Hydrogenation of sulfoxides to sulfides mediated by incomplete cubane-type Mo3S4 clusters: synthetic applications and mechanistic insights

Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont and Rosa Llusar

Catal. Sci. Technol., 2024, 14, 6845
DOI: 10.1039/D4CY00987H

Unprecedented Mo3S4 cluster-catalyzed radical C–C cross-coupling reactions of aryl alkynes and acrylates

Juanjo Mateu-Campos, Eva Guillamón, Vicent S. Safont, Kathrin Junge, Henrik Junge, Matthias Beller and Rosa Llusar

Dalton Trans., 2024, 53, 4147
DOI: 10.1039/D3DT04121B

Renaissance in Alkyne Semihydrogenation: Mechanism, Selectivity, Functional Group Tolerance, and Applications in Organic Synthesis

Rafał Kusy and Karol Grela

Chem. Rev., 2025, 125, 4397
DOI: 10.1021/acs.chemrev.4c00001

Sulfur-Centered Mechanism in Catalytic Methanolysis of Hydrosilanes Mediated by Air-Stable Mo3S4 Clusters

Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Jordi Benet-Buchholz, Mónica Oliva and Rosa Llusar

Inorg. Chem., 2025, 64, 6552
DOI: 10.1021/acs.inorgchem.4c05438

Selective Dehydrogenation of Formic Acid Catalyzed by Air‐Stable Cuboidal PN Molybdenum Sulfide Clusters

María Gutiérrez‐Blanco, Carolin A. M. Stein, Carmina Alfonso, Eva Guillamón, Vicent S. Safont, Iván Sorribes, Henrik Junge, Matthias Beller and Rosa Llusar

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300740

Spin-Crossing in the (Z)-Selective Alkyne Semihydrogenation Mechanism Catalyzed by Mo3S4 Clusters: A Density Functional Theory Exploration

María Gutiérrez-Blanco, Andrés G. Algarra, Eva Guillamón, M. Jesús Fernández-Trujillo, Mónica Oliva, Manuel G. Basallote, Rosa Llusar and Vicent S. Safont

Inorg. Chem., 2024, 63, 1000
DOI: 10.1021/acs.inorgchem.3c03057

Z‐Selective Semihydrogenation of Internal Alkynes Catalyzed by Phenanthroline‐Based PNNP‐Fe(II) Complexes

Tao Wang, Yoshihito Kayaki, Hiroto Fujisaki, Hajime Kawanami, Yoshihiro Shimoyama, Masaru Yoshida and Yumiko Nakajima

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202500785

Proton Reduction with a Cobalt-Doped Thiomolybdate Cluster: A Structural and Functional Model of Co-Doped MoS2

Kamaless Patra, Leyla R. Valerio, Zhou Lu, Kaye Kuphal, William W. Brennessel and Ellen M. Matson

J. Am. Chem. Soc., 2025, 147, 38973
DOI: 10.1021/jacs.5c09888

Visible-Light-Driven (NSNO)Nickel complex catalyzed (Z)-Selective semi-hydrogenation of alkynes

Nuo Zhang, Yong-Bo Zhou, Fei Chen, Zhi-Hong Du, Chun-Bo Bo, Min Li and Ning Liu

Fuel, 2025, 383, 133844
DOI: 10.1016/j.fuel.2024.133844

Molecular Models of Layered Ternary Cu2MoS4 Reveal Sulfur-Based H2 Evolution Pathway

Lauren T. Feden, Shatha Alabbad, Manuraj Kallumkal, Jan-Niklas Boyn and Gwendolyn A. Bailey

J. Am. Chem. Soc., 2025, 147, 36686
DOI: 10.1021/jacs.5c12079