Sean F. McWilliams, Brandon Q. Mercado, K. Cory MacLeod, Majed S. Fataftah, Maxime Tarrago, Xiaoping Wang, Eckhard Bill, Shengfa Ye and Patrick L. Holland

Chem. Sci., 2023, 14, 2303
DOI: 10.1039/D2SC06412J

Fe-catalyzed Fukuyama-type indole synthesis triggered by hydrogen atom transfer

Tianze Zhang, Min Yu and Hanmin Huang

Chem. Sci., 2021, 12, 10501
DOI: 10.1039/D1SC03058B

Iron-catalyzed radical intermolecular addition of unactivated alkenes to alkenyl N-heteroarenes

Wen-Dao Chu, Chun-Mei Wang, Shu Li, Zhi-Hong Dong, Teng Long, Jia-Xi Jiang, Bo Chen, Cheng-Yu He and Quan-Zhong Liu

Org. Chem. Front., 2022, 9, 6973
DOI: 10.1039/D2QO01448C

Modern organic transformations: heterogeneous thermocatalysis or photocatalysis?

Ning Zhang, Wanbing Gong and Yujie Xiong

Chem. Soc. Rev., 2025, 54, 5189
DOI: 10.1039/D2CS00097K

Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines

Soniya Rani, Soumya Ranjan Dash, Asish Bera, Md Nirshad Alam, Kumar Vanka and Pradip Maity

Chem. Sci., 2021, 12, 8996
DOI: 10.1039/D1SC01217G

Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides

Mei-Hua Shen, Xiao-Wen Qi, De-Xia Li, Xin-Yi Wang, Chi-Fan Zhu and Hua-Dong Xu

Org. Chem. Front., 2023, 10, 3010
DOI: 10.1039/D3QO00431G

Photocatalytic Metal Hydride Hydrogen Atom Transfer Mediated Allene Functionalization by Cobalt and Titanium Dual Catalysis

Huaipu Yan, Qian Liao, Yuqing Chen, Gagik G. Gurzadyan, Binghui Lu, Chao Wu and Lei Shi

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202302483

Cyclization via Metal-Catalyzed Hydrogen Atom Transfer/Radical-Polar Crossover

Hiroki Shigehisa

Synlett, 2025, 36, 206
DOI: 10.1055/a-2337-2498

Tandem Oligomerization-Hydrogenation Using Brønsted Acidic Iridium Hydride Catalysts

Austin J. Leitgeb, Scott M. Chapp, Caleb D. Fast, Kathryn E. Fink and Nathan D. Schley

Organometallics, 2025, 44, 1499
DOI: 10.1021/acs.organomet.5c00160

Kombination von Wasserstoffatomtransfer und der Truce‐Smiles‐Umlagerung zur Synthese von β‐Arylethylaminen aus nicht aktivierten Allylsulfonamiden

Hanqi Zhou, Danijela Lunic, Nil Sanosa, Diego Sampedro, Ignacio Funes‐Ardoiz and Christopher J. Teskey

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202418869

Electrochemistry Unlocks New Possibilities in Unsaturated C–C Bond Functionalization

Seonyoung Kim, Ahhyeon Choi and Hyunwoo Kim

Acc. Chem. Res., 2026
DOI: 10.1021/acs.accounts.6c00223

Cobalt-catalyzed alkene hydrogenation by reductive turnover

Vincent van der Puyl, Ruairi O. McCourt and Ryan A. Shenvi

Tetrahedron Letters, 2021, 72, 153047
DOI: 10.1016/j.tetlet.2021.153047

Ligand Relay Cobalt Catalysis for Vicinal Si,O-Alkanes from Terminal Alkynes

Yufeng Sun, Bingcheng Wang, Linhong Long, Jin-Ang Lou, Hui Chen and Zhan Lu

ACS Catal., 2024, 14, 8405
DOI: 10.1021/acscatal.4c02438

Generation of α‐Boryl Radicals by H. Transfer and their Use in Cycloisomerizations

Shicheng Shi, Farbod Salahi, Hunter B. Vibbert, Maleeha Rahman, Scott A. Snyder and Jack R. Norton

Angew Chem Int Ed, 2021, 60, 22678
DOI: 10.1002/anie.202107665

Cost‐Effective Carbon Quaternization with Redox‐Active Esters and Olefins

Sudhir Kumar Hota and Sandip Murarka

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202408301

Radical Retrosynthesis of Natural Products Enabled by Iron‐Based Reductive Olefin Coupling

Griffin L. Barnes, Alex L. Rerick and Phil S. Baran

Angewandte Chemie Novit, 2026, 2
DOI: 10.1002/anov.70017

Nickel-Catalyzed Regio- and Enantioselective Hydroamination of Unactivated Alkenes Using Carbonyl Directing Groups

Changseok Lee, Hyung-Joon Kang, Huiyeong Seo and Sungwoo Hong

J. Am. Chem. Soc., 2022, 144, 9091
DOI: 10.1021/jacs.2c02343

Aldehydes as O-Nucleophiles in Cobalt Hydride Hydrogen Atom Transfer Catalysis: Overriding the Innate Somophilicity

Yi-Chen Nie, Fan Yang, Yu-Hao Li and Rong Zhu

Org. Lett., 2023, 25, 889
DOI: 10.1021/acs.orglett.3c00131

C–C Bond Cleavage of α-Pinene Derivatives Prepared from Carvone as a General Strategy for Complex Molecule Synthesis

Robert F. Lusi, Melecio A. Perea and Richmond Sarpong

Acc. Chem. Res., 2022, 55, 746
DOI: 10.1021/acs.accounts.1c00783

Inner- and Outer-Sphere Cross-Coupling of High Fsp3 Fragments

Simona Kotesova and Ryan A. Shenvi

Acc. Chem. Res., 2023, 56, 3089
DOI: 10.1021/acs.accounts.3c00543

Photoinduced Cobalt Catalysis for the Reductive Coupling of Pyridines and Dienes Enabled by Paired Single‐Electron Transfer**

Jingyang Qin, Manuel Barday, Samikshan Jana, Nil Sanosa, Ignacio Funes‐Ardoiz and Christopher J. Teskey

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310639

Cobalt‐Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines

Huanran Miao, Meihui Guan, Tao Xiong, Ge Zhang and Qian Zhang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202213913

Computational Study on Homolytic Bond Energies of the Ag–X (X = C, O, and H) Complexes and Hammett-Type Analysis of Reactivity

Lei Wu, Shi-Ya Tang and Shaodong Zhou

ACS Omega, 2021, 6, 34904
DOI: 10.1021/acsomega.1c05563

Non‐native Intramolecular Radical Cyclization Catalyzed by a B12‐Dependent Enzyme**

Jianbin Li, Amardeep Kumar and Jared C. Lewis

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202312893

Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene

Haojie Dai, Yuhan Wang, Kailin Wang, Hao Kang, Xiangyang Chen, Bei Ding, Xudan Chen, Ying Du, Lize Dong, Wen Zhong, Ning Sun, Pengyu Liu, Chunyang Yu, Jingyuan Ma, Fei Song, Yongfeng Hu, Shan Tang, Yannan Liu, Wenfeng Jiang, Yuanhai Su, Jun Li and Yongfeng Zhou

Nat Catal, 2025, 8, 645
DOI: 10.1038/s41929-025-01380-z

Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones

Xukai Zhou, Yan Xu and Guangbin Dong

Nat Catal, 2021, 4, 703
DOI: 10.1038/s41929-021-00661-7

Iron‐Catalyzed Markovnikov Hydration of Unactivated Terminal Alkenes Enabled by Reductive Radical‐Polar Crossover

Songzhuo Zheng, Pengtao Bai, Yuting Xiao, Xiaolan Zeng, Heng Song, Shu‐Yang Chen, Shu‐Fen Hou, Yuzan Liu, Rulan Pu, Xingwei Cai, Jianming Pan and Chen Xu

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500162

Cobalt/Photoredox Dual-Catalyzed Cross-Radical Coupling of Alkenes via Hydrogen Atom Transfer and Homolytic Substitution

Yuto Yamaguchi, Yuki Hirata, Kosuke Higashida, Tatsuhiko Yoshino and Shigeki Matsunaga

Org. Lett., 2024, 26, 4893
DOI: 10.1021/acs.orglett.4c01370

Aerobic C–C Bond Cleavage of Allylic Alcohols via Co-Catalyzed Hydrogen Atom Transfer

Meng Deng, Mengqi Chu, Nan Li, Guohui Sun, Fei Li, Dade Guo, Guohui Kang and Baoming Ji

Org. Lett., 2023, 25, 2420
DOI: 10.1021/acs.orglett.3c00556

Cobalt-Catalyzed Photoelectrochemical Dehydration of Primary Alcohols

Xiaoyuan Ying, Yong Zhang and Chao Li

J. Am. Chem. Soc., 2025, 147, 45315
DOI: 10.1021/jacs.5c15270

Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization

Jun-Jie Wang, He Huang, Han-Li Sun, Fan Yang, Jun Wen and Rong Zhu

Nat Catal, 2024, 7, 838
DOI: 10.1038/s41929-024-01182-9

Ligand‐Controlled Stereoselective Synthesis of 2‐Deoxy‐β‐C‐glycosides by Cobalt Catalysis

Bingxue Liu, Deguang Liu, Xianle Rong, Xi Lu, Yao Fu and Qiang Liu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202218544

Asymmetric Allylic Substitution‐Isomerization for the Modular Synthesis of Axially Chiral N‐Vinylquinazolinones

Jia‐Yu Zou, Yu‐Ying Yang, Jun Gu, Fei Liu, Zhiwen Ye, Wenbin Yi and Ying He

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310320

Fe‐Catalyzed Anaerobic Mukaiyama‐Type Hydration of Alkenes using Nitroarenes

Anup Bhunia, Klaus Bergander, Constantin Gabriel Daniliuc and Armido Studer

Angew Chem Int Ed, 2021, 60, 8313
DOI: 10.1002/anie.202015740

Alkene Hydrobenzylation by a Single Catalyst That Mediates Iterative Outer-Sphere Steps

Lingran Kong, Xu-cheng Gan, Vincent A. van der Puyl Lovett and Ryan A. Shenvi

J. Am. Chem. Soc., 2024, 146, 2351
DOI: 10.1021/jacs.3c13398

Merging Hydrogen‐Atom‐Transfer and the Truce‐Smiles Rearrangement for Synthesis of β‐Arylethylamines from Unactivated Allylsulfonamides

Hanqi Zhou, Danijela Lunic, Nil Sanosa, Diego Sampedro, Ignacio Funes‐Ardoiz and Christopher J. Teskey

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202418869

Facile Construction of Benzo[d][1,3]oxazocine: Reductive Radical Dearomatization of N-Alkyl Quinoline Quaternary Ammonium Salts

Fu-Yu Li, Yao Xiao, Dong-Wei Huang, Meng Luo, Lu Li, Hong Xu, Bei Wang and Ji-Yu Wang

Org. Lett., 2024, 26, 1996
DOI: 10.1021/acs.orglett.3c04243

Markovnikov-Selective α-C(sp3)−H Alkylation of Glycine with Alkenes via Photoredox/Co Dual Catalysis

Youwan Ye, Chenxing Zhou, Xianzhen Qi, Yingpeng Su, Dongsheng Ji and Congde Huo

ACS Catal., 2026
DOI: 10.1021/acscatal.6c01493

Investigating cyclization selectivity by ligand tuning based on MHAT/RPC mechanism

Takuma Sugimura and Hiroki Shigehisa

Tetrahedron Letters, 2024, 135, 154902
DOI: 10.1016/j.tetlet.2023.154902

Repurposing haemoproteins for asymmetric metal-catalysed H atom transfer

Xiang Zhang, Dongping Chen, María Álvarez and Thomas R. Ward

Nature, 2025, 644, 381
DOI: 10.1038/s41586-025-09308-0

Regioselective Intermolecular Hydroamination of Unactivated Alkenes: “Co–H” Enabled Remote Functionalization

Dandan Yang, Hai Huang, He Zhang, Li-Ming Yin, Mao-Ping Song and Jun-Long Niu

ACS Catal., 2021, 11, 6602
DOI: 10.1021/acscatal.1c00625

Ligand‐Enabled NiII‐Catalyzed Hydroxylarylation of Alkenes with Molecular Oxygen

Dao‐Ming Wang, Li‐Qin She, Hao Yuan, Yichen Wu, Yong Tang and Peng Wang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202304573

cis‐Aziridines From Terminal Alkenes via Diastereoselective Intramolecular Electrocatalytic Hydroamination

Ahhyeon Choi, Hyeonseo Kim, Daniel Yim, Hyungjun Kim and Hyunwoo Kim

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.4116549

Thermochemical Studies of Nickel Hydride Complexes with Cationic Ligands in Aqueous and Organic Solvents

Andrew D. Cypcar, Tyler A. Kerr and Jenny Y. Yang

Organometallics, 2022, 41, 2605
DOI: 10.1021/acs.organomet.2c00319

Anodizing of Hydrogenated Titanium and Zirconium Films

Alexander Poznyak, Andrei Pligovka and Marco Salerno

Materials, 2021, 14, 7490
DOI: 10.3390/ma14247490

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Donghao Jiang, Xinzhu Li, Mengdie Xiao and Li‐Jie Cheng

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202412828

Catalytic hydrofunctionalizations of alkenes via hydrogen atom transfer with 3d transition metal complexes (MHAT): A pragmatic approach to recent contributions

Antonio Torres-Calis and Juventino J. García

Applied Catalysis A: General, 2025, 704, 120379
DOI: 10.1016/j.apcata.2025.120379

Alkene Hydrogenation via Manganese-Catalyzed Hydrogen Atom Transfer: An Undergraduate Organic Chemistry Experiment

Nan Li, Bike Ren, Jingyi Zhang, Jingyi Guo and Meng Deng

J. Chem. Educ., 2026
DOI: 10.1021/acs.jchemed.5c01824

Harnessing the potential of acyl triazoles in bifunctional cobalt-catalyzed radical cross-coupling reactions

Chang-Yin Tan and Sungwoo Hong

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-51376-9

Nickel-Catalyzed Hydrofluorination of Unactivated Alkenes through a HAT Pathway

Peihong Song and Shaolin Zhu

ACS Catal., 2020, 10, 13165
DOI: 10.1021/acscatal.0c03884

γ-Amino C(sp3)–H Functionalization of Aliphatic Amines through a Light-Driven Triple Catalysis

Masanari Nakagawa, Kazunori Nagao and Hirohisa Ohmiya

ACS Catal., 2024, 14, 8005
DOI: 10.1021/acscatal.4c02004

A Vitamin B12-Inspired Cobalt-Dye Coordination Polymer for Photocatalytic Directional Transportation of Electrons and Hydrogen

Xiongwen Li, Tiexin Zhang, Jianing Li, Yusheng Shi, Cheng He and Chunying Duan

ACS Catal., 2026
DOI: 10.1021/acscatal.6c01028

Cross–coupling of alkenes with photocatalytic fluorination

Qixin Zhou, Tiancen Bian, Guocong Zhang, Liejin Zhou and Zuxiao Zhang

Green Carbon, 2025
DOI: 10.1016/j.greenca.2025.08.002

Electrocatalytic Reduction of C–C π-Bonds via a Cobaltocene-Derived Concerted Proton–Electron Transfer Mediator: Fumarate Hydrogenation as a Model Study

Joseph Derosa, Pablo Garrido-Barros and Jonas C. Peters

J. Am. Chem. Soc., 2021, 143, 9303
DOI: 10.1021/jacs.1c03335

Efficient and modular synthesis of ibogaine and related alkaloids

Rishab N. Iyer, David Favela, Andras Domokos, Guoliang Zhang, Arabo A. Avanes, Samuel J. Carter, Andrian G. Basargin, Alexis R. Davis, Dean J. Tantillo and David E. Olson

Nat. Chem., 2025, 17, 412
DOI: 10.1038/s41557-024-01714-7

Total Synthesis of Euphane Triterpenoids Using Metal‐Catalyzed Hydrogen Atom Transfer

Chengying Zhou, Weitian Qin, Canhui Tu, Yunxuan Chen, Shaomin Fu and Bo Liu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202503943

Cobalt‐Catalyzed Facial‐Selective Hydroalkylation of Cyclopropenes

Zhi‐Lin Zhang, Zhen Li, Yuan‐Tai Xu, Lu Yu, Jian Kuang, Yan Li, Jia‐Wang Wang, Changlin Tian, Xi Lu and Yao Fu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202306381

Electrocatalytic radical-polar crossover hydrofunctionalization of alkenes via cobalt-catalyzed hydrogen atom transfer

Ahhyeon Choi and Hyunwoo Kim

Current Opinion in Electrochemistry, 2024, 44, 101449
DOI: 10.1016/j.coelec.2024.101449

Iron-Mediated Segment Coupling of Alkenols with Acceptors via C–C Radical Translocation and Remote Oxidative 1,5/6-Hydrogen Atom Transfer

Santosh J. Gharpure, Rupali S. Chavan and Dipak J. Fartade

Org. Lett., 2024, 26, 9920
DOI: 10.1021/acs.orglett.4c03749

Radical Carbocyclization Intercepted Reductive C−C Bond Formation Between 1,n‐Enynes or Dienes and Electron‐Poor Olefins/Alkynes

Subhadeep Hazra, Manveer Patel and Jaideep Saha

Adv Synth Catal, 2024, 366, 4688
DOI: 10.1002/adsc.202400503

A Quadruple Catalysis Enabling Intermolecular Branch‐Selective Hydroacylation of Styrenes

Yunosuke Takekawa, Masanari Nakagawa, Kazunori Nagao and Hirohisa Ohmiya

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301484

Recent Advances in Radical Hydrofunctionalization of Alkenes and Dienes via Reductive Metal‐Hydride Hydrogen Atom Transfer (MHAT)

Haigen Shen, Xianrong Zeng and Zhaobin Wang

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401103

Radical Cascade Combining Cross‐Olefin Coupling with the Smiles‐Truce Rearrangement

Jingyang Qin, Lucas Popek, Moritz Wyrtki and Christopher J. Teskey

Angew Chem Int Ed, 2026
DOI: 10.1002/anie.202525790

Photo- and Cobalt-Catalyzed Cycloisomerization of Unsaturated Guanidines, (Iso-)Ureas, and Carbonates

Henry Lindner and Erick M. Carreira

Org. Lett., 2025, 27, 704
DOI: 10.1021/acs.orglett.4c04695

Ligand‐Enabled NiII‐Catalyzed Hydroxylarylation of Alkenes with Molecular Oxygen

Dao‐Ming Wang, Li‐Qin She, Hao Yuan, Yichen Wu, Yong Tang and Peng Wang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202304573

Nickel-Catalyzed Branched Hydroalkylation of Alkenes with Diazo Compounds

Nikita Kvasovs, Valeriia Iziumchenko, Alistair J. Sterling and Vladimir Gevorgyan

J. Am. Chem. Soc., 2025, 147, 8093
DOI: 10.1021/jacs.4c17586

Cobalt‐Catalyzed Chemoselective Isomerization of 2‐Substituted Allyl Ethers Induced by Hydrogen Atom Transfer

Nan Li, Mengdi You, Xiaohan Qiu, Meng Deng, Guohui Kang, Huan Liu, Shu‐Zhen Deng and Baoming Ji

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200488

Cobalt‐Catalyzed Asymmetric Alkylation of (Hetero)Arenes with Styrenes

Tao Qin, Guowei Lv, Huanran Miao, Meihui Guan, Chunlu Xu, Ge Zhang, Tao Xiong and Qian Zhang

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202201967

Diastereoselective Ring Expansion of Cyclic Ketones Enabled by HAT-Initiated Radical Cascade

Wenxue Wang, Shouyang Feng, Yansheng Wei, Hongyu Wang and Yun Li

Org. Lett., 2023, 25, 8022
DOI: 10.1021/acs.orglett.3c03236

Cobalt‐Catalyzed Hydroglycosylation of Alkynes for the Synthesis of Vinyl α‐C‐Glycosides

Jia‐Xi Wang, Yuan Yao, Yingwei Wang and Dawen Niu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202423631

Bimolecular Homolytic Substitution (SH2) and Radical Ligand Transfer (RLT): Emerging Paradigms in Radical Transformations

Anthony J. Fernandes and Dmitry Katayev

ACS Cent. Sci., 2025, 11, 1812
DOI: 10.1021/acscentsci.5c01091

Catalyst Complexity in a Highly Active and Selective Wacker-Type Markovnikov Oxidation of Olefins with a Bioinspired Iron Complex

Jonathan Trouvé, Khalil Youssef, Sitthichok Kasemthaveechok and Rafael Gramage-Doria

ACS Catal., 2023, 13, 4421
DOI: 10.1021/acscatal.3c00593

Bimolecular Homolytic Substitution (SH2) at a Transition Metal

Ying Zhang, Kai‐Dian Li and Huan‐Ming Huang

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400955

Nickel‐Catalyzed Hydrogenation of Enamides and Quinolines via Photoinduced Hydrogen Atom Transfer

