Themed collection HOT articles from Environmental Science: Atmospheres

27 items
Open Access Critical Review

Atmospheric chemistry of halogenated OVOCs: a review of rate coefficients, dielectric strength, and environmental impact

This study assesses the atmospheric fate and environmental consequences of distributed XOVOC emissions.

Graphical abstract: Atmospheric chemistry of halogenated OVOCs: a review of rate coefficients, dielectric strength, and environmental impact
Open Access Critical Review

Enhancing DTT assays for reactive oxygen species detection in atmospheric particulate matter: key factors and methodological insights

Accurate detection of reactive oxygen species (ROS) in particulate matter (PM) is essential for assessing the oxidative potential (OP) of airborne pollutants and their associated health risks.

Graphical abstract: Enhancing DTT assays for reactive oxygen species detection in atmospheric particulate matter: key factors and methodological insights
Open Access Critical Review

Carbon monoxide as an indicator of indoor air quality

Carbon monoxide is a priority pollutant that is suitable as an indicator for assessing indoor air quality. Monitoring should preferably be embedded in an intelligent network of different sensors.

Graphical abstract: Carbon monoxide as an indicator of indoor air quality
Open Access Paper

Idealized modeling of stratospheric aerosol injection deployment scenarios with two non-cooperative actors

Solar radiation management scenarios of two non-cooperative actors deploying stratospheric aerosol injection (SAI) can lead to a free-riding situation, or missing the climatic targets due to temperature oscillations induced by intermittency.

Graphical abstract: Idealized modeling of stratospheric aerosol injection deployment scenarios with two non-cooperative actors
Open Access Paper

Diaterpenylic acid acetate (DTAA): characterization and OH oxidation in atmospheric chambers

DTAA can be viewed as a model later-generation product of monoterpene ozonolysis, a major source of secondary organic aerosol. This paper shows that DTAA is semivolatile and continues reacting with OH, producing even later-generation products.

Graphical abstract: Diaterpenylic acid acetate (DTAA): characterization and OH oxidation in atmospheric chambers
Open Access Paper

Atmospheric brown carbon from biofuel pyrolysis: comparative analysis of dung and wood sources

Chemical and optical analyses of brown carbon (BrC) aerosol components indicate that dung-derived and wood-derived emissions are comprised of nitrogen-containing and oxygen-containing chromophores, respectively.

Graphical abstract: Atmospheric brown carbon from biofuel pyrolysis: comparative analysis of dung and wood sources
Open Access Paper

Revealing discrepancies in potential driving factors of particulate-bound mercury between urban and suburban sites in a Southeast Asian megacity using a generalized additive model

First study highlights the applicability of the generalized additive model in source characterization and provides critical implications for air quality management and mercury mitigation strategies tailored to urban and suburban settings.

Graphical abstract: Revealing discrepancies in potential driving factors of particulate-bound mercury between urban and suburban sites in a Southeast Asian megacity using a generalized additive model
Open Access Paper

Impact of mixing states on aerosol radiative effects and feedback during winter haze episodes over the North China Plain

There are large differences in the aerosol direct radiative effect (DRE) and radiative feedback-induced changes in PM2.5 across various aerosol mixing states (external, Maxwell-Garnett, core–shell, homogeneous) during haze episodes in NCP of China.

Graphical abstract: Impact of mixing states on aerosol radiative effects and feedback during winter haze episodes over the North China Plain
Open Access Paper

Sensitivity to meteorology of regional contributions to air pollution in eastern Canada: part 1: ozone and NOX

We create emulators to capture the effects of changes in weather on O3 and NOX in eastern Canada. Climate change is projected to increase the US contribution to O3 concentrations in eastern Canada more than the Canadian and Quebec contributions.

Graphical abstract: Sensitivity to meteorology of regional contributions to air pollution in eastern Canada: part 1: ozone and NOX
Open Access Paper

Localized pollutant emission increases in China due to COVID-19 lockdowns

Satellite observations reveal unexpected NOx emission hotspots along supply routes and in suburban areas during China's COVID-19 lockdown, demonstrating the value of high-resolution atmospheric monitoring for tracking human activities during crises.

Graphical abstract: Localized pollutant emission increases in China due to COVID-19 lockdowns
Open Access Paper

Accretion product formation in the self- and cross-reactions of small β-hydroxy peroxy radicals

In this work, we observe the formation of accretion products in the self- and cross-reactions of several hydroxy peroxy radicals.

Graphical abstract: Accretion product formation in the self- and cross-reactions of small β-hydroxy peroxy radicals
Open Access Paper

Impact of particle phase state on the competition between condensation and coagulation

The evolution of particle size distribution of secondary organic aerosols (SOAs) is influenced by condensation and coagulation.

Graphical abstract: Impact of particle phase state on the competition between condensation and coagulation
Open Access Paper

Assessing pH- and temperature-dependence in the aqueous phase partitioning of organic acids and bases in the atmosphere

In an increasingly NHx-dominated aqueous regime, changing particle and cloud droplet acidity impacts the partitioning behavior of ionizable organic compounds.

