Issue 22, 2014

Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(ii)–OOH species and a copper mediated NO reductive coupling reaction

Abstract

New peroxynitrite–copper chemistry ensues via addition of nitric oxide (˙NO(g)) to a CuII–hydroperoxo species. In characterizing the system, the ligand–Cu(I) complex was shown to effect a seldom observed ˙NO(g) reductive coupling reaction. Biological implications are discussed.

Graphical abstract: Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(ii)–OOH species and a copper mediated NO reductive coupling reaction

Supplementary files

Article information

Article type
Communication
Submitted
15 loka 2013
Accepted
27 marras 2013
First published
09 joulu 2013

Chem. Commun., 2014,50, 2844-2846

Author version available

Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)–OOH species and a copper mediated NO reductive coupling reaction

S. Kim, M. A. Siegler and K. D. Karlin, Chem. Commun., 2014, 50, 2844 DOI: 10.1039/C3CC47942K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements