Issue 9, 2022

Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC)

Abstract

Although the heterogeneous reactions of toluene significantly affect the atmospheric environment, less attention has been paid to the effects of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC) on nanoparticles. In this study, combined effects on the heterogeneous reactions of toluene/NO2/O3 on α-Fe2O3 nanoparticles were investigated by using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The results show that the addition of O3 to the toluene/NO2 reaction system can promote the formation processes of NOC. More toluene radicals can be formed and oxidized by the reactive oxidant species to form benzyl nitrate on the particle surface. In addition, simulated light illumination can enhance the heterogeneous conversion of toluene to NOC which may be due to the excitation effect of the photoactive properties of α-Fe2O3 and the intermediate product. However, increasing the relative humidity (RH) is unfavorable for NOC formation as a result of competitive effects on reactive sites and reduction of the formation of oligomers. These findings improve the understanding of combined effects on atmospheric NOC formation during the heterogeneous processes of toluene.

Graphical abstract: Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC)

Supplementary files

Article information

Article type
Paper
Submitted
03 touko 2022
Accepted
07 heinä 2022
First published
12 heinä 2022

Environ. Sci.: Nano, 2022,9, 3318-3330

Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC)

X. He, Z. Ma, X. Xi, A. Kudesi and J. Wang, Environ. Sci.: Nano, 2022, 9, 3318 DOI: 10.1039/D2EN00426G

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