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Functionalized magnesium organometallics as versatile intermediates for the synthesis of polyfunctional heterocycles

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Chem. Commun., 2006, 583
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A new procedure for the synthesis of π-conjugated polymers via ligand-free iron(iii)-catalyzed oxidative homocoupling reaction of grignard reagents

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RSC Adv., 2012, 2, 8055
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Synthetic methodologies of achiral diarylmethanols, diaryl and triarylmethanes (TRAMs) and medicinal properties of diaryl and triarylmethanes-an overview

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RSC Adv., 2014, 4, 28317
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Efficient and sustainable laccase-catalyzed iodination ofp-substituted phenols using KI as iodine source and aerial O2as oxidant

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Practical one-pot amidation of N-Alloc-, N-Boc-, and N-Cbz protected amines under mild conditions

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Halogen–magnesium exchange on unprotected aromatic and heteroaromatic carboxylic acids

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Chem. Commun., 2007, 2075
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Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

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Convenient Magnesiation of Aromatic and Heterocyclic Rings Bearing a Hydroxy Group in Presence of LiCl.

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ChemInform, 2005, 36
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Synthesis of (+)-Myrtopsine, (+)-7,8-Dimethoxymyrtopsine, and Related 2,3-Dihydro-3-hydroxy-2-(1-hydroxy-1-methylethyl)benzofuran Natural Products

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HETEROCYCLES, 2006, 70, 279
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Transition‐Metal‐Free Homocoupling of Organomagnesium Compounds

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Angew Chem Int Ed, 2006, 45, 5010
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Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

Nicholas A. Afagh and Andrei K. Yudin

Angew Chem Int Ed, 2010, 49, 262
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Iron-Catalyzed, Chelation-Induced Remote C–H Allylation of Quinolines via 8-Amido Assistance

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Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl

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Chemistry A European J, 2009, 15, 7192
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Recent Advances in Molecular Oxygen Assisted Laccase Catalyzed Sustainable Organic Transformations

Jyothylakshmi Jayakumar, Deepshikha Priyadarshini, Anutthaman Parthasarathy and Sabbasani Rajasekhara Reddy

Asian J Org Chem, 2023, 12
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Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications

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Macromolecules, 2013, 46, 8395
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Selective Acylation of Aryl- and Heteroarylmagnesium Reagents with Esters in Continuous Flow

Benjamin Heinz, Dimitrije Djukanovic, Maximilian A. Ganiek, Benjamin Martin, Berthold Schenkel and Paul Knochel

Org. Lett., 2020, 22, 493
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Magnesiated Unsaturated Silylated Cyanohydrins as Synthetic Equivalents of Aromatic and Heterocyclic Grignard Reagents Bearing a Ketone or an Aldehyde

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Org. Lett., 2006, 8, 617
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Association and Dissociation of Grignard Reagents RMgCl and Their Turbo Variant RMgCl⋅LiCl

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Chemistry A European J, 2016, 22, 7752
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Preparation of Polyfunctional Arylmagnesium Reagents Bearing a Triazene Moiety. A New Carbazole Synthesis

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Improved Procedure for Single-electron-transfer-induced Grignard Cross-coupling Reaction

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Chemistry Letters, 2014, 43, 922
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Efficient Synthesis of Aryl Fluorides

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Angew Chem Int Ed, 2010, 49, 2219
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Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl

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Angew Chem Int Ed, 2008, 47, 6802
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A Convenient Synthesis of Benzonitriles via Electrophilic Cyanation with N‐Cyanobenzimidazole

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Chemistry A European J, 2010, 16, 4725
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Regioselective Functionalization of the Oxazole Scaffold Using TMP-Bases of Mg and Zn

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Einfache Herstellung funktionalisierter Arylmagnesiumreagentien unter Verwendung von Magnesium in Gegenwart von LiCl

Fabian M. Piller, Prasad Appukkuttan, Andrei Gavryushin, Matthew Helm and Paul Knochel

Angewandte Chemie, 2008, 120, 6907
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CuLi2Cl4 catalysed cross-coupling strategy for the formal synthesis of the diterpenoid (+)-subersic acid from (–)-sclareol

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Herstellung und selektive Umsetzungen von gemischt bimetallischen aromatischen und heteroaromatischen Bor‐Magnesium‐Reagentien

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Angewandte Chemie, 2005, 117, 3193
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Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds

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Vollständige Funktionalisierung des Imidazolgerüsts durch selektive Metallierung und Sulfoxid‐Magnesium‐Austausch

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Angewandte Chemie, 2014, 126, 1454
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Chemoselektivität und die eigentümlichen Reaktivitäten funktioneller Gruppen

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The Halogen/Magnesium-Exchange Using iPrMgCl·LiCl and Related Exchange Reagents

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Kinetics of Bromine−Magnesium Exchange Reactions in Heteroaryl Bromides

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Org. Lett., 2009, 11, 3502
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Preparation and Reactions of Heteroaryl Organomagnesium Compounds