Graphical abstract: Assessing pH- and temperature-dependence in the aqueous phase partitioning of organic acids and bases in the atmosphere
Open Access Paper

Investigating the role of anthropogenic terpenoids in urban secondary pollution under summer conditions by a box modeling approach

This modeling study shows that in an urban environment, the SOA production through oxidation of terpenoids emitted from anthropogenic sources is competitive with that induced by their biogenic sources.

Graphical abstract: Investigating the role of anthropogenic terpenoids in urban secondary pollution under summer conditions by a box modeling approach
Open Access Paper

Salting out and nitrogen effects on cloud-nucleating ability of amino acid aerosol mixtures

We investigate the water uptake ability of amino acid ternary mixtures.

Graphical abstract: Salting out and nitrogen effects on cloud-nucleating ability of amino acid aerosol mixtures
Open Access Paper

Laboratory development and validation of vapor phase PFAS methods for soil gas, sewer gas, and indoor air

A thermal desorption GC-tandem MS method was developed to measure vapor-phase PFAS and their potential migration into indoor air.

Graphical abstract: Laboratory development and validation of vapor phase PFAS methods for soil gas, sewer gas, and indoor air
Open Access Paper

Low temperature growth of sub 10 nm particles by ammonium nitrate condensation

Ammonium nitrate will condense to tiny particles under sub-zero conditions, activating well below 10 nm.

Graphical abstract: Low temperature growth of sub 10 nm particles by ammonium nitrate condensation
Open Access Paper

Probe molecular diffusivity in single ternary inorganic–organic microdroplets via interfacial ozonolysis of thiosulfate

The aqueous sodium thiosulfate microdroplets mixed with glucose or sucrose are used as model system of ternary inorganic–organic aerosols, and the RH-dependent diffusivity of thiosulfate in such system is probed via its interfacial ozonolysis.

Graphical abstract: Probe molecular diffusivity in single ternary inorganic–organic microdroplets via interfacial ozonolysis of thiosulfate
Open Access Paper

O3 chemistry of 2,5-dimethylfuran: mechanism development

O3 chemistry of substituted furans might contribute to acidity in nighttime biomass burning plumes.

Graphical abstract: O3 chemistry of 2,5-dimethylfuran: mechanism development
Open Access Paper

Fine particulate air pollution estimation in Ouagadougou using satellite aerosol optical depth and meteorological parameters

Framework for analysis of PM2.5 estimates.

Graphical abstract: Fine particulate air pollution estimation in Ouagadougou using satellite aerosol optical depth and meteorological parameters
Open Access Paper

Spatial and seasonal dynamics of gaseous elemental mercury concentrations over Switzerland observed by a passive air sampler network

Monitoring of gaseous elemental mercury (Hg0) using passive air samplers at 22 sites across Switzerland informs about actual mean national Hg0 concentrations, differences in Hg0 among rural and urban sites and its seasonal dynamics.

Graphical abstract: Spatial and seasonal dynamics of gaseous elemental mercury concentrations over Switzerland observed by a passive air sampler network
Open Access Paper

Study of heterogeneous chemistry and photochemistry of single sea-spray aerosols containing Hg(II) in air using optical trapping – Raman spectroscopy

The heterogeneous chemical reaction happens on the surface of the optically suspended sea-spray aerosol particle and is monitored via the single-particle Raman spectroscopy.

Graphical abstract: Study of heterogeneous chemistry and photochemistry of single sea-spray aerosols containing Hg(ii) in air using optical trapping – Raman spectroscopy
Open Access Paper

Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales

Near-explicit chemical mechanisms representing toluene SOA formation are reduced using the GENOA algorithm and used in 3D simulations of air quality over Greater Paris and in the streets of a district near Paris.

Graphical abstract: Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales
Open Access Paper

Quantifying the dominant sources influencing the 2016 particulate matter pollution episode over northern India

Contribution of anthropogenic, biomass-burning and natural sources to the spatiotemporal extent of the episode across northern India.

Graphical abstract: Quantifying the dominant sources influencing the 2016 particulate matter pollution episode over northern India
Open Access Paper

Heterogeneous ozonolysis of alkyl substituted-polycyclic aromatic hydrocarbons (AlkPAHs) in the atmosphere

Heterogeneous oxidation of alkylated polycyclic aromatic hydrocarbons (alkPAHs) by ozone is more rapid than their parent analogs (PAHs) and can produce a large variety of potentially toxic oxidation products.

Graphical abstract: Heterogeneous ozonolysis of alkyl substituted-polycyclic aromatic hydrocarbons (AlkPAHs) in the atmosphere
Open Access Paper

Antimicrobial activity of safe concentrations of ozone, hydrogen peroxide, and triethylene glycol in air and surfaces

The application of low and non-toxic concentrations of antimicrobial compounds in indoor air is an interesting strategy to reduce airborne bacteria and fungi thereby reducing infection risk.

Graphical abstract: Antimicrobial activity of safe concentrations of ozone, hydrogen peroxide, and triethylene glycol in air and surfaces
Open Access Paper

Temperature, humidity, and ionisation effect of iodine oxoacid nucleation

Raising the ionisation rate (IR) increases the ion concentration, but also amplifies ion losses due to ion–ion recombination, consequently diminishing the formation rate of charged clusters at low HIO3 concentrations.

Graphical abstract: Temperature, humidity, and ionisation effect of iodine oxoacid nucleation
27 items

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