Single-crystalline Mg-substituted Na4Mn3(PO4)2P2O7 nanoparticles as a high capacity and superior cycling cathode for sodium-ion batteries

Hanxue Xu, Jixian Ma, Xuexia He, Jie Sun, Longhai Yang, Ruibin Jiang, Zhibin Lei, Zong-huai Liu and Qi Li

Nanoscale, 2023, 15, 4830
DOI: 10.1039/D2NR05442F

High-rate stability of Na3V2(PO4)2F3 sodium-ion cathode materials enabled by an entropy-increasing strategy

Peifeng Wang, Zhuohui Sun, Kai Zhang, Hongwei Zhang, Xianghua Yao and Youlong Xu

J. Mater. Chem. A, 2025, 13, 25855
DOI: 10.1039/D5TA02224J

Effect of chelator content on the structural and electrochemical performance of Na3V2(PO4)2F3 by sol–gel preparation

Yuanyuan Qin, Long Li, Hongyang Zhao, Mingyue Wang, Xinyang Li, Jing Zhao, Hu Wu and Shujiang Ding

CrystEngComm, 2022, 24, 4519
DOI: 10.1039/D2CE00322H

Nanotechnology engineering of polyanionic Na3V2(PO4)2F3 cathodes toward high-performance sodium-ion batteries

Jiahao Chen, Xingjie Wu, Zhiyong Luo, Xinxian Ren, Junhao Chen, Minjie Chen, Chunliu Xu, Yao Xiao and Weiqing Yang

Chem. Sci., 2026, 17, 6848
DOI: 10.1039/D5SC10141G

High-rate Na0.7Li2.3V2(PO4)2F3 hollow sphere cathode prepared via a solvothermal and electrochemical ion exchange approach for lithium ion batteries

Ayan Mukherjee, Rosy, Tali Sharabani, Ilana Perelshtein and Malachi Noked

J. Mater. Chem. A, 2020, 8, 21289
DOI: 10.1039/D0TA07912J

Aluminum substitution for vanadium in the Na3V2(PO4)2F3 and Na3V2(PO4)2FO2 type materials

Jacob Olchowka, Long H. B. Nguyen, Thibault Broux, Paula Sanz Camacho, Emmanuel Petit, François Fauth, Dany Carlier, Christian Masquelier and Laurence Croguennec

Chem. Commun., 2019, 55, 11719
DOI: 10.1039/C9CC05137F

Na3V2(PO4)2F3–SWCNT: a high voltage cathode for non-aqueous and aqueous sodium-ion batteries

Shuang Liu, Liubin Wang, Jian Liu, Meng Zhou, Qingshun Nian, Yazhi Feng, Zhanliang Tao and Lianyi Shao

J. Mater. Chem. A, 2019, 7, 248
DOI: 10.1039/C8TA09194C

A comprehensive review on the fabrication, modification and applications of Na3V2(PO4)2F3 cathodes

Lin Zhu, Hong Wang, Dan Sun, Yougen Tang and Haiyan Wang

J. Mater. Chem. A, 2020, 8, 21387
DOI: 10.1039/D0TA07872G

Engineering the crystal orientation of Na3V2(PO4)2F3@rGO microcuboids for advanced sodium-ion batteries

Lin Zhu, Qi Zhang, Dan Sun, Qi Wang, Nana Weng, Yougen Tang and Haiyan Wang

Mater. Chem. Front., 2020, 4, 2932
DOI: 10.1039/D0QM00364F

An iron-doped NASICON type sodium ion battery cathode for enhanced sodium storage performance and its full cell applications

Jae Yeol Park, Yoonsu Shim, Yong-il Kim, Yuseon Choi, Ho Jun Lee, Jungjae Park, Ji Eun Wang, Yonghee Lee, Joon Ha Chang, Kanghoon Yim, Chi Won Ahn, Chan-Woo Lee, Do Kyung Kim and Jong Min Yuk

J. Mater. Chem. A, 2020, 8, 20436
DOI: 10.1039/D0TA07766F

Investigation on photocatalytic mechanism of graphitic SiC (g-SiC)/MoS2 van der Waals heterostructured photocatalysts for overall water splitting

Xu Gao, Yanqing Shen, Yanyan Ma, Shengyao Wu and Zhongxiang Zhou

Phys. Chem. Chem. Phys., 2019, 21, 15372
DOI: 10.1039/C9CP02792K

Well-dispersed Na3V2(PO4)2F3@rGO with improved kinetics for high-power sodium-ion batteries

Feng Li, Yifei Zhao, Lishuang Xia, Zhendong Yang, Jinping Wei and Zhen Zhou

J. Mater. Chem. A, 2020, 8, 12391
DOI: 10.1039/D0TA00130A

Boosting sodium-ion mobility in Na3V2(PO4)2F3 through anion engineering with Br− substitution

Sankalpita Chakrabarty, Ziliang Wang, Arun Krishnan, Arad Paperni, Sarah Taragin, Reut Yemini, Ilana Perelshtein, Ayan Mukherjee and Malachi Noked

J. Mater. Chem. A, 2025, 13, 33294
DOI: 10.1039/D5TA05400A

Phosphate-based cathode materials to boost the electrochemical performance of sodium-ion batteries

Archana Kanwade, Sheetal Gupta, Akash Kankane, Abhishek Srivastava, Subhash Chand Yadav and Parasharam M. Shirage

Sustainable Energy Fuels, 2022, 6, 3114
DOI: 10.1039/D2SE00475E

2D-lamellar stacked Na3V2(PO4)2F3@RuO2 as a high-voltage, high-rate capability and long-term cycling cathode material for sodium ion batteries

Yu Zhang, Jiahong Xun, Kaiyuan Zhang, Bo Zhang and Huayun Xu

J. Mater. Chem. A, 2022, 10, 11163
DOI: 10.1039/D1TA11010A

Zwitterionic polymer-derived nitrogen and sulfur co-doped carbon-coated Na3V2(PO4)2F3 as a cathode material for sodium ion battery energy storage

Tianyi Lu, Xiaobo Yu, Xiaokai Li, Jiawei Qi, Shu Huang, Zu Man and Haitao Zhuo

New J. Chem., 2021, 45, 19391
DOI: 10.1039/D1NJ03779J

Particle nanosizing and coating with an ionic liquid: two routes to improve the transport properties of Na3V2(PO4)2FO2

Jacob Olchowka, Runhe Fang, Rafael Bianchini Nuernberg, Chloé Pablos, Dany Carlier, Sophie Cassaignon and Laurence Croguennec

Nanoscale, 2022, 14, 8663
DOI: 10.1039/D2NR01080A

The application of hollow micro-/nanostructured cathodes for sodium-ion batteries

Xiao-Hao Liu, Wei-Hong Lai and Shu-Lei Chou

Mater. Chem. Front., 2020, 4, 1289
DOI: 10.1039/C9QM00674E

Boosting the capacity and stability of Na3V2(PO4)2F3-2xO2x microspheres, using atomic layer deposition of artificial CEI

Sankalpita Chakrabarty, Tali Sharabani, Sarah Taragin, Reut Yemini, Ananya Maddegalla, Ilana Perelshtein, Ayan Mukherjee and Malachi Noked

Journal of Energy Storage, 2024, 84, 111507
DOI: 10.1016/j.est.2024.111507

Understanding crystal structures, ion diffusion mechanisms and sodium storage behaviors of NASICON materials

Ranjusha Rajagopalan, Zhengna Zhang, Yougen Tang, Chuankun Jia, Xiaobo Ji and Haiyan Wang

Energy Storage Materials, 2021, 34, 171
DOI: 10.1016/j.ensm.2020.09.007

Carbon-coating-increased working voltage and energy density towards an advanced Na3V2(PO4)2F3@C cathode in sodium-ion batteries

Zhen-Yi Gu, Jin-Zhi Guo, Zhong-Hui Sun, Xin-Xin Zhao, Wen-Hao Li, Xu Yang, Hao-Jie Liang, Chen-De Zhao and Xing-Long Wu

Science Bulletin, 2020, 65, 702
DOI: 10.1016/j.scib.2020.01.018

Sodium Rich Vanadium Oxy‐Fluorophosphate – Na3.2Ni0.2V1.8(PO4)2F2O – as Advanced Cathode for Sodium Ion Batteries

Rachid Essehli, Hamdi Ben Yahia, Ruhul Amin, Mengya Li, Daniel Morales, Steven G. Greenbaum, Ali Abouimrane, Anand Parejiya, Abdelfattah Mahmoud, Khalid Boulahya, Marm Dixit and Ilias Belharouak

Advanced Science, 2023, 10
DOI: 10.1002/advs.202301091

Mn–Doped Hollow Na3V2O2(PO4)2F as a High Performance Cathode Material for Sodium Ion Batteries

Peng Du, Kan Mi, Fangdong Hu, Xiaolei Jiang and Xiuwen Zheng

Eur J Inorg Chem, 2021, 2021, 1256
DOI: 10.1002/ejic.202001159

Boosting sodium-ion battery performance using Na3(VO)2(PO4)2F microrods self-embedded in a 3D conductive interpenetrated framework

Qiao Hu, Guangming Han, Jiaying Liao and Jianfeng Yao

Journal of Alloys and Compounds, 2024, 988, 174261
DOI: 10.1016/j.jallcom.2024.174261

Sodium Superionic Conductors (NASICONs) as Cathode Materials for Sodium-Ion Batteries

Qingbo Zhou, Linlin Wang, Wenyao Li, Kangning Zhao, Minmin Liu, Qian Wu, Yujie Yang, Guanjie He, Ivan P. Parkin, Paul R. Shearing, Dan J. L. Brett, Jiujun Zhang and Xueliang Sun

Electrochem. Energy Rev., 2021, 4, 793
DOI: 10.1007/s41918-021-00120-8

Three-dimensional ordered microporous Na3V2(PO4)2F3@C/Carbon cloth as High-rate and stable flexible cathodes for Na-ion and Zn-ion batteries

Rui Ling, Shuting Zhao, Chao Yang and Wentao Qi

Applied Surface Science, 2023, 620, 156875
DOI: 10.1016/j.apsusc.2023.156875

Construction of superior performance LiVPO4F/C cathode assisting by a regulating additive NH4F and the “Combination-Protection-Release” mechanism for lithium ion batteries

Weihua Zhang, Peng Gao, Zhuang Hu, Changling Fan, Ruisheng Zhang, Caiwang Cai, Shaochang Han, Jinshui Liu and Jilei Liu

Journal of Power Sources, 2022, 523, 231024
DOI: 10.1016/j.jpowsour.2022.231024

Vanadium substituted Fe, Cr co-doped high performance C/Na3V2(PO4)2F3 cathode for sodium-ion batteries

Sanchayan Mahato, Sayan Das, Debakshi Gupta and Koushik Biswas

Journal of Electroanalytical Chemistry, 2024, 955, 118046
DOI: 10.1016/j.jelechem.2024.118046

Unraveling the mechanism of optimal concentration for Fe substitution in Na3V2(PO4)2F3/C for Sodium-Ion batteries

Long Li, Youlong Xu, Rui Chang, Chao Wang, Shengnan He and Xiangdong Ding

Energy Storage Materials, 2021, 37, 325
DOI: 10.1016/j.ensm.2021.01.029

Data‐Driven Design of NASICON‐Type Electrodes Using Graph‐Based Neural Networks

Yoonsu Shim, Incheol Jeong, Junpyo Hur, Hyoungjeen Jeen, Seung‐Taek Myung, Kang Taek Lee, Seungbum Hong, Jong Min Yuk and Chan‐Woo Lee

Batteries & Supercaps, 2024, 7
DOI: 10.1002/batt.202400186

Unraveling the storage mechanism of Na3V2−xNix(PO4)2F3/C cathodes for sodium-ion batteries through electrochemical, operando X-ray diffraction and microscopy studies

Simranjot K. Sapra, Jeng-Kuei Chang and Rajendra S. Dhaka

Energy Storage Materials, 2025, 81, 104478
DOI: 10.1016/j.ensm.2025.104478

Low temperature hydrothermal synthesis of Na3Fe2(PO4)2F3 and its cathode electrochemistry in Na- and Li-ion batteries

Subal Chandra Manna, Prashanth Sandineni and Amitava Choudhury

Journal of Solid State Chemistry, 2021, 295, 121922
DOI: 10.1016/j.jssc.2020.121922

High‐ionicity fluorophosphate lattice via aliovalent substitution as advanced cathode materials in sodium‐ion batteries

Zhen‐Yi Gu, Jin‐Zhi Guo, Xin‐Xin Zhao, Xiao‐Tong Wang, Dan Xie, Zhong‐Hui Sun, Chen‐De Zhao, Hao‐Jie Liang, Wen‐Hao Li and Xing‐Long Wu

InfoMat, 2021, 3, 694
DOI: 10.1002/inf2.12184

Trace polytetrafluoroethylene constructing Na3V2(PO4)3/Na3V2(PO4)2F3 heterostructure with multi-electron reaction and self-enhanced built-in electric field

Yuru Zhao, Bingbing Wang, Que Huang, Changcheng Liu, Yuelei Pan, Li Guo and Yanjun Chen

Energy Storage Materials, 2025, 81, 104462
DOI: 10.1016/j.ensm.2025.104462

Dual carbon-confined Na2MnPO4F nanoparticles as a superior cathode for rechargeable sodium-ion battery

Rui Ling, Shu Cai, Kaier Shen, Zhiyuan Sang, Dongli Xie, Jiayue Sun, Kunzhou Xiong, Jinze Guo and Xiaohong Sun

Ceramics International, 2019, 45, 19799
DOI: 10.1016/j.ceramint.2019.06.235

Achieving a Rapid Na+ Migration and Highly Reversible Phase Transition of NASICON for Sodium‐Ion Batteries with Suppressed Voltage Hysteresis and Ultralong Lifespan

Qiao Wu, Yuanzhen Ma, Shengqiang Zhang, Xin Chen, Jinbo Bai, Hui Wang and Xiaojie Liu

Small, 2024, 20
DOI: 10.1002/smll.202404660

Development and challenge of advanced nonaqueous sodium ion batteries

Yi Sun, Pengcheng Shi, Jingjuan Chen, Qiujie Wu, Xin Liang, Xianhong Rui, Hongfa Xiang and Yan Yu

EnergyChem, 2020, 2, 100031
DOI: 10.1016/j.enchem.2020.100031

The review of sodium and potassium-ion battery advances in density functional theory: Progresses, challenges and prospects

Mei Yang, Shuling Chen, Yunqi Jia and Liuzhang Ouyang

Materials Science and Engineering: R: Reports, 2026, 167, 101097
DOI: 10.1016/j.mser.2025.101097

In-situ structural evolution analysis of Zr-doped Na3V2(PO4)2F3 coated by N-doped carbon layer as high-performance cathode for sodium-ion batteries

Chuan Guo, Jianwei Yang, Zhiyuan Cui, Shuo Qi, Qianqian Peng, Weiwei Sun, Li-Ping Lv, Yi Xu, Yong Wang and Shuangqiang Chen

Journal of Energy Chemistry, 2022, 65, 514
DOI: 10.1016/j.jechem.2021.06.015

In situ redox reaction induced firmly anchoring of Na3V2(PO4)2F3 on reduced graphene oxide & carbon nanosheets as cathodes for high stable sodium-ion batteries

Yue Zhang, Ting Wang, Yakun Tang, Yudai Huang, Dianzeng Jia, Yong Guo and Zhen Zhou

Journal of Power Sources, 2021, 516, 230515
DOI: 10.1016/j.jpowsour.2021.230515

Recent progress and strategic perspectives of high-voltage Na3V2(PO4)2F3 cathode: Fundamentals, modifications, and applications in sodium-ion batteries

Yu-Hao Chen, Yi-Han Zhao, Shu-Hui Tian, Peng-Fei Wang, Feilong Qiu and Ting-Feng Yi

Composites Part B: Engineering, 2023, 266, 111030
DOI: 10.1016/j.compositesb.2023.111030

