New reactivity of late 3d transition metal complexes in catalytic reactions of alkynes

Shenghan Teng, Peiyao Liang and Jianrong Steve Zhou

Chem. Soc. Rev., 2025, 54, 2664
DOI: 10.1039/D4CS01130A

Tunable C–H functionalization and dearomatization enabled by an organic photocatalyst

Bohang An, Hao Cui, Chao Zheng, Ji-Lin Chen, Feng Lan, Shu-Li You and Xiao Zhang

Chem. Sci., 2024, 15, 4114
DOI: 10.1039/D4SC00120F

Photo-promoted radical cascade cyclization of 4-(allylamino)-3-cyanocoumarins: access to sulfonylated pyrido[3,2-c]coumarin derivatives

Luyao Yang, Jialuo Ying, Hao Zheng, Yuyan Xu, Liping Wu and Zhiwei Chen

Green Chem., 2025, 27, 3524
DOI: 10.1039/D4GC06598K

Beyond single pathways: synergistic SET–EnT pathways in visible-light photochemistry

Bao-Gui Cai, Qiang Wang, Jun Xuan and Wen-Jing Xiao

Chem. Soc. Rev., 2026
DOI: 10.1039/D6CS00112B

NHC and photoredox co-catalyzed 1,4-alkylcarbonylation of 1,3-enynes

Zhaoyang Zhang, Jia-Yi Yang, Shihao Li, Xiao-Xuan Li and Yi-Si Feng

Org. Chem. Front., 2025, 12, 3984
DOI: 10.1039/D4QO02311K

Synthetic methodologies to access skipped dienes: a focus on the catalytic systems

Polyssena Renzi, Alberto Lanfranco, Lucia Pazderová, Marco Rusconi, Jacopo Scarfiello and Annamaria Deagostino

Org. Biomol. Chem., 2025, 23, 6052
DOI: 10.1039/D5OB00646E

The stereo-divergent functionalization of alkynes: a comprehensive review

Ranjay Shaw, Ashmita Singh, Ismail Althagafi, Ramendra Pratap and Dharmendra Kumar Yadav

RSC Adv., 2025, 15, 12202
DOI: 10.1039/D5RA01579K

anti-Selective Carboacylation of Alkynes via Photoredox/Nickel Dual Catalysis

Xian-Hua Pan, Chang-Xin Shi, Ya-Ping Hou, Li-Fang Wang, Rui-Qi Niu and Lei Guo

Org. Lett., 2024, 26, 9498
DOI: 10.1021/acs.orglett.4c03439

Acetone Serving as a Solvent and Interaction Partner Promotes the Direct Olefination of N-Tosylhydrazones under Visible Light

Dingding Xia, Tong Li, Xin-Yan Ke, Jinxin Wang, Xin Luan, Shao-Fei Ni, Yu Zhang and Wei-Dong Zhang

J. Org. Chem., 2024, 89, 6180
DOI: 10.1021/acs.joc.4c00184

Synthesis of Hexafluoroisopropyl Aryl Ethers via Dual Photoredox/Nickel-Catalyzed C–O Coupling

Xu He, Yu-Yang Zhang, Jia-Yi Shou, Lingling Chu and Feng-Ling Qing

Org. Lett., 2024, 26, 6782
DOI: 10.1021/acs.orglett.4c02553

Divergent catalysis: elucidation of ligand-controlled chemo-divergent Pd-catalyzed intramolecular allene-silacyclobutane reactions

Sui-Fang Peng, Jia-Wei Si, Fei Ye, Li Li, Shuang-Li Liu, Zheng Xu, Fuk-Yee Kwong and Li-Wen Xu

Journal of Catalysis, 2025, 452, 116449
DOI: 10.1016/j.jcat.2025.116449

Kinetically controlled Z-alkene synthesis using iron-catalysed allene dialkylation

Tong-De Tan, Kai Ze Tee, Xiaohua Luo, Peng-Cheng Qian, Xinglong Zhang and Ming Joo Koh

Nat. Synth, 2024, 4, 116
DOI: 10.1038/s44160-024-00658-7

Radical Alkylcyanation of 1,6-Enynes with Isonitriles as Bifunctional Reagents

Zhonghou Huang, Jian Qin, Yuntong Hu, Shengqing Zhu and Lingling Chu

Org. Lett., 2024, 26, 10763
DOI: 10.1021/acs.orglett.4c03744

Recent Advances in Visible Light Induced Radical 1,2-Functionalization of Alkynes

Kangkui Li, Xianyang Long, Yue Huang and Shifa Zhu

Acta Chimica Sinica, 2024, 82, 658
DOI: 10.6023/A24030090

Cascade Hydrothiolation and Hydroamidation of Alkynes to Regioselectively Afford 1,2‐Disubstituted Alkane Derivatives under Photocatalysis

Rui Fu, Mengyu Xu, Yujing Wang and Xiaoguang Bao

Chin. J. Chem., 2026, 44, 462
DOI: 10.1002/cjoc.70380

Stereodivergent reductive C(sp2)-C(sp3) coupling between cycloketone oximes and vinyl halides enabled by tunable photoredox/Ti dual catalysis

Huai-Gui Li, Can-Ming Zhu, Weidong Yuan, Hongyi Chen, Zhengyuan Bo, Chao Deng, Yingguang Zhu, Kang Chen and Qing-Yuan Meng

Chinese Chemical Letters, 2025, 111941
DOI: 10.1016/j.cclet.2025.111941

Metal-Free Photoinduced Cascade Cyclization of Alkyne-Tethered N-Alkoxybenzamides

Ximei Tang, Chen Baoc, Guang Cheng, Yuling Liao, Wenlin Xie and Guanyinsheng Qiu

Synthesis, 2025, 57, 1499
DOI: 10.1055/a-2517-1556

Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction

Yumin Pan, Tingting Xie, Jiming Peng, Cuihui Cao and Bi-Qun Zou

Catal Lett, 2025, 155
DOI: 10.1007/s10562-024-04900-x