin

Angewandte Chemie, 2017, 129, 1051
DOI: 10.1002/ange.201610798

Impact of the Carbene Derivative Charge on the Decomposition Rates of Hoveyda–Grubbs-like Metathesis Catalysts

Magdalena Jawiczuk, Anna Marczyk, Katarzyna Młodzikowska-Pieńko and Bartosz Trzaskowski

J. Phys. Chem. A, 2020, 124, 6158
DOI: 10.1021/acs.jpca.0c03096

N‐Heterocyclic Carbenes with a Nido‐C2B9 Carborane Backbone

Zhongzheng Cui, Beining Wang, Junxia Li, Ronglin Pang, Yanrui Kang and Xu‐Qiong Xiao

Chin. J. Chem., 2021, 39, 2410
DOI: 10.1002/cjoc.202100302

Hoveyda-Grubbs complexes with boryl anions are predicted to be fast metathesis catalysts

B. Trzaskowski and K. Grela

Catalysis Communications, 2016, 86, 133
DOI: 10.1016/j.catcom.2016.08.025

RETRACTED ARTICLE: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review

Sina Matavos-Aramyan, Sadaf Soukhakian and Mohammad Hossein Jazebizadeh

Top Curr Chem (Z), 2020, 378
DOI: 10.1007/s41061-020-00304-8

Air‐Stable Oxyallyl Patterns and a Switchable N‐Heterocyclic Carbene

Eder Tomás‐Mendivil, Marc Devillard, Vianney Regnier, Jacques Pecaut and David Martin

Angewandte Chemie, 2020, 132, 11613
DOI: 10.1002/ange.202002669

Influence of ring substituents on the electronic properties of 1,2,4-triazolylidenes

Torsten Hölzel and Christian Ganter

Journal of Organometallic Chemistry, 2020, 915, 121234
DOI: 10.1016/j.jorganchem.2020.121234

1,3‐Thiazolium‐4‐aminides: Syntheses and Characterization of Fluorescent Mesoionic Compounds

Alena Therese Storm, Mimoza Gjikaj, Jan C. Namyslo, Jörg Adams and Andreas Schmidt

Eur J Org Chem, 2021, 2021, 4803
DOI: 10.1002/ejoc.202100794

Homo- and Heteropolymetallic Complexes of the Hybrid, Ambidentate N-Heterocyclic Carbene Ligand IMes-acac

Vincent César, Valentina Mallardo, Adela Nano, Sadie F. DePeter, Stéphanie Bastin, Alix Sournia-Saquet, Aline Maisse-François, Noël Lugan and Stéphane Bellemin-Laponnaz

ACS Omega, 2018, 3, 15582
DOI: 10.1021/acsomega.8b02268

Radical and Non-Radical States of the [Os(PIQ)] Core (PIQ = 9,10-Phenanthreneiminoquinone): Iminosemiquinone to Iminoquinone Conversion Promoted o-Metalation Reaction

Sachinath Bera, Sandip Mondal, Suvendu Maity, Thomas Weyhermüller and Prasanta Ghosh

Inorg. Chem., 2016, 55, 4746
DOI: 10.1021/acs.inorgchem.6b00040

Smart N-Heterocyclic Carbene Ligands in Catalysis

Eduardo Peris

Chem. Rev., 2018, 118, 9988
DOI: 10.1021/acs.chemrev.6b00695

A Cationic N-Heterocyclic Carbene Containing an Ammonium Moiety

Mirko Ruamps, Noël Lugan and Vincent César

Organometallics, 2017, 36, 1049
DOI: 10.1021/acs.organomet.7b00017

Functionalised N‐Heterocyclic Carbene Ligands in Bimetallic Architectures

Kieren J. Evans and Stephen M. Mansell

Chemistry A European J, 2020, 26, 5927
DOI: 10.1002/chem.201905510

Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis

Alexandre Nasr, Andrea Winkler and Matthias Tamm

Coordination Chemistry Reviews, 2016, 316, 68
DOI: 10.1016/j.ccr.2016.02.011

Buttressing Effect as a Key Design Principle towards Highly Efficient Palladium/N‐Heterocyclic Carbene Buchwald–Hartwig Amination Catalysts

Yin Zhang, Guy Lavigne, Noël Lugan and Vincent César

Chemistry A European J, 2017, 23, 13792
DOI: 10.1002/chem.201702859

Ruthenium Catalysts Supported by Amino‐Substituted N‐Heterocyclic Carbene Ligands for Olefin Metathesis of Challenging Substrates

Vincent César, Yin Zhang, Wioletta Kośnik, Adam Zieliński, Adam A. Rajkiewicz, Mirko Ruamps, Stéphanie Bastin, Noël Lugan, Guy Lavigne and Karol Grela

Chemistry A European J, 2017, 23, 1950
DOI: 10.1002/chem.201604934

Highly Emissive Red Heterobimetallic IrIII/MI (MI = CuI and AuI) Complexes for Efficient Light-Emitting Electrochemical Cells

Anna Bonfiglio, Pei-Wan Hsiao, Yin Chen, Christophe Gourlaouen, Quentin Marchand, Vincent César, Stéphane Bellemin-Laponnaz, Yun-Xin Wang, Chin-Wei Lu, Chantal Daniel, Federico Polo, Hai-Ching Su and Matteo Mauro

Chem. Mater., 2022, 34, 1756
DOI: 10.1021/acs.chemmater.1c03972

Ruthenium Metathesis Catalysts Bearing Anionic N-Heterocyclic Carbenes: A Computational Study on Failed Approaches to Their Synthesis

Anna Marczyk and Bartosz Trzaskowski

Organometallics, 2023, 42, 689
DOI: 10.1021/acs.organomet.3c00068

Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes

Jiwei Wang, Xiaoming Cao, Shichang Lv, Caiyun Zhang, Sheng Xu, Min Shi and Jun Zhang

Nat Commun, 2017, 8
DOI: 10.1038/ncomms14625

Application of N-heterocyclic carbene–Cu(I) complexes as catalysts in organic synthesis: a review

Nosheen Beig, Varsha Goyal and Raj Kumar Bansal

Beilstein J. Org. Chem., 2023, 19, 1408
DOI: 10.3762/bjoc.19.102

Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents

Ajay Padunnappattu, Carine Duhayon, Vincent César and Yves Canac

Organometallics, 2022, 41, 2868
DOI: 10.1021/acs.organomet.2c00429

Anionic N-heterocyclic carbenes derived from sydnone imines such as molsidomine. Trapping reactions with selenium, palladium, and gold

Tyll Freese, Ana-Luiza Lücke, Catharina A.S. Schmidt, Mika Polamo, Martin Nieger, Jan C. Namyslo and Andreas Schmidt

Tetrahedron, 2017, 73, 5350
DOI: 10.1016/j.tet.2017.07.032

Air‐Stable Oxyallyl Patterns and a Switchable N‐Heterocyclic Carbene

Eder Tomás‐Mendivil, Marc Devillard, Vianney Regnier, Jacques Pecaut and David Martin

Angew Chem Int Ed, 2020, 59, 11516
DOI: 10.1002/anie.202002669

Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development

Roman O. Pankov, Darya O. Prima and Valentine P. Ananikov

Coordination Chemistry Reviews, 2024, 516, 215897
DOI: 10.1016/j.ccr.2024.215897

Coinage metal complexes of the carbenic tautomer of Nitron

Charlotte Thie, Sandra Hitzel, Lars Wallbaum, Clemens Bruhn and Ulrich Siemeling

Journal of Organometallic Chemistry, 2016, 821, 112
DOI: 10.1016/j.jorganchem.2016.03.023

Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes

Sebastian Mummel, Felix Lederle, Eike G. Hübner, Jan C. Namyslo, Martin Nieger and Andreas Schmidt

Angew Chem Int Ed, 2021, 60, 18882
DOI: 10.1002/anie.202107495

Stable Di‐ and Tri‐coordinated Carbon(II) Supported by an Electron‐Rich β‐Diketiminate Ligand

Vianney Regnier, Yoan Planet, Curtis E. Moore, Jacques Pecaut, Christian Philouze and David Martin

Angew Chem Int Ed, 2017, 56, 1031
DOI: 10.1002/anie.201610798

Ein redoxaktives, heterobimetallisches N‐heterocyclisches Carben auf Basis eines Bis(imino)pyrazin‐Liganden

Nicolas I. Regenauer, Sven Jänner, Hubert Wadepohl and Dragoş‐Adrian Roşca

Angewandte Chemie, 2020, 132, 19482
DOI: 10.1002/ange.202005865

Palladium(II) Complexes with Anionic N-Heterocyclic Carbene–Borate Ligands as Catalysts for the Amination of Aryl Halides

Andrea Winkler, Kai Brandhorst, Matthias Freytag, Peter G. Jones and Matthias Tamm

Organometallics, 2016, 35, 1160
DOI: 10.1021/acs.organomet.6b00217

Mono‐ IrIII versus Heterobimetallic IrIII‐AuI Complexes for Circularly Polarized Luminescence

Lavinia Ballerini, Christophe Gourlaouen, Mathias Delporte–Pébay, Cristina Cebrián Ávila, Émilie Voirin, Vincent César, Stéphane Bellemin‐Laponnaz, Jeanne Crassous, Chantal Daniel and Matteo Mauro

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501611

Nickel(II) allyl complexes with anionic N-heterocyclic carbene-borate ligands

Jenni Frosch, Matthias Freytag, Peter G. Jones and Matthias Tamm

Journal of Organometallic Chemistry, 2020, 918, 121311
DOI: 10.1016/j.jorganchem.2020.121311

A Redox‐Active Heterobimetallic N‐Heterocyclic Carbene Based on a Bis(imino)pyrazine Ligand Scaffold

Nicolas I. Regenauer, Sven Jänner, Hubert Wadepohl and Dragoş‐Adrian Roşca

Angew Chem Int Ed, 2020, 59, 19320
DOI: 10.1002/anie.202005865

Pyrazoles in the Intersection of Mesomeric Betaines and N-Heterocyclic Carbenes: Formation of NHC Selenium Adducts of Pyrazolium-4-aminides

Kai Hillrichs, Jan C. Namyslo, Felix Lederle, Eike G. Hübner and Andreas Schmidt

Synthesis, 2022, 54, 3351
DOI: 10.1055/s-0040-1719912

Phosphorescent Cationic Heterodinuclear IrIII/MI Complexes (M=CuI, AuI) with a Hybrid Janus‐Type N‐Heterocyclic Carbene Bridge

Anna Bonfiglio, Lenka Pallova, Vincent César, Christophe Gourlaouen, Stéphane Bellemin‐Laponnaz, Chantal Daniel, Federico Polo and Matteo Mauro

Chemistry A European J, 2020, 26, 11751
DOI: 10.1002/chem.202002767

Manual control of catalytic reactions: Reactions by an apoenzyme gel and a cofactor gel

Yuichiro Kobayashi, Yoshinori Takashima, Akihito Hashidzume, Hiroyasu Yamaguchi and Akira Harada

Sci Rep, 2015, 5
DOI: 10.1038/srep16254