Hollow structured cathode materials for rechargeable batteries

Xiaobo Zhu, Jiayong Tang, Hengming Huang, Tongen Lin, Bin Luo and Lianzhou Wang

Science Bulletin, 2020, 65, 496
DOI: 10.1016/j.scib.2019.12.008

Lattice‐Interface Dual Engineering Unlocking Quasi‐Zero‐Strain and High‐Rate Zinc‐Ion Storage in Polyanionic Cathode

Qiaofeng Huang, Sheng Ouyang, Jiarui Lin, Rui Jiang, Jiajie Zhou, Xiaoyan Shi, Junling Xu, Lianyi Shao and Zhipeng Sun

Advanced Science, 2026, 13
DOI: 10.1002/advs.202521583

Recent advances in high energy-density cathode materials for sodium-ion batteries

Yingchun Lyu, Yuchen Liu, Zhuo-Er Yu, Na Su, Yang Liu, Wenxian Li, Qian Li, Bingkun Guo and Bin Liu

Sustainable Materials and Technologies, 2019, 21, e00098
DOI: 10.1016/j.susmat.2019.e00098

Improved sodium storage properties of Zr-doped Na3V2(PO4)2F3/C as cathode material for sodium ion batteries

Mingxue Wang, Kun Wang, Xiaobing Huang, Tao Zhou, Huasheng Xie and Yurong Ren

Ceramics International, 2020, 46, 28490
DOI: 10.1016/j.ceramint.2020.08.006

Electrolyte Design with Dual –C≡N Groups Containing Additives to Enable High-Voltage Na3V2(PO4)2F3-Based Sodium-Ion Batteries

Mingqin Jiang, Tianyu Li, Yanling Qiu, Xin Hou, Hongzhen Lin, Qiong Zheng and Xianfeng Li

J. Am. Chem. Soc., 2024, 146, 12519
DOI: 10.1021/jacs.4c00702

Microwave-Assisted Hydrothermal Synthesis of Na3V2(PO4)2F3 Nanocuboid@Reduced Graphene Oxide as an Ultrahigh-Rate and Superlong-Lifespan Cathode for Fast-Charging Sodium-Ion Batteries

Jieduo Guan, Shilin Zhou, Jiajie Zhou, Fangdan Wu, Xiaoyan Shi, Junling Xu, Lianyi Shao, Zhiqiang Luo and Zhipeng Sun

ACS Appl. Mater. Interfaces, 2024
DOI: 10.1021/acsami.4c01894

Mg-doped Na3V2-xMgx(PO4)2F3@C sodium ion cathodes with enhanced stability and rate capability

Yusheng Zhang, Youzuo Hu, Tingting Feng, Ziqiang Xu and Mengqiang Wu

Journal of Power Sources, 2024, 602, 234337
DOI: 10.1016/j.jpowsour.2024.234337

Rational Design of Phosphate Cathodes with Improved Na-storage Performance

Xusheng Zhang, Huican Mao, Zhao Chen, Lin Zhou, Lilu Liu, Mingxuan Wu, Zilong Lv, Zhihao Zhang, Yukun Zhong, Yong-Sheng Hu and Junmei Zhao

ACS Energy Lett., 2025, 10, 2804
DOI: 10.1021/acsenergylett.5c00653

Phase-manipulated hierarchically core-shell Na3(VO1-xPO4)2F1+2x (0≤x≤1)@Na3V2(PO4)3 and its synergistic effect with conformally wrapped reduced graphene oxide framework towards high-performance cathode for sodium-ion batteries

Jiarong He, Tao Tao, Fan Yang, Zhipeng Sun and Haitao Huang

Materials Today Physics, 2022, 27, 100813
DOI: 10.1016/j.mtphys.2022.100813

Three‐Sodium Ion Activity of a Hollow Spherical Na3V2(PO4)2F3 Cathode: Demonstrating High Capacity and Stability

Ayan Mukherjee, Tali Sharabani, Ilana Perelshtein and Malachi Noked

Batteries & Supercaps, 2020, 3, 52
DOI: 10.1002/batt.201900147

Aliovalent‐Ion‐Induced Lattice Regulation Based on Charge Balance Theory: Advanced Fluorophosphate Cathode for Sodium‐Ion Full Batteries

