Novel mono- and dimolybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand are prepared and characterized by X-ray analyses. These complexes afford a stoichiometric amount of ammonia by treatment with sulfuric acid at room temperature.
Y. Tanabe, S. Kuriyama, K. Arashiba, Y. Miyake, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2013, 49, 9290 DOI: 10.1039/C3CC45228J
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