Tracking Initial Fe(II)-Driven Ferrihydrite Transformations: A Mössbauer Spectroscopy and Isotope Investigation

Drew Latta, Kevin M. Rosso and Michelle M. Scherer

ACS Earth Space Chem., 2023, 7, 1814
DOI: 10.1021/acsearthspacechem.2c00291

Photoinduced transformation of ferrihydrite in the presence of aqueous sulfite and its influence on the repartitioning of Cd

Jinwen Qiu, Xiaokang Hou, Yuan Ren, Chengshuai Liu, Fangyuan Meng, Jyh-Fu Lee, Yu-Jung Lin, Ziyuan Huang, Huanxin Ma, Zhenqing Shi and Chunhua Feng

Water Research, 2023, 231, 119607
DOI: 10.1016/j.watres.2023.119607

Short-Chain Carboxylic Acids Influencing Mineralization Mechanisms of Ferrihydrite Transformation to Hematite and Goethite

Xiaofan Pan, Xin Huang and Ning Deng

Environ. Sci. Technol., 2025, 59, 12910
DOI: 10.1021/acs.est.5c00455

Geochemical Decoupling of Iron and Zinc during Transformation of Zn-Bearing Ferrihydrite in Reducing Sediments

Pierre Lefebvre, Andrew R. C. Grigg and Ruben Kretzschmar

Environ. Sci. Technol., 2024, 58, 20224
DOI: 10.1021/acs.est.4c09261

Quantifying Sulfidization and Non-Sulfidization in Long-Term In-Situ Microbial Colonized As(V)-Ferrihydrite Coated Sand Columns: Insights into as Mobility

Di Zhang, Wei Xiu, Cui Ren, Guangyu Chen, Jonathan R. Lloyd, Naji M. Bassil, Laura A. Richards, David A. Polya and Huaming Guo

SSRN Journal, 2022
DOI: 10.2139/ssrn.4156386

Regulation of ferrihydrite biotransformation by Fe(II) supply rates and extracellular polymeric substances

Anxu Sheng, Yurong Deng, Yuefei Ding, Linxin Cheng, Yuyan Liu, Xiaoxu Li, Yuji Arai and Juan Liu

Geochimica et Cosmochimica Acta, 2024, 385, 87
DOI: 10.1016/j.gca.2024.08.029

Iron Oxyhydroxide Transformation in a Flooded Rice Paddy Field and the Effect of Adsorbed Phosphate

Katrin Schulz, Worachart Wisawapipat, Kurt Barmettler, Andrew R. C. Grigg, L. Joëlle Kubeneck, Luiza Notini, Laurel K ThomasArrigo and Ruben Kretzschmar

Environ. Sci. Technol., 2024, 58, 10601
DOI: 10.1021/acs.est.4c01519

Physical Contact between Bacteria and Carbonaceous Materials: The Key Switch Triggering Activated Carbon and Biochar to Promote Microbial Iron Reduction

Lin Shen, Xiao Zhu, Haoze Jiang, Juntao Zhang, Chengyu Chen, John R. Reinfelder, Andreas Kappler, Liping Fang, Tongxu Liu, Chuanping Liu, Yundang Wu and Fangbai Li

Environ. Sci. Technol., 2025, 59, 9576
DOI: 10.1021/acs.est.4c14024

Effects of coexisting goethite or lepidocrocite on Fe(II)-induced ferrihydrite transformation pathways and Cd speciation

Meiling Yin, Xin Li, Chuling Guo, Qiaohui Zhong, Xiaofei Li, Lijuan Zeng, Yuting Zhou, Chen Yang and Zhi Dang

Science of The Total Environment, 2025, 959, 178321
DOI: 10.1016/j.scitotenv.2024.178321

Kinetics of Mn(II) adsorption and catalytic oxidation on the surface of ferrihydrite

Shuai Lan, Zhangjie Qin, Xiaoming Wang, Yupeng Yan, Yadong Tang, Xionghan Feng and Qin Zhang

Science of The Total Environment, 2021, 791, 148225
DOI: 10.1016/j.scitotenv.2021.148225