Zhen‐Yi Gu, Jin‐Zhi Guo, Zhong‐Hui Sun, Xin‐Xin Zhao, Xiao‐Tong Wang, Hao‐Jie Liang, Bo Zhao, Wen‐Hao Li, Xiu‐Mei Pan and Xing‐Long Wu

Small, 2021, 17
DOI: 10.1002/smll.202102010

Three‐Dimensional Graphene Network Decorated with Highly Symmetrical Cuboid Na3V2(PO4)2F3 Particles: High Rate Capability and Cycling Stability for Sodium‐Ion Batteries

Shuyuan Xu, Huijun Li and Xiaomin Wang

ChemElectroChem, 2021, 8, 866
DOI: 10.1002/celc.202001514

Manganese‐based polyanionic cathodes for sodium‐ion batteries

Yubin Niu, Yanan Zhao and Maowen Xu

Carbon Neutralization, 2023, 2, 150
DOI: 10.1002/cnl2.48

A Novel Na4MnCr(PO4)2F3 Cathode with High Energy Density for Sodium-Ion Batteries

Jiahui Liu, Tongyu Liu, Yoshiyuki Kawazoe and Qiang Sun

J. Phys. Chem. Lett., 2023, 14, 7759
DOI: 10.1021/acs.jpclett.3c01750

An investigation of the effects of a high valence state dopant (Zr4+) and the experimental insertion of two Na+ ions in the NaVOPO4 matrix

Neelaveni A, Senthil K, Kalaivani R, Nalini B and Sivakumar N

Current Applied Physics, 2023, 55, 64
DOI: 10.1016/j.cap.2023.09.001

Dual carbon skeleton supported NVPFO sodium-ion battery cathode with high rate capability, superior cycling performance, and wide temperature adaptability

Jianhui Ma, Xihong Zu, Xueqing Qiu and Wenli Zhang

Chemical Engineering Journal, 2024, 493, 152792
DOI: 10.1016/j.cej.2024.152792

Optimizing the Mg Doping Concentration of Na3V2–xMgx(PO4)2F3/C for Enhanced Sodiation/Desodiation Properties

Diah Agustina Puspitasari, Jagabandhu Patra, I-Ming Hung, Dominic Bresser, Tai-Chou Lee and Jeng-Kuei Chang

ACS Sustainable Chem. Eng., 2021, 9, 6962
DOI: 10.1021/acssuschemeng.1c00418

Nanostructured Electrode Materials for Advanced Sodium-Ion Batteries

Yongjin Fang, Xin-Yao Yu and Xiong Wen (David) Lou

Matter, 2019, 1, 90
DOI: 10.1016/j.matt.2019.05.007

Optimizing high voltage Na3V2(PO4)2F3 cathode for achieving high rate sodium-ion batteries with long cycle life

Yuvaraj Subramanian, Woong Oh, Woosung Choi, Hayeon Lee, Mihee Jeong, Ranjith Thangavel and Won-Sub Yoon

Chemical Engineering Journal, 2021, 403, 126291
DOI: 10.1016/j.cej.2020.126291

Surfactant-assisted synthesis of self-assembled Na3V2(PO4)2F3@C microspheres as the cathode for Na-ion batteries

Shi-jie Wang, Kang Liang, Jian-bin Li, Xiao-bing Huang and Yu-rong Ren

Vacuum, 2023, 211, 111894
DOI: 10.1016/j.vacuum.2023.111894

CTAB-Assisted Synthesis of C@Na3V2(PO4)2F3 With Optimized Morphology for Application as Cathode Material for Na-Ion Batteries

Ana Criado, Pedro Lavela, Gregorio F. Ortiz, José L. Tirado, Somaya Gzouli, Zineb Edfouf and Carlos Pérez-Vicente

Front. Phys., 2019, 7
DOI: 10.3389/fphy.2019.00207

Improved sodium storage properties of co-doped Na3V2(PO4)2F3@graphene as anode material for sodium ion batteries

