Themed collection HOT articles from Environmental Science: Processes & Impacts

47 items
Accepted Manuscript - Paper

Comprehensive comparison of sampling methods for evaluating hexamethylene diisocyanate (HDI) in the air of an automotive collision repair facility

Paper

Flow imaging microscopy-based method for rapid, high-throughput measurement of fiber count and length distributions in air

Discrepancies between Flow Imaging Microscopy (FIM) and Phase Contrast Microscopy (PCM) decrease as fiber counts increase, underscoring the value of FIM's high-throughput measurement capability.

Graphical abstract: Flow imaging microscopy-based method for rapid, high-throughput measurement of fiber count and length distributions in air
Paper

Surfaces, silica and semivolatile organics—limonene uptake and desorption indoors and outdoors

The uptake and desorption of organics on silica surfaces is important in both outdoor and indoor environments.

Graphical abstract: Surfaces, silica and semivolatile organics—limonene uptake and desorption indoors and outdoors
Paper

Machine learning prediction of DOC–water partitioning coefficients for organic pollutants from diverse DOM origins

Machine learning modeling provides an effective tool for assessing the partitioning of organic pollutants in dissolved organic matter of various origins.

Graphical abstract: Machine learning prediction of DOC–water partitioning coefficients for organic pollutants from diverse DOM origins
Paper

Co-occurrence of microbial source tracking markers and antibiotic resistance genes in Chishui River, China

Fecal contamination is an important source for the emergence of antibiotic resistance genes (ARGs) worldwide.

Graphical abstract: Co-occurrence of microbial source tracking markers and antibiotic resistance genes in Chishui River, China
Open Access Paper

Spontaneous aqueous defluorination of trifluoromethylphenols: substituent effects and revisiting the mechanism

While trifluoromethylphenols (TFMPs) are environmental contaminants that can be precursors to the persistent trifluoroacetic acid, this study demonstrates that certain TFMPs can undergo complete hydrolytic defluorination in aqueous solutions.

Graphical abstract: Spontaneous aqueous defluorination of trifluoromethylphenols: substituent effects and revisiting the mechanism
Paper

Comparative cytotoxicity and toxicological mechanisms of 6:2 Cl-PFAES and PFOS in pancreatic β cells: implications for glucose metabolism disruption

This study found that 6:2 Cl-PFAES is more toxic than PFOS toward pancreatic β cells, inducing oxidative stress, apoptosis, and diabetes-related gene alterations, disrupting glucose metabolism.

Graphical abstract: Comparative cytotoxicity and toxicological mechanisms of 6:2 Cl-PFAES and PFOS in pancreatic β cells: implications for glucose metabolism disruption
Open Access Paper

PFAS drinking water treatment trade-offs: comparing the health burden of GAC treatment to the health benefits of reduced PFAS exposure

This study quantifies and compares the health benefits of lower PFAS exposure via drinking water to the health burden of more frequent GAC regeneration.

Graphical abstract: PFAS drinking water treatment trade-offs: comparing the health burden of GAC treatment to the health benefits of reduced PFAS exposure
Open Access Paper

Sulfur depletion through repetitive redox cycling unmasks the role of the cryptic sulfur cycle for (methyl)thioarsenate formation in paddy soils

The reduced sulfur required for arsenic thiolation in paddy soils comes mainly from the reduction of the soil's sulfate content. Here we show how the cryptic sulfur cycle offers a secondary sulfate pool, influencing thioarsenate biogeochemistry.

Graphical abstract: Sulfur depletion through repetitive redox cycling unmasks the role of the cryptic sulfur cycle for (methyl)thioarsenate formation in paddy soils
Paper

Study on the mechanism of Phoslock's impact on nitrogen migration at the sediment–water interface

Phoslock slowed down NO3–N consumption and increased NH4+–N concentration in the overlying water. It accelerated the migration of bioavailable NO3–N from overlying water to sediment and slowed down the release of bioavailable NH4+–N from sediment.

Graphical abstract: Study on the mechanism of Phoslock's impact on nitrogen migration at the sediment–water interface
Open Access Paper

Quantifying ambient concentration and emission profile of D5-siloxane of a residential neighborhood in the Greater Houston area

This study measures real-time concentrations of D5-siloxane, a VCP emitted from personal care products, in a residential area in Houston, Texas. Concentrations were then implemented into a box model in order to estimate per-person per-day emissions.

Graphical abstract: Quantifying ambient concentration and emission profile of D5-siloxane of a residential neighborhood in the Greater Houston area
Open Access Paper

Are ingredients of personal care products likely to undergo long-range transport to remote regions?

