Issue 28, 2015

First copper(ii) phase M 0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

Abstract

M0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(II) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.

Graphical abstract: First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

Supplementary files

Article information

Article type
Communication
Submitted
23 huhti 2015
Accepted
04 kesä 2015
First published
04 kesä 2015

Dalton Trans., 2015,44, 12493-12496

Author version available

First copper(II) phase M0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

P. Fuentealba, C. Cortés, N. Audebrand, E. Le Fur, V. Paredes-García, D. Venegas-Yazigi, J. Manzur and E. Spodine, Dalton Trans., 2015, 44, 12493 DOI: 10.1039/C5DT01540E

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