Issue 30, 2015
From the journal:

Journal of Materials Chemistry C

A heterospin pressure sensor†

Kseniya Yu. Maryunina,a   Xiao Zhang,a   Sadafumi Nishihara,a   Katsuya Inoue,*a   Vitaly A. Morozov,b   Galina V. Romanenkob  and  Victor I. Ovcharenko*b  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Center for Chiral Science and Institute for Advanced Materials Research, Hiroshima University, 1-3-1, Kogamiyama, Higashi-Hiroshima, Japan
E-mail: kxi@hiroshima-u.ac.jp

b International Tomography Center SB RAS, Institutskaya 3a, Novosibirsk, Russia
E-mail: Victor.Ovcharenko@tomo.nsc.ru

Abstract

The effect of external pressure on the magnetic properties was studied for the first time for heterospin crystals based on the Cu(II) complex with nitroxide [Cu(hfac)2NN-PzMe], which exhibits a spin-crossover-like phenomenon. An increase in the hydrostatic pressure to 0.14 GPa caused a significant shift of the magnetic anomaly temperature (from 150 K to 300 K). This complex actually functions as a highly sensitive external pressure sensor.

Graphical abstract: A heterospin pressure sensor

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Article information

DOI
https://doi.org/10.1039/C5TC01005E
Article type
Communication
Submitted
10 huhti 2015
Accepted
14 touko 2015
First published
14 touko 2015

J. Mater. Chem. C, 2015,3, 7788-7791

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A heterospin pressure sensor

K. Yu. Maryunina, X. Zhang, S. Nishihara, K. Inoue, V. A. Morozov, G. V. Romanenko and V. I. Ovcharenko, J. Mater. Chem. C, 2015, 3, 7788 DOI: 10.1039/C5TC01005E

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