Hiriyakkanavar Ila, Oliver Baron, Andreas J Wagner and Paul Knochel

Chemistry Letters, 2006, 35, 2
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Functionalization of Unprotected Uracil Derivatives Using the Halogen−Magnesium Exchange

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Org. Lett., 2007, 9, 1639
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Copper‐Mediated Remote Highly Site‐Selective C–H Bond Bromination and Chlorination of Quinolines at the C5 Position that is Geometrically Difficult to Access

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Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

Florence Mongin and Anne Harrison-Marchand

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Minimization of Side Reactions in Bromine Magnesium Exchanges with i-PrMgCl/LiCl and s-BuMgCl/LiCl Mixtures

Dieter Hauk, Sebastian Lang and Alexander Murso

Org. Process Res. Dev., 2006, 10, 733
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Efficient construction of ABC-tricyclic core of schweinfurthins and its application in amide based analog synthesis

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Selective Transformation of Well‐Defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation

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Chemistry A European J, 2018, 24, 3186
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Full Functionalization of the 7‐Azaindole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange

Nadja M. Barl, Elodie Sansiaume‐Dagousset, Konstantin Karaghiosoff and Paul Knochel

Angew Chem Int Ed, 2013, 52, 10093
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Preparation and Selective Reactions of Mixed Bimetallic Aromatic and Heteroaromatic Boron–Magnesium Reagents

Oliver Baron and Paul Knochel

Angew Chem Int Ed, 2005, 44, 3133
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New and efficient RCM in pyridinic series: synthesis of 2H-dihydropyrano- or 2,3H-dihydrooxepino[3,2-b]pyridines

Estelle Banaszak, Corinne Comoy and Yves Fort

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Catalytic Asymmetric Synthesis of a Tertiary Benzylic Carbon Center via Phenol-Directed Alkene Hydrogenation

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A Unified Strategy Toward 5‐, 6‐, and 7‐Membered Nitrogen Heterocycles Through Free Radical then Metal‐Mediated Functionalization of Ene‐carbamates

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Stability and Unimolecular Reactivity of Palladate(II) Complexes [LnPdR3]− (L=Phosphine, R=Organyl, n=0 and 1)

Marlene Kolter and Konrad Koszinowski

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Preparation of Polyfunctional Aryl Azides from Aryl Triazenes. A New Synthesis of Ellipticine, 9-Methoxyellipticine, Isoellipticine, and 7-Carbethoxyisoellipticine

Ching-Yuan Liu and Paul Knochel

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Continuous Preparation of Arylmagnesium Reagents in Flow with Inline IR Monitoring

Tobias Brodmann, Peter Koos, Albrecht Metzger, Paul Knochel and Steven V. Ley

Org. Process Res. Dev., 2012, 16, 1102
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Synthesis of Functionalized o‐, m‐, and p‐Terphenyl Derivatives by Consecutive Cross‐Coupling Reactions of Triazene‐Substituted Arylboronic Esters

Ching‐Yuan Liu, Andrey Gavryushin and Paul Knochel

Chemistry An Asian Journal, 2007, 2, 1020
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Efficient Synthesis of Aryl Fluorides

Pazhamalai Anbarasan, Helfried Neumann and Matthias Beller

Angewandte Chemie, 2010, 122, 2265
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Übergangsmetall‐freie Homokupplungen von Organomagnesiumverbindungen

Arkady Krasovskiy, Alexander Tishkov, Vicente del Amo, Herbert Mayr and Paul Knochel

Angewandte Chemie, 2006, 118, 5132
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Full Functionalization of the Imidazole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange

Christoph Sämann, Estibaliz Coya and Paul Knochel

Angew Chem Int Ed, 2014, 53, 1430
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2‐[(Neopentyl glycolato)boryl]phenyl Triflates and Halides for Fluoride Ion‐Mediated Generation of Functionalized Benzynes

Takashi Ikawa, Rika Yamamoto, Akira Takagi, Toyohiro Ito, Kazunori Shimizu, Masahiko Goto, Yoshitaka Hamashima and Shuji Akai

Adv Synth Catal, 2015, 357, 2287
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Highly Efficient One-Pot Access to Functionalized Arylboronic Acids via Noncryogenic Bromine/Magnesium Exchanges

Timo Leermann, Frédéric R. Leroux and Françoise Colobert

Org. Lett., 2011, 13, 4479
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Vollfunktionalisierung des 7‐Azaindol‐Gerüsts durch selektive Metallierung und Sulfoxid‐Magnesium‐Austausch

Nadja M. Barl, Elodie Sansiaume‐Dagousset, Konstantin Karaghiosoff and Paul Knochel

Angewandte Chemie, 2013, 125, 10278
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Alkenyl Magnesium Compounds: Generation and Synthetic Application

Miaomiao Zhu, Liang Liu, Hai‐Tao Yu, Wen‐Xiong Zhang and Zhenfeng Xi

Chemistry A European J, 2018, 24, 19122
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