Zi‐Kui Liu, Lan Qin, Yi Wei, Xiao‐Qiang Hu and You‐Quan Zou

Chin. J. Chem., 2025, 43, 1673
DOI: 10.1002/cjoc.70039

Asymmetric Reduction of Unactivated Alkenes

Nico D. Fessner, Sebastian Roth, Richard Niese and Michael Müller

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.70826

Hydrogen production and transfer hydrogenation of phenylacetylene with ammonia borane in water catalyzed by the [Pd(2-pymo)2]n framework

Adam W. Augustyniak and Anna M. Trzeciak

Inorganica Chimica Acta, 2022, 538, 120977
DOI: 10.1016/j.ica.2022.120977

Combining the best of both worlds: radical-based divergent total synthesis

Kyriaki Gennaiou, Antonios Kelesidis, Maria Kourgiantaki and Alexandros L Zografos

Beilstein J. Org. Chem., 2023, 19, 1
DOI: 10.3762/bjoc.19.1

Radikale Kaskadenreaktion, welche die Kreuzkupplung von Olefinen mit der Smiles‐Truce‐Umlagerung kombiniert

Jingyang Qin, Lucas Popek, Moritz Wyrtki and Christopher J. Teskey

Angewandte Chemie, 2026
DOI: 10.1002/ange.202525790

Cobalt-electrocatalytic HAT for functionalization of unsaturated C–C bonds

Samer Gnaim, Adriano Bauer, Hai-Jun Zhang, Longrui Chen, Cara Gannett, Christian A. Malapit, David E. Hill, David Vogt, Tianhua Tang, Ryan A. Daley, Wei Hao, Rui Zeng, Mathilde Quertenmont, Wesley D. Beck, Elya Kandahari, Julien C. Vantourout, Pierre-Georges Echeverria, Hector D. Abruna, Donna G. Blackmond, Shelley D. Minteer, Sarah E. Reisman, Matthew S. Sigman and Phil S. Baran

Nature, 2022, 605, 687
DOI: 10.1038/s41586-022-04595-3

Mechanistic Elucidation of a Radical‐Promoted Hydrogenation Relevant to Borrowing Hydrogen Catalysis

Amreen K. Bains, Abhishek Kundu and Debashis Adhikari

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300586

Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols

Yu‐Hao Huang, Qing‐Xiu Gu, Qing‐Cen Chao, Han‐Zhi Xiao and Hai‐Hua Lu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202507638

Proton-Modulated Nickel Hydride Electrocatalysis for the Hydrogenation of Unsaturated Bonds and Olefin Isomerization

Xue Song, Yuan-Qiong Huang, Bodi Zhao, Hanshuo Wu, Xiaotian Qi and Jianchun Wang

J. Am. Chem. Soc., 2025, 147, 20644
DOI: 10.1021/jacs.5c03821

Directing‐Group‐Assisted Markovnikov Hydroximation of Styrenes Enabled by Photoredox/Cobalt Dual‐Catalysis

Qian Xiao, Maojian Lu, Yonghong Xiao and Jian‐Ji Zhong

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401156

Synthesis of five-, six-, and seven-membered cyclic isoureas via MHAT/RPC promoted cycloisomerization

Nao Mimata and Hiroki Shigehisa

Tetrahedron Letters, 2024, 135, 154890
DOI: 10.1016/j.tetlet.2023.154890

Enantiocontrolled Total Synthesis of (−)-Retigeranic Acid A

Xiaoming Chen, Weidong Yao, Hufeng Zheng, Hongyu Wang, Pan-Pan Zhou, Dao-Yong Zhu and Shao-Hua Wang

J. Am. Chem. Soc., 2023, 145, 13549
DOI: 10.1021/jacs.3c04850

Methodologies for the synthesis of quaternary carbon centers via hydroalkylation of unactivated olefins: twenty years of advances

Thiago S Silva and Fernando Coelho

Beilstein J. Org. Chem., 2021, 17, 1565
DOI: 10.3762/bjoc.17.112

Natural Product Synthesis Enabled by Radical-Polar Crossover Reactions

Nicolas Müller, Thomas Magauer and Ondřej Kováč

J. Org. Chem., 2025, 90, 5083
DOI: 10.1021/acs.joc.5c00306

Dioxygen-promoted cobalt-catalyzed oxidative hydroamination using unactivated alkenes and free amines

Wei-Ting Ye and Rong Zhu

Chem Catalysis, 2022, 2, 345
DOI: 10.1016/j.checat.2021.12.003

Cobaltkatalysierte Photochemische Semipinakol‐Umlagerung Nichtaktivierter Allylalkohole

Henry Lindner and Erick M. Carreira

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202407827

Cobalt-Catalyzed γ-C–H Functionalization of Alcohols via Olefin-Tethered Radical Relay

Phong Dam, Kosala N. Amarasinghe, Chenyang Wang, Olga S. Bokareva, Luis Miguel Azofra and Osama El-Sepelgy

JACS Au, 2026, 6, 95
DOI: 10.1021/jacsau.5c00909

Fe‐Catalyzed Anaerobic Mukaiyama‐Type Hydration of Alkenes using Nitroarenes

Anup Bhunia, Klaus Bergander, Constantin Gabriel Daniliuc and Armido Studer

Angewandte Chemie, 2021, 133, 8394
DOI: 10.1002/ange.202015740

Dual‐katalysierte intermolekulare reduktive Kopplung von Dienen und Ketonen**

Victor J. Mayerhofer, Martina Lippolis and Christopher J. Teskey

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202314870

Photocatalytic Deuterium Atom Transfer Deuteration of Electron‐Deficient Alkenes with High Functional Group Tolerance

Akihiko Suzuki, Yuji Kamei, Masaaki Yamashita, Yusuke Seino, Yuto Yamaguchi, Tatsuhiko Yoshino, Masahiro Kojima and Shigeki Matsunaga

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202214433

Alkylazolation of Alkenes via Photocatalytic Radical Polar Crossover

Tiancen Bian and Zuxiao Zhang

Org. Lett., 2025, 27, 747
DOI: 10.1021/acs.orglett.4c04384

Cobalt-catalyzed alkene hydrohalogenation via hydrogen atom transfer

Arman Khosravi and Ming-Yu Ngai

Tetrahedron, 2025, 187, 134944
DOI: 10.1016/j.tet.2025.134944

Photo‐ and Cobalt‐Catalyzed Synthesis of Heterocycles via Cycloisomerization of Unactivated Olefins

Henry Lindner, Willi M. Amberg, Tristano Martini, David M. Fischer, Eléonore Moore and Erick M. Carreira

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202319515

Dual‐Catalytic Structural Isomerisation as a Route to α‐Arylated Ketones

Danijela Lunic, Nikita Vystavkin, Jingyang Qin and Christopher J. Teskey

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202409388

Construction of a (NNN)Ru-Incorporated Porous Organic Polymer with High Catalytic Activity for β-Alkylation of Secondary Alcohols with Primary Alcohols

Yao Cui, Jixian Wang, Lei Yu, Ying Xu, David J. Young, Haiyan Li and Hongxi Li

Polymers, 2022, 14, 231
DOI: 10.3390/polym14020231

Co-MHAT-Catalyzed Wacker-Type Oxidation of 1,3-Enynes into Ynones

Ying Jiang, Wen-Chao Zhao, Kai Xiao, Yu Zhou, Wei Huang, Shengbin Zhou and Feng-Hua Zhang

Org. Lett., 2025, 27, 13962
DOI: 10.1021/acs.orglett.5c04558

Additives Promote Divergent Reactivity in Photolytic Deoxygenation and Lactonization Reactions of Cobalt Alkoxycarbonyls

Jacob N. Hackbarth, Dana R. Chambers, Cory T. Ludwig, Tyler K. Brown and David B. C. Martin

Eur J Org Chem, 2026, 29
DOI: 10.1002/ejoc.202501091

Recent Progress in Chromium-Mediated Carbonyl Addition Reactions

Yuri Katayama, Harunobu Mitsunuma and Motomu Kanai

Synthesis, 2022, 54, 1684
DOI: 10.1055/a-1696-6429

Formation of TEMPO Adducts with Hydrogen Atom Transfer: An Alternative Pathway to Versatile Hydrofunctionalizations of Olefins

Chengbo Yao, Muinat A. Aliyu, Yanjun Wan and Jack R. Norton

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403899

Secondary phosphine oxide-activated nickel catalysts for site-selective alkene isomerization and remote hydrophosphination

Lin Huang, En Qi Lim and Ming Joo Koh

Chem Catalysis, 2022, 2, 508
DOI: 10.1016/j.checat.2021.12.014

Light-Driven Cobalt Hydride Catalyzed Hydroarylation of Styrenes

Enrico Bergamaschi, Victor J. Mayerhofer and Christopher J. Teskey

ACS Catal., 2022, 12, 14806
DOI: 10.1021/acscatal.2c05109

Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction

Navid Jameei Moghaddam, Marcos Gil-Sepulcre, Jia-Wei Wang, Jordi Benet-Buchholz, Carolina Gimbert-Suriñach and Antoni Llobet

Inorg. Chem., 2022, 61, 16639
DOI: 10.1021/acs.inorgchem.2c02150

Reversal of the Regioselectivity of Iron‐Promoted Hydrogenation and Hydrohalogenation of gem‐Difluoroalkenes

Yu‐Yang Zhang, Yuchen Zhang, Xiao‐Song Xue and Feng‐Ling Qing

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202406324

Cobalt‐Catalyzed Photo‐Semipinacol Rearrangement of Unactivated Allylic Alcohols

Henry Lindner and Erick M. Carreira

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202407827

Hydride-Free Hydrogenation: Unraveling the Mechanism of Electrocatalytic Alkyne Semihydrogenation by Nickel–Bipyridine Complexes

Gabriel Durin, Mi-Young Lee, Martina A. Pogany, Thomas Weyhermüller, Nicolas Kaeffer and Walter Leitner

J. Am. Chem. Soc., 2023, 145, 17103
DOI: 10.1021/jacs.3c03340

Iron-Catalyzed Radical Hydrothiolation of gem-Difluoroalkenes

You-Zhi Liao, Bai-Qun Ruan, Hai-Yang Hu, Hao Cheng, Bi-Qin Wang and Fei Pan

Org. Lett., 2025, 27, 9293
DOI: 10.1021/acs.orglett.5c02890

Biocatalytic, asymmetric radical hydrogenation of unactivated alkenes

Jaicy Vallapurackal, Rajib Mandal, Justin Bossenbroek, Aris V. Rubio, Ethan Poladian, James D. Collings, Cesar Torres, Matthew Hendrickson, Julian Morales, Max B. Lyons, Kyle Schultz, Hannah S. Shafaat, K. N. Houk and Soumitra V. Athavale