Sunlight-Driven Transformation of Ferrihydrite via Ligand-to-Metal Charge Transfer: The Critical Factors and Arsenic Repartitioning

Cheng Wang, Chaoyun Ying, Wentao Wang, Shuijing Zhou, Biao Wan, Wenfeng Tan and Xionghan Feng

Environ. Sci. Technol., 2025, 59, 6567
DOI: 10.1021/acs.est.4c11046

Coupled redox cycling of Fe and Mn in the environment: The complex interplay of solution species with Fe- and Mn-(oxyhydr)oxide crystallization and transformation

Jing Liu, Qingze Chen, Yixuan Yang, Hongyan Wei, Minwang Laipan, Runliang Zhu, Hongping He and Michael F. Hochella

Earth-Science Reviews, 2022, 232, 104105
DOI: 10.1016/j.earscirev.2022.104105

A New Approach for Investigating Iron Mineral Transformations in Soils and Sediments Using 57Fe-Labeled Minerals and 57Fe Mössbauer Spectroscopy

Luiza Notini, Katrin Schulz, L. Joëlle Kubeneck, Andrew R. C. Grigg, Katherine A. Rothwell, Giulia Fantappiè, Laurel K. ThomasArrigo and Ruben Kretzschmar

Environ. Sci. Technol., 2023, 57, 10008
DOI: 10.1021/acs.est.3c00434

Impact of Zn substitution on Fe(II)-induced ferrihydrite transformation pathways

Jinshu Yan, Andrew J. Frierdich and Jeffrey G. Catalano

Geochimica et Cosmochimica Acta, 2022, 320, 143
DOI: 10.1016/j.gca.2022.01.014

Diagenetic iron-oxyhydroxides formed in suboxic to anoxic mine-impacted lake sediments near Sudbury, Ontario

Birendra Sapkota and Tom Al

Chemical Geology, 2024, 658, 122131
DOI: 10.1016/j.chemgeo.2024.122131

Microbial community mediates hydroxyl radical production in soil slurries by iron redox transformation

Dan Wan, Fei-Fei Liu, Jiu-Bin Chen, Andreas Kappler, Yakov Kuzyakov, Cong-Qiang Liu and Guang-Hui Yu

Water Research, 2022, 220, 118689
DOI: 10.1016/j.watres.2022.118689

Enrichment and fractionation of rare earth elements (REEs) in ion-adsorption-type REE deposits: Constraints of an iron (hydr)oxide-clay mineral composite

Xiaoliang Liang, Puqiu Wu, Gaoling Wei, Yiping Yang, Shichao Ji, Lingya Ma, Jingwen Zhou, Wei Tan, Jianxi Zhu, Yoshio Takahashi and Maarten A.T.M. Broekmans

American Mineralogist, 2025, 110, 114
DOI: 10.2138/am-2023-9217

Understanding the Importance of Labile Fe(III) during Fe(II)-Catalyzed Transformation of Metastable Iron Oxyhydroxides

Juan Liu, Anxu Sheng, Xiaoxu Li, Yuji Arai, Yuefei Ding, Mingjun Nie, Mingquan Yan and Kevin M. Rosso

Environ. Sci. Technol., 2022, 56, 3801
DOI: 10.1021/acs.est.1c08044

Ab Initio Evaluation of Solid-State Transformation Pathways from Ferrihydrite to Goethite

Michel Sassi and Kevin M. Rosso

ACS Earth Space Chem., 2022, 6, 800
DOI: 10.1021/acsearthspacechem.2c00026

Fe(II) Redox Chemistry in the Environment

Jianzhi Huang, Adele Jones, T. David Waite, Yiling Chen, Xiaopeng Huang, Kevin M. Rosso, Andreas Kappler, Muammar Mansor, Paul G. Tratnyek and Huichun Zhang

Chem. Rev., 2021, 121, 8161
DOI: 10.1021/acs.chemrev.0c01286

Coexisting Goethite Promotes Fe(II)-Catalyzed Transformation of Ferrihydrite to Goethite