Jing Cao, Yongfeng Wang, Yayi Chen, Zhao Li, Lu Deng, Kunyao Wu and Yalan Wang

Ferroelectrics, 2021, 584, 221
DOI: 10.1080/00150193.2021.1984770

Scalable and Economic Synthesis of High-Performance Na3V2(PO4)2F3 by a Solvothermal–Ball-Milling Method

Hongming Yi, Le Lin, Moxiang Ling, Zhiqiang Lv, Rui Li, Qiang Fu, Huamin Zhang, Qiong Zheng and Xianfeng Li

ACS Energy Lett., 2019, 4, 1565
DOI: 10.1021/acsenergylett.9b00748

A combined first principles and experimental study on Al-doped Na3V2(PO4)2F3 cathode for rechargeable Na batteries

Shu-Han Zhuang, Chun-Chuen Yang, Mingtao Zheng, Subadevi Rengapillai, Sivakumar Marimuthu, Yu-Shen Chiang, Bor Kae Chang, Chia-Hung Huang and Wei-Ren Liu

Surface and Coatings Technology, 2022, 434, 128184
DOI: 10.1016/j.surfcoat.2022.128184

NASICON-structured Na3MnTi(PO4)2.83F0.5 cathode with high energy density and rate performance for sodium-ion batteries

Jiefei Liu, Yu Zhao, Xiaofeng Huang, Yu Zhou, Kwok-ho Lam, Denis Y.W. Yu and Xianhua Hou

Chemical Engineering Journal, 2022, 435, 134839
DOI: 10.1016/j.cej.2022.134839

Unveiling the Effect of Al Doping on the Sodium Iron Hexacyanoferrate Cathode for the Development of High‐Performance Na‐Ion Battery

P. Mohana Sundaram, Soumyashree Das Adhikari, P. Sennu, Vineeth Sasikumar Kala, C. Sanjaykumar, Rahul Singh, Md Osama Zubair, Mahesh Chandra, Hemant Kumar and Vipin Kumar

Batteries & Supercaps, 2026, 9
DOI: 10.1002/batt.70367

Boosting sodium-ion battery performance with binary metal-doped Na3V2(PO4)2F3 cathodes

Jie Wang, Qiming Liu, Shiyue Cao, Huijuan Zhu and Yilin Wang

Journal of Colloid and Interface Science, 2024, 665, 1043
DOI: 10.1016/j.jcis.2024.04.003

Optimizing Sc-Doped Na3V2(PO4)2F3/C as a High-Performance Cathode Material for Sodium-Ion Battery Applications

Shaokang Guo, Jian Peng, Neeraj Sharma, Jiaqi Pan, Yi Liao, Xinhao An, Hanchi Li, Zhisong Ge, Chunliang Zhou, Wen Liang Tan and Junnan Liu

Chem. Mater., 2025, 37, 1500
DOI: 10.1021/acs.chemmater.4c02872

Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

Xinyuan Wang, Fan Zhang, Xingyu Zhou, Qian Wang, Changyu Liu, Yangyang Liu, Hui Wang and Xiaojie Liu

Journal of Energy Chemistry, 2025, 100, 509
DOI: 10.1016/j.jechem.2024.08.064

Doping Engineering of Sodium Vanadium Fluorophosphates Cathodes for Sodium-Ion Batteries

Rakyung Kim, Minjun Hwang and Ho Seok Park

Korean J. Chem. Eng., 2026, 43, 57
DOI: 10.1007/s11814-025-00388-2

Investigating the structure, electronic properties, and ion migration of Na3V2(PO4)3 cathodes via mono/multi-element doping of Cr, Fe, and Si

Meng Gao, Haiyuan Chen and Xiaobin Niu

Solid State Ionics, 2024, 406, 116456
DOI: 10.1016/j.ssi.2024.116456

Improved electrochemical performance of high voltage cathode Na3V2(PO4)2F3 for Na-ion batteries through potassium doping

Leyi Li, Xiaohao Liu, Linbin Tang, Haimei Liu and Yong-Gang Wang

Journal of Alloys and Compounds, 2019, 790, 203
DOI: 10.1016/j.jallcom.2019.03.127