Science, 2025, 390, 1050
DOI: 10.1126/science.aea4737

Ligand-Controlled Cobalt-Catalyzed Regiodivergent Alkyne Hydroalkylation

Yan Li, Deguang Liu, Lei Wan, Jun-Yang Zhang, Xi Lu and Yao Fu

J. Am. Chem. Soc., 2022, 144, 13961
DOI: 10.1021/jacs.2c06279

Iron(ΙΙΙ) Catalyzed Aerobic Cα−Cβ Cleavage of Allylic Alcohols

Georgia G. Bagkavou and Christos I. Stathakis

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400556

Electrocatalytic Radical-Polar Crossover Hydroetherification of Alkenes with Phenols

Steve H Park, Jieun Jang, Kwangmin Shin and Hyunwoo Kim

ACS Catal., 2022, 12, 10572
DOI: 10.1021/acscatal.2c02436

Intermolecular Hydroalkoxylation and Hydrocarboxylation of 2-Azadienes with High Efficiency

Juan M. I. Serviano, Erik J. T. Phipps and Patrick L. Holland

J. Org. Chem., 2023, 88, 3277
DOI: 10.1021/acs.joc.2c02534

Correspondence on “Organo‐Mediator Enabled Electrochemical Deuteration of Styrenes”

Simon Kolb and Daniel B. Werz

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202316037

Nickel‐Catalyzed Switchable Site‐Selective Alkene Hydroalkylation by Temperature Regulation**

Jia‐Wang Wang, De‐Guang Liu, Zhe Chang, Zhen Li, Yao Fu and Xi Lu

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205537

Asymmetric Total Synthesis of Norzoanthamine

Zhengyuan Xin, Hui Wang, Haibing He, Xiaoli Zhao and Shuanhu Gao

Angew Chem Int Ed, 2021, 60, 12807
DOI: 10.1002/anie.202102643

Iron‐Catalyzed Wacker‐type Oxidation of Olefins at Room Temperature with 1,3‐Diketones or Neocuproine as Ligands**

Florian Puls, Philipp Linke, Olga Kataeva and Hans‐Joachim Knölker

Angewandte Chemie, 2021, 133, 14202
DOI: 10.1002/ange.202103222

Photoredox/Nickel-Catalyzed Hydrogenation of Alkenes Using Water as the Hydrogen Source

Jie Gao, Liu-Shuo Shi, Xian-Chen He, Yu Zheng, Kai Chen and Hua Yang

Org. Lett., 2026, 28, 4157
DOI: 10.1021/acs.orglett.6c00677

Cobalt-Catalyzed Enantioconvergent Decarboxylative N-Alkylation

Siwen Huang, Ramon Trevino, Dishun Zuo, Xin Tian, Wenhan Yang, William B. Hughes, Seth O. Fremin, Arka Porey, Vy T. B. Nguyen, Bo Gao, Xiyuan Xu, Babu Raj Dhungana, Yingqian Jiang, Yao Sun, Chao Huang, Min He, Chandan Giri, Shree Krishna Dhakal, Bin Qin, Yongxiang Liu, Maosheng Cheng, Oleg V. Larionov and Shengfei Jin

J. Am. Chem. Soc., 2025, 147, 21097
DOI: 10.1021/jacs.5c06317

Cobalt-catalyzed Divergent Markovnikov and Anti-Markovnikov Hydroamination

Xiang-Gui Zhang, Zi-Xin He, Peng Guo, Zheng Chen and Ke-Yin Ye

Org. Lett., 2022, 24, 22
DOI: 10.1021/acs.orglett.1c03511

Natural Product Synthesis through the Lens of Informatics

Stone Woo and Ryan A. Shenvi

Acc. Chem. Res., 2021, 54, 1157
DOI: 10.1021/acs.accounts.0c00791

Intercepting Hydrogen Evolution with Hydrogen-Atom Transfer: Electron-Initiated Hydrofunctionalization of Alkenes

Xiangyu Wu, Cara N. Gannett, Jinjian Liu, Rui Zeng, Luiz F. T. Novaes, Hongsen Wang, Héctor D. Abruña and Song Lin

J. Am. Chem. Soc., 2022, 144, 17783
DOI: 10.1021/jacs.2c08278

Photocatalytic Deuterium Atom Transfer Deuteration of Electron‐Deficient Alkenes with High Functional Group Tolerance

Akihiko Suzuki, Yuji Kamei, Masaaki Yamashita, Yusuke Seino, Yuto Yamaguchi, Tatsuhiko Yoshino, Masahiro Kojima and Shigeki Matsunaga

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202214433

Asymmetric Total Syntheses of (+)-Davisinol and (+)-18-Benzoyldavisinol: A HAT-Initiated Transannular Redox Radical Approach

Kuan Yu, Fengjie Yao, Qingrui Zeng, Hujun Xie and Hanfeng Ding

J. Am. Chem. Soc., 2021, 143, 10576
DOI: 10.1021/jacs.1c05703

Modifying commodity-relevant unsaturated polymers via Co-catalyzed MHAT

Yun-Nian Yin, Bang-Sen Zhao, Han-Yuan Liu, Rui-Qing Sheng, Dong-Chen Ouyang and Rong Zhu

Chem, 2024, 10, 3088
DOI: 10.1016/j.chempr.2024.05.021

Iron Catalyzed Radical Alkylation of Cyclic Ketimines with Olefins via Metal Hydride Atom Transfer

Xixi Hu, Ruizhi Sun, Yu Tian, Xinyue Xu, Yijia Zhu, Hui Liu, Dong Liu and Lizhi Zhang

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401430

Allylboronic Esters as Acceptors in Radical Addition, Boron 1,2-Migration, and Trapping Cascades

Kalipada Jana and Armido Studer

Org. Lett., 2022, 24, 1100
DOI: 10.1021/acs.orglett.2c00039

Co–Mabiq Flies Solo: Light-Driven Markovnikov-Selective C- and N-Alkylation of Indoles and Indazoles without a Cocatalyst

Oaikhena Zekeri Esezobor, Wenyi Zeng, Lukas Niederegger, Michael Grübel and Corinna R. Hess

J. Am. Chem. Soc., 2022, 144, 2994
DOI: 10.1021/jacs.1c10930

Markovnikov‐Selective Cobalt‐Catalyzed Wacker‐Type Oxidation of Styrenes into Ketones under Ambient Conditions Enabled by Hydrogen Bonding

Naba Abuhafez, Andreas W. Ehlers, Bas de Bruin and Rafael Gramage‐Doria

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202316825

Synthesis of Modified Fusicoccane Diterpenoids via Diverging MHAT Reactivity

Dylan W. Snelson, Sebastian A. Fernandez and Ryan A. Shenvi

Synthesis, 2026, 58, 557
DOI: 10.1055/a-2744-6756

Cross- and branched-selective hydroalkenylation by metal hydride selection

Chunyu Li, Xu-cheng Gan, Yu Irie, Milo A. Smith and Ryan A. Shenvi

Science, 2026, 391, 1262
DOI: 10.1126/science.aeb2389

Dual Cobalt and Photoredox Catalysis Enabled Redox‐Neutral Annulation of 2‐Propynolphenols

Yao Zhu, Yong‐Qin He, Wan‐Fa Tian, Mei Wang, Zhao‐Zhao Zhou, Xian‐Rong Song, Hai‐Xin Ding and Qiang Xiao

Adv Synth Catal, 2021, 363, 3372
DOI: 10.1002/adsc.202100221

Catalytic Asymmetric Hydroalkoxylation of C–C Multiple Bonds

Jennifer L. Kennemur, Rajat Maji, Manuel J. Scharf and Benjamin List

Chem. Rev., 2021, 121, 14649
DOI: 10.1021/acs.chemrev.1c00620

Chloroalkylation of Unactivated Alkenes via a Cobalt-Mediated Radical Ligand Transfer (RLT) Photoredox Catalysis Platform

Subrata Patra, Anthony J. Fernandes, Besa Kadriu and Dmitry Katayev

JACS Au, 2025, 5, 6231
DOI: 10.1021/jacsau.5c01211

Unraveling Hydrogen Atom Transfer Mechanisms with Voltammetry: Oxidative Formation and Reactivity of Cobalt Hydride

Dylan G. Boucher, Andrew D. Pendergast, Xiangyu Wu, Zachary A. Nguyen, Rohit G. Jadhav, Song Lin, Henry S. White and Shelley D. Minteer

J. Am. Chem. Soc., 2023, 145, 17665
DOI: 10.1021/jacs.3c03815

Highly chemoselective synthesis of hindered amides via cobalt-catalyzed intermolecular oxidative hydroamidation

Yun-Nian Yin, Rui-Qi Ding, Dong-Chen Ouyang, Qing Zhang and Rong Zhu

Nat Commun, 2021, 12
DOI: 10.1038/s41467-021-22373-z

Non‐native Intramolecular Radical Cyclization Catalyzed by a B12‐Dependent Enzyme**

Jianbin Li, Amardeep Kumar and Jared C. Lewis

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202312893

Photocatalytic Metal Hydride Hydrogen Atom Transfer Mediated Allene Functionalization by Cobalt and Titanium Dual Catalysis

Huaipu Yan, Qian Liao, Yuqing Chen, Gagik G. Gurzadyan, Binghui Lu, Chao Wu and Lei Shi

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202302483

Evolution of a Synthetic Strategy toward the Heptacyclic Core Framework of Nominine

Wenkuan Mao, Fengjie Yao, Kuan Yu, Jun Xuan and Hanfeng Ding

J. Org. Chem., 2026
DOI: 10.1021/acs.joc.6c00318

Controlling Chemoselectivity of Catalytic Hydroboration with Light

Enrico Bergamaschi, Danijela Lunic, Liam A. McLean, Melissa Hohenadel, Yi‐Kai Chen and Christopher J. Teskey

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202114482

Catalytic Synthesis of Cyclic Guanidines via Hydrogen Atom Transfer and Radical-Polar Crossover

Shunya Ohuchi, Hiroki Koyama and Hiroki Shigehisa

ACS Catal., 2021, 11, 900
DOI: 10.1021/acscatal.0c05359

Dual‐Catalysed Intermolecular Reductive Coupling of Dienes and Ketones**

Victor J. Mayerhofer, Martina Lippolis and Christopher J. Teskey

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202314870

Electrocatalytic Access to Azetidines via Intramolecular Allylic Hydroamination: Scrutinizing Key Oxidation Steps through Electrochemical Kinetic Analysis

Steve H. Park, Geunsu Bae, Ahhyeon Choi, Suyeon Shin, Kwangmin Shin, Chang Hyuck Choi and Hyunwoo Kim

J. Am. Chem. Soc., 2023, 145, 15360
DOI: 10.1021/jacs.3c03172

Reductive Cross-Coupling of Olefins via a Radical Pathway

Wei Zhou, Igor A. Dmitriev and Paolo Melchiorre

J. Am. Chem. Soc., 2023, 145, 25098
DOI: 10.1021/jacs.3c11285

Nickel-catalysed hydrodimerization of unactivated terminal alkenes

Li Cheng, Jiandong Liu, Yunrong Chen and Hegui Gong

Nat. Synth, 2023, 2, 364
DOI: 10.1038/s44160-023-00239-0

Fe/Thiol Cooperative Hydrogen Atom Transfer Olefin Hydrogenation: Mechanistic Insights That Inform Enantioselective Catalysis

Sarah R. Buzsaki, Savannah M. Mason, Padmanabha V. Kattamuri, Juan M. I. Serviano, Dinora N. Rodriguez, Conner V. Wilson, Drew M. Hood, Jonathan D. Ellefsen, Yen-Chu Lu, Jolie Kan, Julian G. West, Scott J. Miller and Patrick L. Holland

J. Am. Chem. Soc., 2024, 146, 17296
DOI: 10.1021/jacs.4c04047

Dual‐Catalytic Structural Isomerisation as a Route to α‐Arylated Ketones

Danijela Lunic, Nikita Vystavkin, Jingyang Qin and Christopher J. Teskey

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202409388

Copper‐Catalyzed Markovnikov Hydroboration of Alkenes via Hydrogen Atom Transfer (MHAT)

Antonio Torres‐Calis and Juventino J. García

Adv Synth Catal, 2026, 368
DOI: 10.1002/adsc.70286

Metalloenzyme-Catalyzed Radical Reactions Unknown or Uncommon in Native Enzymology

Wenzhen Fu, Liu-Peng Zhao and Yang Yang

Chem. Rev., 2026, 126, 4135
DOI: 10.1021/acs.chemrev.5c00837

Paramagnetic Transition Metal Hydride Complexes

Adi Fishkin and Robert H. Morris

Chem. Rev., 2026, 126, 204
DOI: 10.1021/acs.chemrev.5c00531

Deep Eutectic Solvent as a Sustainable Medium for C–C Bond Formation Via Multicomponent Radical Conjugate Additions

Beatriz Saavedra and Diego J. Ramón

ACS Sustainable Chem. Eng., 2021, 9, 7941
DOI: 10.1021/acssuschemeng.1c02193

Photo‐ und Electrochemische Cobalt‐Katalysierte Wasserstoffatomübertragung für die Hydrofunktionalisierung von Alkenen

Samikshan Jana, Victor J. Mayerhofer and Christopher J. Teskey

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202304882

Two-phase terpenoid biosynthesis-inspired divergent total syntheses of bridged polycyclic natural products

Goh Sennari

Jpn. J. Pestic. Sci., 2023, 48, 173
DOI: 10.1584/jpestics.W23-33

Constructing Four-Membered Heterocycles by Cycloisomerization

Ayami Osato, Takashi Fujihara and Hiroki Shigehisa

ACS Catal., 2023, 13, 4101
DOI: 10.1021/acscatal.2c06404

Regio- and enantioselective hydrofluorination of internal alkenes via nickel-catalyzed hydrogen atom transfer

Fan Chen, Xiaoyu Zhao, Weihang Miao, Yingying Li, Ye Yuan and Lingling Chu

Chinese Chemical Letters, 2025, 36, 110239
DOI: 10.1016/j.cclet.2024.110239

Correspondence on “Organo‐Mediator Enabled Electrochemical Deuteration of Styrenes”

Simon Kolb and Daniel B. Werz

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202316037

Reversal of the Regioselectivity of Iron‐Promoted Hydrogenation and Hydrohalogenation of gem‐Difluoroalkenes

Yu‐Yang Zhang, Yuchen Zhang, Xiao‐Song Xue and Feng‐Ling Qing

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202406324

Asymmetric Hydrogen Atom Transfer

Andrew G. Feng, Marcus Vinicius Pinto Pereira Junior, Scott J. Miller and Robert R. Knowles

ACS Catal., 2026, 16, 844
DOI: 10.1021/acscatal.5c07862

Synthesis, Characterization, and Evaluation of the Cobalt–Carbon Bond Strength of (PNNP)CoIII-R Complexes

Justin D. Miller, Mitchell M. Walsh, Curtis E. Moore and Christine M. Thomas

Organometallics, 2026, 45, 845
DOI: 10.1021/acs.organomet.6c00008

Diastereoselectivity Switch During Alkene Reductions: Diastereodivergent Syntheses of Molecular Fossils via MHAT or Homogeneous Catalytic Hydrogenation Reactions

Christian R. S. Maior, Paulo C. S. Costa, Carolina B. P. Ligiéro, Lygia S. de Moraes, Gustavo R. Sousa, Sidney G. Lima, Pierre M. Esteves and Paulo C. M. L. Miranda

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203731

A Dual Photoredox/Cobalt Catalytic System Enables Markovnikov-Selective Hydroaminoalkylation of Alkenes

Yunosuke Takekawa, Lilian Geniller, Kazunori Nagao and Hirohisa Ohmiya

Precision Chemistry, 2026, 4, 650
DOI: 10.1021/prechem.5c00388

Multiple Deuterium Atom Transfer Perdeuteration of Unactivated Alkenes under Base‐Assisted Cobalt/Photoredox Dual Catalysis

Akihiko Suzuki, Kosuke Higashida, Tatsuhiko Yoshino and Shigeki Matsunaga

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500233

Stereodivergent, Kinetically Controlled Isomerization of Terminal Alkenes via Nickel Catalysis

Camille Z. Rubel, Anne K. Ravn, Hang Chi Ho, Shenghua Yang, Zi‐Qi Li, Keary M. Engle and Julien C. Vantourout

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202320081

Four‐Step Synthesis of (−)‐4‐epi‐Presilphiperfolan‐8α‐ol by Intramolecular Iron Hydride Atom Transfer‐Mediated Ketone‐Alkene Coupling and Studies to Access trans‐Hydrindanols with a Botryane Scaffold

Mar Saladrigas, Enrique Gómez‐Bengoa, Josep Bonjoch and Ben Bradshaw

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203286

Selective Hydrofunctionalization of Alkenyl Fluorides Enabled by Nickel-Catalyzed Hydrogen Atoms and Group Transfer: Reaction Development and Mechanistic Study

Fan Chen, Qianwei Zhang, Yingying Li, Zhi-Xiang Yu and Lingling Chu

J. Am. Chem. Soc., 2024
DOI: 10.1021/jacs.4c01506

Cyclization Reaction by MHAT/RPC Mechanism

Hiroki Shigehisa

J. Synth. Org. Chem. Jpn., 2024, 82, 890
DOI: 10.5059/yukigoseikyokaishi.82.890

Cobalt‐Catalyzed Facial‐Selective Hydroalkylation of Cyclopropenes

Zhi‐Lin Zhang, Zhen Li, Yuan‐Tai Xu, Lu Yu, Jian Kuang, Yan Li, Jia‐Wang Wang, Changlin Tian, Xi Lu and Yao Fu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202306381

Quaternary Carbons from Amines and Acids

Ruheng Zhao, Shengchun Wang, Pingsen Shi, Sandip Kumar Das, Sijing Meng, Aiwen Lei and Tim Cernak

J. Am. Chem. Soc., 2026, 148, 19461
DOI: 10.1021/jacs.6c05065

Cobalt-Catalyzed Markovnikov Hydrofluorocarbonylation of Unactivated Alkenes

Xinzhu Li, Donghao Jiang, Wei Li and Li-Jie Cheng

ACS Catal., 2026, 16, 1594
DOI: 10.1021/acscatal.5c07868

Markovnikov-selective hydroamination of aliphatic alkenes with anilines and azoles through light-driven multiple catalysis

Naoto Kishida, Rino Kobayashi, Masanari Nakagawa, Kazunori Nagao and Hirohisa Ohmiya

Bulletin of the Chemical Society of Japan, 2026, 99
DOI: 10.1093/bulcsj/uoag021

Asymmetric allylic substitution-isomerization for accessing axially chiral vinylindoles by intramolecular π … π stacking interactions

Ying-Xiang Wu, Qi Liu, Qiang Zhang, Zhiwen Ye and Ying He

Cell Reports Physical Science, 2022, 3, 101005
DOI: 10.1016/j.xcrp.2022.101005

Asymmetric C–H Dehydrogenative Allylic Alkylation by Ternary Photoredox-Cobalt-Chiral Primary Amine Catalysis under Visible Light

Zongbin Jia, Long Zhang and Sanzhong Luo

J. Am. Chem. Soc., 2022, 144, 10705
DOI: 10.1021/jacs.2c03299

Cobalt/Brønsted acid co-catalyzed visible light-induced intermolecular Markovnikov hydrocarboxylation of unactivated alkenes

Xudong Mao, Ming Hou, Yuanrui Wang and Xiao-Feng Wu

Journal of Catalysis, 2026, 453, 116535
DOI: 10.1016/j.jcat.2025.116535

Electrochemical Transition Metal Hydride Catalysis

Xinyi Wang, Depeng Duan, Lu Song and Niankai Fu

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202500348

Cyclopentadienyl ring activation in organometallic chemistry and catalysis

Andrew VanderWeide and Demyan E. Prokopchuk

Nat Rev Chem, 2023, 7, 561
DOI: 10.1038/s41570-023-00501-1

Proximal and Remote Hydrocarboxylation of Alkenes with Carbon Dioxide Enabled by Nickel‐Catalyzed Hydrogen Atom Transfer

Rong‐De He and Yixin Lu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424790

Effect of Ligand Backbone on the Electrochemical Hydrogen Evolution Reaction and Hydrogen-Atom-Transfer Reactivity Using a Nickel Polypyridine Quinoline Complex

Sabarni Paul, Subhankar Sutradhar, Aniruddha Paik, Amit Biswas, Soumadip Das, Chandan Das, Rajib Maity, Alok Mahata, Siba P. Midya, Bholanath Maity and Sujoy Rana

Inorg. Chem., 2025, 64, 7988
DOI: 10.1021/acs.inorgchem.4c05512

Unified Total Syntheses of Benzenoid Cephalotane-Type Norditerpenoids: Cephanolides and Ceforalides

Goh Sennari, Kristen E. Gardner, Stefan Wiesler, Maximilian Haider, Alina Eggert and Richmond Sarpong

J. Am. Chem. Soc., 2022, 144, 19173
DOI: 10.1021/jacs.2c08803

Markovnikov Hydrocarbonylation of Unactivated Alkenes via Cobalt/Photoredox Dual Catalysis

Donghao Jiang, Cheng Wang, Xinzhu Li, Cuining Liu, Zhudi He and Li-Jie Cheng

ACS Catal., 2026, 16, 3965
DOI: 10.1021/acscatal.5c09016

Iron-Catalyzed Hydrobenzylation: Stereoselective Synthesis of (−)-Eugenial C

Xu-cheng Gan, Simona Kotesova, Alberto Castanedo, Samantha A. Green, Søren Lau Borcher Møller and Ryan A. Shenvi

J. Am. Chem. Soc., 2023, 145, 15714
DOI: 10.1021/jacs.3c05428

Markovnikov‐Selective Cobalt‐Catalyzed Wacker‐Type Oxidation of Styrenes into Ketones under Ambient Conditions Enabled by Hydrogen Bonding

Naba Abuhafez, Andreas W. Ehlers, Bas de Bruin and Rafael Gramage‐Doria

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202316825

Proximal and Remote Hydrocarboxylation of Alkenes with Carbon Dioxide Enabled by Nickel‐Catalyzed Hydrogen Atom Transfer

Rong‐De He and Yixin Lu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424790

Indium‐mediated allylation of carbonyl compounds in deep eutectic solvents

Nerea González‐Gallardo, Beatriz Saavedra, Gabriela Guillena and Diego J. Ramón

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6418

Cobalt-Catalyzed Synthesis of Alkenyl Heterocycles via Regioselective Intramolecular 1,4-Hydrofunctionalization of Dienes

Chi-Fan Zhu, Yuan Tian, Jun-Ju Mai, Mingyuan Shi, Xiasen Dong, Dongping Shen, Mei-Hua Shen and Hua-Dong Xu

Org. Lett., 2024, 26, 8260
DOI: 10.1021/acs.orglett.4c02884

Cationic copolymerization of isobutylene and bio-renewable β-myrcene towards sustainable elastomers: synthesis and mechanism

Yanqing Feng, Penghui Guo, Wei Ding, Yushun Jin, Ruofan Liu and Yibo Wu

J Polym Res, 2025, 32
DOI: 10.1007/s10965-025-04306-2

(Salen)Titanium‐Catalyzed Asymmetric Hydrogen Atom Transfer for Epoxides Reduction

Zhongyun Xu, Jian Shen, Longfei Li, Wanjiao Chen, Shengxiao Li, Jie Jiang and Yong‐Qiang Zhang

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202214111

Geometry-Controlled Synthesis of Pyrido/Pyrrolo-isoindolones via MHAT Radical Cyclization of Carbethoxy Methylene Isoindolone

Santosh J. Gharpure, Rupali S. Chavan, Kaushik C. Pansuriya and Anusha Khandelwal

Org. Lett., 2025, 27, 14017
DOI: 10.1021/acs.orglett.5c04595

Formal Glycosylation of Quinones with exo-Glycals Enabled by Iron-Mediated Oxidative Radical–Polar Crossover

Haijuan Liu, Adrien G. Laporte, Damien Tardieu, Damien Hazelard and Philippe Compain

J. Org. Chem., 2022, 87, 13178
DOI: 10.1021/acs.joc.2c01635

Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer

Masaaki Yamashita, Akihiko Suzuki, Tatsuhiko Yoshino, Kosuke Higashida, Masahiro Kojima and Shigeki Matsunaga

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500448

Cobalt–Carbon Bonding in a Salen-Supported Cobalt(IV) Alkyl Complex Postulated in Oxidative MHAT Catalysis

Conner V. Wilson, Dongyoung Kim, Ajay Sharma, Reagan X. Hooper, Rinaldo Poli, Brian M. Hoffman and Patrick L. Holland

J. Am. Chem. Soc., 2022, 144, 10361
DOI: 10.1021/jacs.2c02128

Unlocking nucleophilic reactivity in Co-MHAT catalysis: Stereospecific backside-backside displacement by anion-activated organocobalt

Bang-Sen Zhao, Yun-Nian Yin and Rong Zhu

Sci. Adv., 2025, 11
DOI: 10.1126/sciadv.adz1406

Cobalt-Hydride-Catalyzed Alkene-Carboxylate Transposition (ACT) of Allyl Carboxylates

Gaoyuan Zhao, Arman Khosravi, Sahil Sharma, Djamaladdin G. Musaev and Ming-Yu Ngai

J. Am. Chem. Soc., 2024, 146, 31391
DOI: 10.1021/jacs.4c12583

Total Synthesis of Euphane Triterpenoids Using Metal‐Catalyzed Hydrogen Atom Transfer

Chengying Zhou, Weitian Qin, Canhui Tu, Yunxuan Chen, Shaomin Fu and Bo Liu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202503943

Photoinduced Hydrocarboxylation via Thiol-Catalyzed Delivery of Formate Across Activated Alkenes

Sara N. Alektiar and Zachary K. Wickens

J. Am. Chem. Soc., 2021, 143, 13022
DOI: 10.1021/jacs.1c07562

Electrochemical hydrogenation and oxidation of organic species involving water

Cuibo Liu, Fanpeng Chen, Bo-Hang Zhao, Yongmeng Wu and Bin Zhang

Nat Rev Chem, 2024, 8, 277
DOI: 10.1038/s41570-024-00589-z

Cost‐Effective Carbon Quaternization with Redox‐Active Esters and Olefins

Sudhir Kumar Hota and Sandip Murarka

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202408301

Ligand‐Controlled Stereoselective Synthesis of 2‐Deoxy‐β‐C‐glycosides by Cobalt Catalysis

Bingxue Liu, Deguang Liu, Xianle Rong, Xi Lu, Yao Fu and Qiang Liu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202218544

MHAT-driven copper-catalyzed hydrosilylation of alkenes: a new radical pathway for a less explored regioselectivity

Antonio Torres-Calis, Eduardo Gabriel Guzmán-López, Miguel Reina, Marcos Flores-Alamo and Juventino J. García

Journal of Catalysis, 2026, 453, 116494
DOI: 10.1016/j.jcat.2025.116494

Asymmetric Divergent Synthesis of ent-Kaurane-, ent-Atisane-, ent-Beyerane-, ent-Trachylobane-, and ent-Gibberellane-type Diterpenoids

Xian-He Zhao, Le-Le Meng, Xiao-Tao Liu, Peng-Fei Shu, Cheng Yuan, Xian-Tao An, Tian-Xi Jia, Qi-Qiong Yang, Xiang Zhen and Chun-An Fan

J. Am. Chem. Soc., 2023, 145, 311
DOI: 10.1021/jacs.2c09985

Where Enantioselection is Set: A Mechanistic Framework for Asymmetric Hydrogen‐Atom Transfer

Zhongyun Xu, Yufeng Yang and Yong‐Qiang Zhang

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202526135

Asymmetric Allylic Substitution‐Isomerization for the Modular Synthesis of Axially Chiral N‐Vinylquinazolinones

Jia‐Yu Zou, Yu‐Ying Yang, Jun Gu, Fei Liu, Zhiwen Ye, Wenbin Yi and Ying He

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310320

Shuttle HAT for mild alkene transfer hydrofunctionalization

Tanner C. Jankins, Philip M. Blank, Andrea Brugnetti, Philip Boehm, Françoise A. Aouane and Bill Morandi

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-53281-7

Enzymatic Metal–Hydrogen Atom Transfer with a Cobalt Protoporphyrin Cofactor

Carly L. Masonheimer, Michael J. Rourke, Reece S. Gardner, Ryan L. Hall, Lydia J. Perkins, Thomas C. Brunold and Andrew R. Buller

J. Am. Chem. Soc., 2026, 148, 5443
DOI: 10.1021/jacs.5c19000

Merging Double Hydrogen Atom Transfer and Stepwise Proton-Coupled Electron Transfer for γ-C–H Hydrazination of Alcohols

Kaiming Zuo, Phong Dam, Kosala N. Amarasinghe, Anke Spannenberg, Jabor Rabeah, Olga S. Bokareva, Luis Miguel Azofra and Osama El-Sepelgy

JACS Au, 2026, 6, 1012
DOI: 10.1021/jacsau.5c01435

Scalable Total Synthesis of (−)-Triptonide: Serendipitous Discovery of a Visible-Light-Promoted Olefin Coupling Initiated by Metal-Catalyzed Hydrogen Atom Transfer (MHAT)

Xianhe Fang, Nan Zhang, Si-Cong Chen and Tuoping Luo

J. Am. Chem. Soc., 2022, 144, 2292
DOI: 10.1021/jacs.1c12525

Recent Progress in Asymmetric Oxidative Radical–Polar Crossover Reactions

Xiaochong Guo, Kangping Wu and Mianling Zhang

Adv Synth Catal, 2026, 368
DOI: 10.1002/adsc.70315

A Dual Cobalt and Photoredox Catalysis for Hydrohalogenation of Alkenes

Shotaro Shibutani, Kazunori Nagao and Hirohisa Ohmiya

J. Am. Chem. Soc., 2024, 146, 4375
DOI: 10.1021/jacs.3c10133

Branched-Selective Hydroacylation of Alkenes via Photoredox Cobalt and N-Heterocyclic Carbene Cooperative Triple Catalysis

Xiangzhang Tao, Qing Wang, Lingyu Kong, Shengyang Ni, Yi Pan and Yi Wang

ACS Catal., 2022, 12, 15241
DOI: 10.1021/acscatal.2c04970

Iron‐Catalyzed Wacker‐type Oxidation of Olefins at Room Temperature with 1,3‐Diketones or Neocuproine as Ligands**

Florian Puls, Philipp Linke, Olga Kataeva and Hans‐Joachim Knölker

Angew Chem Int Ed, 2021, 60, 14083
DOI: 10.1002/anie.202103222

Asymmetric Total Synthesis of Norzoanthamine

Zhengyuan Xin, Hui Wang, Haibing He, Xiaoli Zhao and Shuanhu Gao

Angewandte Chemie, 2021, 133, 12917
DOI: 10.1002/ange.202102643

Photochemische Cobaltkatalysierte Synthese von Heterozyklen durch die Zykloisomerisierung Nichtaktivierter Olefine

Henry Lindner, Willi M. Amberg, Tristano Martini, David M. Fischer, Eléonore Moore and Erick M. Carreira

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202319515

Strategy Evolution in a Skeletal Remodeling and C–H Functionalization-Based Synthesis of the Longiborneol Sesquiterpenoids

Robert F. Lusi, Goh Sennari and Richmond Sarpong

J. Am. Chem. Soc., 2022, 144, 17277
DOI: 10.1021/jacs.2c08136

Influence of Cage Effects in Directing the Outcome of C–X Bond Forming Reactions

Zihang Qiu and Constanze N. Neumann

ACS Org. Inorg. Au, 2024, 4, 1
DOI: 10.1021/acsorginorgau.3c00044

Multiple Deuterium Atom Transfer Perdeuteration of Unactivated Alkenes under Base‐Assisted Cobalt/Photoredox Dual Catalysis

Akihiko Suzuki, Kosuke Higashida, Tatsuhiko Yoshino and Shigeki Matsunaga

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500233

Stereocontrolled Radical Bicyclizations of Oxygenated Precursors Enable Short Syntheses of Oxidized Abietane Diterpenoids

Darius Vrubliauskas, Benjamin M. Gross and Christopher D. Vanderwal

J. Am. Chem. Soc., 2021, 143, 2944
DOI: 10.1021/jacs.0c13300

Nickel‐Catalyzed Switchable Site‐Selective Alkene Hydroalkylation by Temperature Regulation**

Jia‐Wang Wang, De‐Guang Liu, Zhe Chang, Zhen Li, Yao Fu and Xi Lu

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205537

Controlling Chemoselectivity of Catalytic Hydroboration with Light

Enrico Bergamaschi, Danijela Lunic, Liam A. McLean, Melissa Hohenadel, Yi‐Kai Chen and Christopher J. Teskey

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202114482

Synthetic and Mechanistic Studies into the Reductive Functionalization of Nitro Compounds Catalyzed by an Iron(salen) Complex

Emily Pocock, Martin Diefenbach, Thomas M. Hood, Michael Nunn, Emma Richards, Vera Krewald and Ruth L. Webster

J. Am. Chem. Soc., 2024, 146, 19839
DOI: 10.1021/jacs.4c02797

Mechanistic Studies on the Hexadecafluorophthalocyanine–Iron‐Catalyzed Wacker‐Type Oxidation of Olefins to Ketones**

Florian Puls, Felix Seewald, Vadim Grinenko, Hans‐Henning Klauß and Hans‐Joachim Knölker

Chemistry A European J, 2021, 27, 16776
DOI: 10.1002/chem.202102848

Markovnikov-Selective Hydroboration of Unactivated Alkenes via MHAT under Cobalt/Photoredox Dual Catalysis

Yusuke Seino, Shintaro Dozen, Tatsuhiko Yoshino, Kosuke Higashida and Shigeki Matsunaga

Org. Lett., 2026, 28, 2771
DOI: 10.1021/acs.orglett.6c00348

(Salen)Titanium‐Catalyzed Asymmetric Hydrogen Atom Transfer for Epoxides Reduction

Zhongyun Xu, Jian Shen, Longfei Li, Wanjiao Chen, Shengxiao Li, Jie Jiang and Yong‐Qiang Zhang

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202214111

Directed Hydrogen Atom Transfer for Selective Reactions of Polyenols

Daniel E. Essayan, Matthew J. Schubach, Jeanelle M. Smoot, Taranee Puri and Sergey V. Pronin

J. Am. Chem. Soc., 2024, 146, 18224
DOI: 10.1021/jacs.4c06601

On the role of thermally activated EDA complexes in decarboxylative cross-coupling

Nathan Dao and Ryan A. Shenvi

Tetrahedron, 2024, 166, 134204
DOI: 10.1016/j.tet.2024.134204

A new reaction framework for allyl carboxylates

Gaoyuan Zhao, Arman Khosravi, Sahil Sharma, Djamaladdin G. Musaev and Ming-Yu Ngai

Trends in Chemistry, 2025, 7, 99
DOI: 10.1016/j.trechm.2024.12.004

Divergent Total Syntheses of (−)-Crinipellins Facilitated by a HAT-Initiated Dowd–Beckwith Rearrangement

Yifan Zhao, Jialei Hu, Ruyi Chen, Fengping Xiong, Hujun Xie and Hanfeng Ding

J. Am. Chem. Soc., 2022, 144, 2495
DOI: 10.1021/jacs.1c13370

Radical Rearrangement of Terminal Epoxides to Methyl Ketones via Cobalt Photocatalysis

Brian Funk, Michael Yasuda and Julian G. West

Org. Lett., 2026, 28, 6281
DOI: 10.1021/acs.orglett.6c01341

Photo‐Initiated Cobalt‐Catalyzed Radical Olefin Hydrogenation

Sier Sang, Tobias Unruh, Serhiy Demeshko, Luis I. Domenianni, Nicolaas P. van Leest, Philipp Marquetand, Felix Schneck, Christian Würtele, Felix J. de Zwart, Bas de Bruin, Leticia González, Peter Vöhringer and Sven Schneider

Chemistry A European J, 2021, 27, 16978
DOI: 10.1002/chem.202101705

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Tariq Ali, Haiyan Wang, Waseem Iqbal, Tariq Bashir, Rahim Shah and Yong Hu

Advanced Science, 2023, 10
DOI: 10.1002/advs.202205077

From Sweet Molecular Giants to Square Sugars and Vice Versa

Philippe Compain

Synlett, 2023, 34, 1866
DOI: 10.1055/s-0042-1751449

Merging Hydrogen Atom Transfer and Halogen Atom Transfer for Iodide-Catalyzed Radical Reductive Cyclization of 1,6-Enynes

Linglong Ding, Yi-Hui Deng, Tian-Yu Sun, Yuqin Jiang and Xiao-Feng Xia

Org. Lett., 2022, 24, 3113
DOI: 10.1021/acs.orglett.2c00552

Hydrodealkenylative C(sp3)–C(sp2) Bond Fragmentation Using Isayama–Mukaiyama Peroxidation

Jeremy H. Dworkin, Zhuoxi M. Chen, Kathleen C. Cheasty, Aris V. Rubio and Ohyun Kwon

J. Am. Chem. Soc., 2025, 147, 13531
DOI: 10.1021/jacs.5c00540

Asymmetric Total Syntheses of Hetidine-Type C20-Diterpenoid Alkaloids: Spirasines V and VI, Spiradine D, and the Proposed Structures of Spirafines II and III

Fengjie Yao, Yufei Wu, Yidian Sheng, Kuan Yu, Peirong Rao, Jun Xuan and Hanfeng Ding

J. Am. Chem. Soc., 2025, 147, 39004
DOI: 10.1021/jacs.5c13564

Mechanism of Alkene Hydrofunctionalization by Oxidative Cobalt(salen) Catalyzed Hydrogen Atom Transfer

Conner V. Wilson and Patrick L. Holland

J. Am. Chem. Soc., 2024, 146, 2685
DOI: 10.1021/jacs.3c12329

Recent developments for the synthesis of the dihydroisoquinolin-1(2H)-ones via cyclization of N-allylbenzamides

Yan-Ning Niu, Ke-Yu Wang, Feng-Yan Han and Xiao-Feng Xia

Tetrahedron, 2025, 174, 134497
DOI: 10.1016/j.tet.2025.134497

Synthesis of Primary Amines via Hydrogen Atom Transfer-Initiated Cyclization/Reduction Cascade of Unsaturated Nitriles

Henry Lindner, Michael Schneider, Philipp Mader, Frederic Su and Erick M. Carreira

Org. Lett., 2024, 26, 5467
DOI: 10.1021/acs.orglett.4c01739

Redirecting Formate Delivery toward Alkenes: Markovnikov α-Carboxylation via Cobalt/Photoredox/Bro̷nsted Acid Catalysis

Shantanu Nandi, Souvik Majumder, Alejandro García-Eguizábal, Ignacio Funes-Ardoiz and Dorota Gryko

J. Am. Chem. Soc., 2025, 147, 44984
DOI: 10.1021/jacs.5c13504

Electrochemical hydroxylation of alkenes with H2O

Guoqing Yang, Jingpei Jia, Yuan Deng and Youai Qiu

National Science Review, 2026, 13
DOI: 10.1093/nsr/nwag047

Building Catalytic Reactions One Electron at a Time

Julian G. West

Acc. Chem. Res., 2024, 57, 3068
DOI: 10.1021/acs.accounts.4c00515

Photocatalytic hydrogenation of alkenes using ammonia-borane

Eva Rivera-Chao, Wesley J. Olivier, Michael J. Tilby and Daniele Leonori

Chem, 2026, 12, 102711
DOI: 10.1016/j.chempr.2025.102711

cis‐Aziridines From Terminal Alkenes via Diastereoselective Intramolecular Electrocatalytic Hydroamination

Ahhyeon Choi, Hyeonseo Kim, Daniel Yim, Hyungjun Kim and Hyunwoo Kim

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.4116549

Mn-Mediated α-Radical Addition of Carbonyls to Olefins: Systematic Study, Scope, and Electrocatalysis

Sylvain Charvet, Maurice Médebielle and Julien C. Vantourout

J. Org. Chem., 2022, 87, 5690
DOI: 10.1021/acs.joc.2c00054

A Nickel Complex with a Proton-Responsive PNP Pincer-Type Ligand as a Proton-Coupled Electron Transfer Reagent

Jyotima Mukherjee, Nils Ostermann, Xaiza Aniban, Inna Safianova, Nils Rotthowe, Ricardo Mata and Inke Siewert

Organometallics, 2023, 42, 3258
DOI: 10.1021/acs.organomet.3c00378

Generation of α‐Boryl Radicals by H. Transfer and their Use in Cycloisomerizations

Shicheng Shi, Farbod Salahi, Hunter B. Vibbert, Maleeha Rahman, Scott A. Snyder and Jack R. Norton

Angewandte Chemie, 2021, 133, 22860
DOI: 10.1002/ange.202107665

Remote Steric and Electronic Effects of N-Heterocyclic Carbene Ligands on Alkene Reactivity and Regioselectivity toward Hydrocupration Reactions: The Role of Expanded-Ring N-Heterocyclic Carbenes

Aqeel A. Hussein and Azhar Ariffin

J. Org. Chem., 2023, 88, 13009
DOI: 10.1021/acs.joc.3c01121

Intramolecular Hydrogen Atom Transfer Hydroarylation of Alkenes toward δ-Lactams Using Cobalt-Photoredox Dual Catalysis