Luiza Notini, Laurel K. ThomasArrigo, Ralf Kaegi and Ruben Kretzschmar

Environ. Sci. Technol., 2022, 56, 12723
DOI: 10.1021/acs.est.2c03925

The effects of different iron and phosphorus treatments on the formation and morphology of iron plaque in rice roots (Oryza sativa L)

Haoran Hu, Liyan Bi, Lei Wang, Fangdong Zhan, Xinran Liang, Li Qin and Yuan Li

Front. Plant Sci., 2024, 14
DOI: 10.3389/fpls.2023.1304505

A model towards understanding stabilities and crystallization pathways of iron (oxyhydr)oxides in redox-dynamic environments

Xiaoxu Li, Anxu Sheng, Yuefei Ding and Juan Liu

Geochimica et Cosmochimica Acta, 2022, 336, 92
DOI: 10.1016/j.gca.2022.09.002

Fe(II)-Catalyzed Transformation of Ferrihydrite with Different Degrees of Crystallinity

Yuyan Liu, Yuefei Ding, Anxu Sheng, Xiaoxu Li, Jiawei Chen, Yuji Arai and Juan Liu

Environ. Sci. Technol., 2023, 57, 6934
DOI: 10.1021/acs.est.3c00555

Arsenic redistribution associated with Fe(II)-induced jarosite transformation in the presence of polygalacturonic acid

Xiaohu Jin, Chuling Guo, Qi Huang, Xueqin Tao, Xiaofei Li, Yingying Xie, Zhi Dang, Jiangmin Zhou and Guining Lu

Science of The Total Environment, 2024, 935, 173444
DOI: 10.1016/j.scitotenv.2024.173444

Abiotic Attenuation of Nitrobenzene Controlled by Reduction Capacity Shifts during Fe(II)aq–Catalyzed Ferrihydrite Transformation

Xin Li, Huixiang Zhang, Shanshan Yang, Juan Liu and Fei Liu

Environ. Sci. Technol., 2025, 59, 12958
DOI: 10.1021/acs.est.5c01613

Transformation of 2-Line Ferrihydrite to Goethite at Alkaline pH

Fabio E. Furcas, Barbara Lothenbach, Shishir Mundra, Camelia N. Borca, Cristhiana Carine Albert, O. Burkan Isgor, Thomas Huthwelker and Ueli M. Angst

Environ. Sci. Technol., 2023, 57, 16097
DOI: 10.1021/acs.est.3c05260

Structure and composition of natural ferrihydrite nano-colloids in anoxic groundwater

Maya Engel, Vincent Noël, Samuel Pierce, Libor Kovarik, Ravi K. Kukkadapu, Juan S. Lezama Pacheco, Odeta Qafoku, J. Ray Runyon, Jon Chorover, Weijiang Zhou, John Cliff, Kristin Boye and John R. Bargar

Water Research, 2023, 238, 119990
DOI: 10.1016/j.watres.2023.119990

Labile Fe(III) supersaturation controls nucleation and properties of product phases from Fe(II)-catalyzed ferrihydrite transformation

Anxu Sheng, Juan Liu, Xiaoxu Li, Langli Luo, Yuefei Ding, Chunmei Chen, Xin Zhang, Chongmin Wang and Kevin M. Rosso

Geochimica et Cosmochimica Acta, 2021, 309, 272
DOI: 10.1016/j.gca.2021.06.027

Quantifying sulfidization and non-sulfidization in long-term in-situ microbial colonized As(V)-ferrihydrite coated sand columns: Insights into As mobility

Di Zhang, Tiantian Ke, Wei Xiu, Cui Ren, Guangyu Chen, Jonathan R. Lloyd, Naji M. Bassil, Laura A. Richards, David A. Polya, Guangcai Wang and Huaming Guo

Science of The Total Environment, 2023, 858, 160066
DOI: 10.1016/j.scitotenv.2022.160066

Pore-Size-Dependent Kinetics and Product Distribution of Fe(II)-Catalyzed Ferrihydrite Transformation

Linxin Cheng, Yuefei Ding, Yuanyuan Liu, Jing Chen, Xiaohui Wu, Juan Liu, Linling Wang and Anxu Sheng

Environ. Sci. Technol., 2025, 59, 12667
DOI: 10.1021/acs.est.5c03094