Issue 36, 2019

Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

Abstract

A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael adducts with acceptable to high enantioselectivities (up to 97% ee) and very high yields (up to 96%).

Graphical abstract: Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

Supplementary files

Article information

Article type
Paper
Submitted
23 huhti 2019
Accepted
23 touko 2019
First published
05 heinä 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 21063-21069

Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

H. N. Genc, RSC Adv., 2019, 9, 21063 DOI: 10.1039/C9RA03029H

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