Yuto Yamaguchi, Yusuke Seino, Akihiko Suzuki, Yuji Kamei, Tatsuhiko Yoshino, Masahiro Kojima and Shigeki Matsunaga

Org. Lett., 2022, 24, 2441
DOI: 10.1021/acs.orglett.2c00700

Photocatalytic phosphine-mediated water activation for radical hydrogenation

Jingjing Zhang, Christian Mück-Lichtenfeld and Armido Studer

Nature, 2023, 619, 506
DOI: 10.1038/s41586-023-06141-1

Where Enantioselection is Set: A Mechanistic Framework for Asymmetric Hydrogen‐Atom Transfer

Zhongyun Xu, Yufeng Yang and Yong‐Qiang Zhang

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202526135

Navigating the Bio‐Inspired Structure‐Function Landscape: Spectroscopy Driven Finding of Hidden Radical Oxidation in Co‐porphyrinic Porous Organic Polymer

Bishal Boro, Chandan Biswas, Thanh Huyen Vuong, Subhajit Nandy, Abhijit Shrotri, Yuta Tsuji, Jabor Rabeah and John Mondal

Small Methods, 2026, 10
DOI: 10.1002/smtd.202501981

An evolved artificial radical cyclase enables the construction of bicyclic terpenoid scaffolds via an H-atom transfer pathway

Dongping Chen, Xiang Zhang, Anastassia Andreevna Vorobieva, Ryo Tachibana, Alina Stein, Roman P. Jakob, Zhi Zou, Damian Alexander Graf, Ang Li, Timm Maier, Bruno E. Correia and Thomas R. Ward

Nat. Chem., 2024, 16, 1656
DOI: 10.1038/s41557-024-01562-5

Intramolecular Radical Oxygen-Transfer Reactions Using Nitroarenes

Jonas Elfert, Anup Bhunia, Constantin G. Daniliuc and Armido Studer

ACS Catal., 2023, 13, 6704
DOI: 10.1021/acscatal.3c00958

Cobalt‐Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines

Huanran Miao, Meihui Guan, Tao Xiong, Ge Zhang and Qian Zhang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202213913

Isocyanide Activation by Phosphinimide-Ligated Cr(II) Centers

Paul Rathke and Jonathan Rittle

Organometallics, 2025, 44, 2520
DOI: 10.1021/acs.organomet.5c00278

Markovnikov hydroamination of terminal alkenes by phosphine redox catalysis

Flora Fan, Kassandra F. Sedillo, Alexander J. Maertens and Abigail G. Doyle

Nature, 2026, 652, 96
DOI: 10.1038/s41586-026-10263-7

A Triple Photoredox/Cobalt/Brønsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes

Masanari Nakagawa, Yuki Matsuki, Kazunori Nagao and Hirohisa Ohmiya

J. Am. Chem. Soc., 2022, 144, 7953
DOI: 10.1021/jacs.2c00527

Stereodivergent, Kinetically Controlled Isomerization of Terminal Alkenes via Nickel Catalysis

Camille Z. Rubel, Anne K. Ravn, Hang Chi Ho, Shenghua Yang, Zi‐Qi Li, Keary M. Engle and Julien C. Vantourout

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202320081

Cobalt-Catalyzed Markovnikov-Selective Radical Hydroacylation of Unactivated Alkenes with Acylphosphonates

Benxiang Zhang, Jiayan He, Yi Li, Tao Song, Yewen Fang and Chaozhong Li

J. Am. Chem. Soc., 2021, 143, 4955
DOI: 10.1021/jacs.1c02629

Photo‐ and Electrochemical Cobalt Catalysed Hydrogen Atom Transfer for the Hydrofunctionalisation of Alkenes

Samikshan Jana, Victor J. Mayerhofer and Christopher J. Teskey

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202304882

Metal-Hydride C–C Cross-Coupling of Alkenes Through a Double Outer-Sphere Mechanism

Nathan Dao, Xu-cheng Gan and Ryan. A. Shenvi

J. Org. Chem., 2024, 89, 16106
DOI: 10.1021/acs.joc.4c00260

Fe-Catalyzed Hydroallylation of Unactivated Alkenes with Vinyl Cyclopropanes

Biplab Mondal, Subhadeep Hazra, Ayan Chatterjee, Manveer Patel and Jaideep Saha

Org. Lett., 2023, 25, 5676
DOI: 10.1021/acs.orglett.3c02105

Enhanced Excited-State Hydricity of Pd–H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes

Sumon Sarkar, Soumen Ghosh, Daria Kurandina, Yusuf Noffel and Vladimir Gevorgyan

J. Am. Chem. Soc., 2023, 145, 12224
DOI: 10.1021/jacs.3c02410

Cobalt Hydride-Catalyzed Hydroalkynylation of Alkenes with Alkynyl Trifluoroborates

Meihui Guan, Ting Yin, Yue Wang, Huanran Miao, Ge Zhang and Qian Zhang

ACS Catal., 2024, 14, 9294
DOI: 10.1021/acscatal.4c02211

Nickel-catalyzed alkene ipso-selective reductive hydroamination with nitroarenes

Zhen Li, Jiawang Wang, Xi Lu and Yao Fu

zgkxjsdxxb, 2022, 52, 1
DOI: 10.52396/JUSTC-2022-0119

One-Electron Approach for Trans-Selective Alkyne Semi-Reduction via Cobalt Catalysis

Rakesh Mondal, Lior Galmidi, Avra Tzaguy, Tal Sason, Moran Feller, Mark A. Iron, Liat Avram, Ronny Neumann and Samer Gnaim

J. Am. Chem. Soc., 2025, 147, 41272
DOI: 10.1021/jacs.5c07630

Enantioselective Divergent Total Syntheses of Cycloaurenones and Dysiherbols

Yu‐Hao Huang, Qing‐Xiu Gu, Qing‐Cen Chao, Han‐Zhi Xiao and Hai‐Hua Lu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202507638

Concise Total Synthesis of Salimabromide

Hai-Hua Lu, Kang-Ji Gan, Fu-Qiang Ni, Zhihan Zhang and Yao Zhu

J. Am. Chem. Soc., 2022, 144, 18778
DOI: 10.1021/jacs.2c08337

Role of Steric Effects on Rates of Hydrogen Atom Transfer Reactions

Yi Sun, Fengjiao Liu, Jacob N. Sanders and K. N. Houk

J. Org. Chem., 2023, 88, 12668
DOI: 10.1021/acs.joc.3c01361

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Donghao Jiang, Xinzhu Li, Mengdie Xiao and Li‐Jie Cheng

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202412828

Remote C–H Amination and Alkylation of Camphor at C8 through Hydrogen-Atom Abstraction

Goh Sennari, Hiroki Yamagishi and Richmond Sarpong

J. Am. Chem. Soc., 2024, 146, 7850
DOI: 10.1021/jacs.4c01351

Cobalt‐Catalyzed Hydroglycosylation of Alkynes for the Synthesis of Vinyl α‐C‐Glycosides

Jia‐Xi Wang, Yuan Yao, Yingwei Wang and Dawen Niu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202423631

Repurposing myoglobin into an abiological asymmetric ketoreductase

Xiang Zhang, Dongping Chen, Julian Stropp, Ryo Tachibana, Zhi Zou, Daniel Klose and Thomas R. Ward

Chem, 2024, 10, 2577
DOI: 10.1016/j.chempr.2024.06.010

Efficient O-deallylation triggered by cobalt hydride-catalyzed oxidative hydrofunctionalization

Yun-Nian Yin, Han-Yuan Liu, Dong-Chen Ouyang, Qing Zhang and Rong Zhu

Green Synthesis and Catalysis, 2023, 4, 64
DOI: 10.1016/j.gresc.2022.01.005

Manganese/Enzyme Sequential Catalytic Pathway for the Production of Optically Active γ-Functionalized Alcohols

Meng Deng, Jiaqi Yang, Zhiyi Kong, Yaning Li, Quanpeng Wang, Huan Liu, Shu-Zhen Deng and Nan Li

J. Org. Chem., 2024, 89, 9103
DOI: 10.1021/acs.joc.4c00776

Synthesis and target annotation of the alkaloid GB18

Stone Woo and Ryan A. Shenvi

Nature, 2022, 606, 917
DOI: 10.1038/s41586-022-04840-9

Co-Catalyzed Hydrofluorination of Alkenes: Photocatalytic Method Development and Electroanalytical Mechanistic Investigation

Jinjian Liu, Jian Rong, Devin P. Wood, Yi Wang, Steven H. Liang and Song Lin

J. Am. Chem. Soc., 2024, 146, 4380
DOI: 10.1021/jacs.3c10989

Photoinduced Cobalt Catalysis for the Reductive Coupling of Pyridines and Dienes Enabled by Paired Single‐Electron Transfer**

Jingyang Qin, Manuel Barday, Samikshan Jana, Nil Sanosa, Ignacio Funes‐Ardoiz and Christopher J. Teskey

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310639

Enantiospecific 1,3-hydrogen transfer of alkenes and alkynes

Qi Liu, Wan-Yi Xu, Cen-Cen You, Rong-Gui Zhou and Ying He

Trends in Chemistry, 2024, 6, 627
DOI: 10.1016/j.trechm.2024.08.004

Annulation Producing Diverse Heterocycles Promoted by Cobalt Hydride

Takuma Sugimura, Ren Yamada, Wataru Kanna, Tsuyoshi Mita, Satoshi Maeda, Bartłomiej Szarłan and Hiroki Shigehisa

ACS Catal., 2024, 14, 15514
DOI: 10.1021/acscatal.4c05195

Cobalt‐Catalyzed Asymmetric Alkylation of (Hetero)Arenes with Styrenes

Tao Qin, Guowei Lv, Huanran Miao, Meihui Guan, Chunlu Xu, Ge Zhang, Tao Xiong and Qian Zhang

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202201967

Anilido-Oxazoline-Ligated Iron Alkoxide Complexes for Living Ring-Opening Polymerization of Cyclic Esters with Controllability

Yu Pan, Mingyang Hao, Xia Li, Yi Meng, Xiaohui Kang, Gangqiang Zhang, Xingrun Sun, Xue-Zhi Song, Lin Zhang and Yat-Ming So

Inorg. Chem., 2025, 64, 530
DOI: 10.1021/acs.inorgchem.4c04028

1,3-Difunctionalization of [1.1.1]propellane through iron-hydride catalyzed hydropyridylation

Changha Kim, Yuhyun Kim and Sungwoo Hong

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-50356-3