Ingredients from personal care products were found in Greenland snow, with higher levels tied to air masses from northern Europe and Russia. The study also assessed partitioning properties, phase distribution, and potential for long-range transport.

Graphical abstract: Are ingredients of personal care products likely to undergo long-range transport to remote regions?
Paper

Hybrid intelligence for environmental pollution: biodegradability assessment of organic compounds through multimodal integration of graph attention networks and QSAR models

Assessing the biodegradability of organic compounds is essential for reducing their environmental impact, ensuring regulatory compliance, promoting sustainable development and supporting effective pollution remediation.

Graphical abstract: Hybrid intelligence for environmental pollution: biodegradability assessment of organic compounds through multimodal integration of graph attention networks and QSAR models
Paper

Associations of individual and mixtures of organophosphate pesticides with the risk of osteoporosis in adult population

This work provides an assessment of the effects of organophosphorus pesticide exposure on osteoporosis and bone mineral density in adults.

Graphical abstract: Associations of individual and mixtures of organophosphate pesticides with the risk of osteoporosis in adult population
Open Access Paper

Sorption kinetics of metallic and organic contaminants on micro- and nanoplastics: remarkable dependence of the intraparticulate contaminant diffusion coefficient on the particle size and potential role of polymer crystallinity

We developed a mechanistic diffusion model to describe the sorption kinetics of metallic and organic contaminants on nano- and micro-plastics.

Graphical abstract: Sorption kinetics of metallic and organic contaminants on micro- and nanoplastics: remarkable dependence of the intraparticulate contaminant diffusion coefficient on the particle size and potential role of polymer crystallinity
Paper

Spatiotemporal distribution characteristics of physicochemical properties of waste plastics with different landfill age and depth

Plastics are widely used for their excellent properties, and the primary disposal method is sanitary landfilling.

Graphical abstract: Spatiotemporal distribution characteristics of physicochemical properties of waste plastics with different landfill age and depth
Paper

In situ remediation of eutrophic Wolong Lake sediments using novel PVA-SA-biochar and PVA-SA-zeolite embedded immobilized indigenous microorganisms: a pilot study

Sediment restoration has become a key link in river and lake pollution control.

Graphical abstract: In situ remediation of eutrophic Wolong Lake sediments using novel PVA-SA-biochar and PVA-SA-zeolite embedded immobilized indigenous microorganisms: a pilot study
Paper

Reversible and irreversible retention of heavy metals in saturated porous media: association with kaolin

Competitive adsorption and cation exchange are critical processes for the reversible and irreversible interactions of heavy metals with environmental media.

Graphical abstract: Reversible and irreversible retention of heavy metals in saturated porous media: association with kaolin
Open Access Paper

The INGENIOUS project: towards understanding air pollution in homes

This paper provides an overview of the INGENIOUS (UnderstandING the sourcEs, traNsformations and fates of IndOor air pollUtantS) project, aiming to better understand air pollution in homes.

Graphical abstract: The INGENIOUS project: towards understanding air pollution in homes
Paper

Dissolved phosphorous through dry–wet–dry transitions in a small-dammed river basin: integrated understanding on transport patterns, export controls, and fate

The connections between terrestrial DP sources and aquatic DP sinks were comprehended in a small-dammed watershed through an integrated understanding of DP transport patterns, export controls, and their fate over dry–wet–dry transitions.

Graphical abstract: Dissolved phosphorous through dry–wet–dry transitions in a small-dammed river basin: integrated understanding on transport patterns, export controls, and fate
Open Access Paper

Chemical characterization of polymer and chloride content in waste plastic materials using pyrolysis – direct analysis in real time – high-resolution mass spectrometry

This study presents an application of TPD-DART-HRMS for plastic, enabling rapid characterization of waste through Kendrick grouping and Tanimoto comparison.

Graphical abstract: Chemical characterization of polymer and chloride content in waste plastic materials using pyrolysis – direct analysis in real time – high-resolution mass spectrometry
Paper

Associations of coke oven emission exposure with pulmonary function, blood pressure, blood cell parameters, and biochemical indices in coking workers: a cross-sectional pilot study

The study clearly showed that PAH exposure could damage hematological parameters and blood lipids, and benzene exposure could increase blood pressure, and decrease PLT count.

Graphical abstract: Associations of coke oven emission exposure with pulmonary function, blood pressure, blood cell parameters, and biochemical indices in coking workers: a cross-sectional pilot study
Paper

Fluorinated aromatic PBCTF and 6:2 diPAP in bridge and traffic paints

This study takes a multifaceted approach toward characterizing total fluorine and per- and polyfluoroalkyl substances (PFAS) in traffic and bridge paints.

