Issue 1, 2011

A bimetallic iron(iii) catalyst for CO2/epoxide coupling

Abstract

A novel di-iron(III) catalyst for the copolymerisation of cyclohexene oxide and CO2 to yield poly(cyclohexene carbonate), under mild conditions, is reported. The catalyst selectivity was completely changed on addition of an ammonium co-catalyst to yield only the cis-isomer of the cyclic carbonate, also under mild conditions. Additionally, the catalyst was active for propylene carbonate and styrene carbonate production at 1 atm pressure.

Graphical abstract: A bimetallic iron(iii) catalyst for CO2/epoxide coupling

Supplementary files

Article information

Article type
Communication
Submitted
29 kesä 2010
Accepted
07 syys 2010
First published
27 syys 2010

Chem. Commun., 2011,47, 212-214

A bimetallic iron(III) catalyst for CO2/epoxide coupling

A. Buchard, M. R. Kember, K. G. Sandeman and C. K. Williams, Chem. Commun., 2011, 47, 212 DOI: 10.1039/C0CC02205E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements