Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

Jonathan W. Dube; Zachary D. Brown; Christine A. Caputo; Philip P. Power; Paul J. Ragogna

doi:10.1039/C3CC48933G

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Activation of gaseous PH₃ with low coordinate diaryltetrylene compounds†

Jonathan W. Dube,^a Zachary D. Brown,^b Christine A. Caputo,^b Philip P. Power^b and Paul J. Ragogna*^a

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* Corresponding authors

^a Department of Chemistry and Center for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, 1151 Richmond St., London, Ontario, Canada
E-mail: pragogna@uwo.ca

^b Department of Chemistry, The University of California, 1 Shields Ave, Davis, California, USA

Abstract

The reaction of phosphine gas with a low coordinate diaryl germylene or diarylstannylene results in both oxidative addition and arene elimination at the group 14 atom. The products were characterised by ³¹P NMR spectroscopy and X-ray crystallography, and represent the first P–H bond activation by a heavy group 14 element compound.

This article is part of the themed collection: Metal-Mediated Transformations of Small Molecules

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Article information

DOI: https://doi.org/10.1039/C3CC48933G
Article type: Communication
Submitted: 22 marras 2013
Accepted: 09 joulu 2013
First published: 09 joulu 2013

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Chem. Commun., 2014,50, 1944-1946

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Activation of gaseous PH₃ with low coordinate diaryltetrylene compounds

J. W. Dube, Z. D. Brown, C. A. Caputo, P. P. Power and P. J. Ragogna, Chem. Commun., 2014, 50, 1944 DOI: 10.1039/C3CC48933G

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