Graphical abstract: Fluorinated aromatic PBCTF and 6:2 diPAP in bridge and traffic paints
Open Access Paper

Mobile monitoring reveals the importance of non-vehicular particulate matter sources in London

A novel application of mobile monitoring to investigate the spatial distribution of vehicular and non-vehicular urban particulate matter sources in London, UK.

Graphical abstract: Mobile monitoring reveals the importance of non-vehicular particulate matter sources in London
Paper

Associations of indoor airborne microbiome with lung function: evidence from a randomized, double-blind, crossover study of microbial intervention

Indoor airborne microbiome contributes to human lung function and can be modified by air purification.

Graphical abstract: Associations of indoor airborne microbiome with lung function: evidence from a randomized, double-blind, crossover study of microbial intervention
Open Access Paper

Physicochemical properties and their impact on ice nucleation efficiency of respiratory viral RNA and proteins

Ice nucleation processes in the earth's atmosphere are critical for cloud formation, radiation, precipitation, and climate change.

Graphical abstract: Physicochemical properties and their impact on ice nucleation efficiency of respiratory viral RNA and proteins
Open Access Paper

Improved prediction of PFAS partitioning with PPLFERs and QSPRs

Per- and polyfluoroalkyl substances (PFAS) are chemicals of high concern and are undergoing hazard and risk assessment worldwide.

Graphical abstract: Improved prediction of PFAS partitioning with PPLFERs and QSPRs
Paper

Formation of atmospheric molecular clusters containing nitric acid with ammonia, methylamine, and dimethylamine

This study investigates the formation of atmospheric molecular clusters containing ammonia (NH3, A), methylamine (CH3NH2, MA), or dimethylamine (CH3NHCH3, DMA) with nitric acid (HNO3, NA) using quantum mechanics.

Graphical abstract: Formation of atmospheric molecular clusters containing nitric acid with ammonia, methylamine, and dimethylamine
Open Access Paper

Modeling of mercury deposition in India: evaluating emission inventories and anthropogenic impacts

Fragile ecosystems (Western Ghats and Himalayas), and major rice cultivation areas are vulnerable to highest Hg deposition. Indian anthropogenic emissions strongly influence deposition fluxes with varying regional impacts.

Graphical abstract: Modeling of mercury deposition in India: evaluating emission inventories and anthropogenic impacts
Paper

A 150 years record of polycyclic aromatic compounds in the Sihailongwan Maar Lake, Northeast China: impacts of socio-economic developments and pollution control

The geochemical composition of sediment cores can serve as a proxy for reconstructing past human and nature-driven environmental and climatic changes.

Graphical abstract: A 150 years record of polycyclic aromatic compounds in the Sihailongwan Maar Lake, Northeast China: impacts of socio-economic developments and pollution control
Open Access Paper

Emerging investigator series: in-depth chemical profiling of tire and artificial turf crumb rubber: aging, transformation products, and transport pathways

Chemical profiling of artificial turf crumb rubber reveals time-based trends in transformation products and transport pathways.

Graphical abstract: Emerging investigator series: in-depth chemical profiling of tire and artificial turf crumb rubber: aging, transformation products, and transport pathways
Paper

Identifying initial transformation products during chlorination of the indole moiety and unveiling their formation mechanisms

Initial transformation products and their formation mechanisms in the chlorination of the indole moiety in tryptophan (Trp) are investigated using a quantum chemical computational method.

Graphical abstract: Identifying initial transformation products during chlorination of the indole moiety and unveiling their formation mechanisms
Paper

Photodegradation of the main synthetic musk (HHCB) in water: kinetic study and influencing factors

Galaxolide (HHCB) is the most common synthetic musk compound detected in numerous daily products.

Graphical abstract: Photodegradation of the main synthetic musk (HHCB) in water: kinetic study and influencing factors
Open Access Paper

Development of a sampling protocol for collecting leaf surface material for multiphase chemistry studies

We describe a robust and flexible protocol to collect water-soluble chemicals from leaf surfaces for atmosphere-biosphere interaction studies.

Graphical abstract: Development of a sampling protocol for collecting leaf surface material for multiphase chemistry studies
Paper

Potential effects of soil petroleum contamination on decomposition of Artemisia annua plant litter

Artemisia annua litter produced in soil contaminated with 15 and 30 g kg−1 of petroleum exhibited significantly lower decomposition rates than that from uncontaminated soil.

Graphical abstract: Potential effects of soil petroleum contamination on decomposition of Artemisia annua plant litter
Open Access Paper

An uneven distribution of strontium in the coccolithophore Scyphosphaera apsteinii revealed by nanoscale X-ray fluorescence tomography

Coccolithophores are biogeochemically and ecologically important phytoplankton that produce calcium carbonate scales, or coccoliths. Here, we show that one species of coccolithophore grows coccoliths with uneven distribution of Sr, in contrast to current fractionation model theory.

Graphical abstract: An uneven distribution of strontium in the coccolithophore Scyphosphaera apsteinii revealed by nanoscale X-ray fluorescence tomography
Paper

Co-culture of benzalkonium chloride promotes the biofilm formation and decreases the antibiotic susceptibility of a Pseudomonas aeruginosa strain

The physiological and biochemical behaviors of Pseudomonas aeruginosa were modulated using benzalkonium chloride, potentially through the attenuation of the quorum sensing system.

Graphical abstract: Co-culture of benzalkonium chloride promotes the biofilm formation and decreases the antibiotic susceptibility of a Pseudomonas aeruginosa strain
Open Access Paper

Characteristics and adsorption behavior of typical microplastics in long-term accelerated weathering simulation

Adsorption of different organic pollutants by three microplastics before and after weathering.

Graphical abstract: Characteristics and adsorption behavior of typical microplastics in long-term accelerated weathering simulation
Paper

The first report on the assessment of maximum acceptable daily intake (MADI) of pesticides for humans using intelligent consensus predictions

Direct or indirect consumption of pesticides and their related products by humans and other living organisms without safe dosing may pose a health risk.

Graphical abstract: The first report on the assessment of maximum acceptable daily intake (MADI) of pesticides for humans using intelligent consensus predictions
Paper

Co-exposure to tire wear particles and nickel inhibits mung bean yield by reducing nutrient uptake

Tire wear particles and nickel have detrimental effects on plant health by causing blockage and altering nutrient hemotasis, ultimately reducing plant yield.

Graphical abstract: Co-exposure to tire wear particles and nickel inhibits mung bean yield by reducing nutrient uptake
Paper

Experimental factors influencing the bioaccessibility and the oxidative potential of transition metals from welding fumes

Experimental conditions such as extraction methods and storage conditions induce biases on the measurement of the oxidative potential and the bioaccessibility of transition metals from welding fumes.

Graphical abstract: Experimental factors influencing the bioaccessibility and the oxidative potential of transition metals from welding fumes
Open Access Paper

Experimental determination of the partitioning of representative organic pollutants to the air–water interface

Glancing-angle laser-induced fluorescence is used to obtain adsorption isotherms of organic pollutants at the air–water interface.

Graphical abstract: Experimental determination of the partitioning of representative organic pollutants to the air–water interface
Open Access Paper

Speeding it up: dual effects of biostimulants and iron on the biodegradation of poly(lactic acid) at mesophilic conditions

Biodegradation of poly(lactic acid) (PLA) in compost environment enriched with iron, and gelatin significantly enhanced microbial enzymatic activity, thus accelerating PLA degradation at mesophilic conditions (home/backyard composting setting).

Graphical abstract: Speeding it up: dual effects of biostimulants and iron on the biodegradation of poly(lactic acid) at mesophilic conditions
Open Access Paper

Atmospheric mercury uptake and accumulation in forests dependent on climatic factors

The uptake of total gaseous mercury (TGM) by Korean forest foliage is mainly affected by local wind speed, boosting its passage and absorption. Mercury levels and isotopic signatures in litter and topsoil fluctuate, particularly in areas with high wind speed, temperature, and low elevation.

Graphical abstract: Atmospheric mercury uptake and accumulation in forests dependent on climatic factors
Open Access Paper

Characterization and dermal bioaccessibility of residual- and listed PFAS ingredients in cosmetic products

Estimation of dermal bioaccessibility and characterization of listed-ingredient and residual per- and polyfluoroalkyl substances (PFAS) in cosmetic products.

Graphical abstract: Characterization and dermal bioaccessibility of residual- and listed PFAS ingredients in cosmetic products
Paper

Effects of carbonate on ferrihydrite transformation in alkaline media

This study indicates that in alkaline media, carbonate slightly inhibits ferrihydrite transformation and suppresses goethite formation, but promotes hematite formation, which has important implications for elemental biogeochemical cycles.

Graphical abstract: Effects of carbonate on ferrihydrite transformation in alkaline media
Open Access Paper

Emission inventory of PFASs and other fluorinated organic substances for the fluoropolymer production industry in Europe

This study assesses the environmental impact of the fluoropolymer industry in Europe by making an inventory of their emissions of PFASs and other fluorinated organic substances.

Graphical abstract: Emission inventory of PFASs and other fluorinated organic substances for the fluoropolymer production industry in Europe
47 items

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