Recent advances of NASICON-Na3V2(PO4)3 as cathode for sodium-ion batteries: Synthesis, modifications, and perspectives

Bowen Zhang, Kaixuan Ma, Xin Lv, Kun Shi, Yuan Wang, Zhiyang Nian, Yuehua Li, Ling Wang, Lei Dai and Zhangxing He

Journal of Alloys and Compounds, 2021, 867, 159060
DOI: 10.1016/j.jallcom.2021.159060

Dual-site doping strategy for enhancing the rate and cycling performance of Na3V2(PO4)2F3 cathode

Yanyan Li, Qiong Liu, Tong Liu, Juanjuan Wang, Yingying Liu, Yaxuan Cai, Haiting Lv, Kangzhe Cao and Yang Fan

Journal of Power Sources, 2025, 652, 237694
DOI: 10.1016/j.jpowsour.2025.237694

Synthesis of nano-Na3V2(PO4)2F3 cathodes with excess Na+ intercalation for enhanced capacity

Manhua Peng, Xiayan Wang and Guangsheng Guo

Applied Materials Today, 2020, 19, 100554
DOI: 10.1016/j.apmt.2020.100554

High-voltage Na 3 V 2 (PO 4 ) 2 F 3 cathodes enabled by low-valence metal cations

Yutian Chen, Deyan Luan, Hao Zhao, Siyang Meng, Jianwei Li, Zhiming Liu and Xiong Wen (David) Lou

Sci. Adv., 2026, 12
DOI: 10.1126/sciadv.aed1452

Substitution of Iron for Vanadium in Phosphate Fluoride Positive Electrode Materials for Na-Ion Batteries

Sofie Knies, Hafssa Arraghraghi, Giovanni Gammaitoni, Stefan Seidlmayer, Lorenzo Stievano and Matteo Bianchini

Chem. Mater., 2025, 37, 5129
DOI: 10.1021/acs.chemmater.5c00806

Vanadium-based polyanionic compounds as cathode materials for sodium-ion batteries: Toward high-energy and high-power applications

Zhiqiang Lv, Moxiang Ling, Meng Yue, Xianfeng Li, Mingming Song, Qiong Zheng and Huamin Zhang

Journal of Energy Chemistry, 2021, 55, 361
DOI: 10.1016/j.jechem.2020.07.008

Heterointerface charge reorganization enables high-voltage sodium storage in NASICON-type cathodes

Shuoshuo Cheng, Chenchen Song, Miaorui Yang, Fan Li, Zhiyu Song, Shiyu Li, Peng Lv and Ying Bai

Energy Storage Materials, 2026, 86, 105024
DOI: 10.1016/j.ensm.2026.105024

Boosting sodium-ion battery performance with vanadium substituted Fe, Ni dual doped fluorophosphate cathode over a wide temperature range

Sanchayan Mahato and Koushik Biswas

Journal of Power Sources, 2025, 626, 235734
DOI: 10.1016/j.jpowsour.2024.235734

Fiber-Shape Na3V2(PO4)2F3@N-Doped Carbon as a Cathode Material with Enhanced Cycling Stability for Na-Ion Batteries

Yunsha Li, Xinghui Liang, Guobin Zhong, Chao Wang, Shijia Wu, Kaiqi Xu and Chenghao Yang

ACS Appl. Mater. Interfaces, 2020, 12, 25920
DOI: 10.1021/acsami.0c05490

Achieving the Stable Structure and Superior Performance of Na3V2(PO4)2O2F Cathodes via Na-Site Regulation

Jing Liu, Lu-Lu Zhang, Xing-Zhong Cao, Xing Lin, Yue Shen, Peng Zhang, Cheng Wei, Yang-Yang Huang, Wei Luo and Xue-Lin Yang

ACS Appl. Energy Mater., 2020, 3, 7649
DOI: 10.1021/acsaem.0c01077

Iron–Manganese Dual-Doping Tailors the Electronic Structure of Na3V2(PO4)2F3 for High-Performance Sodium-Ion Batteries

Jien Li, Shuang Luo, Renjie Li, Yingkai Hua, Linlong Lyu, Xiangjun Pu, Jun Fan and Zheng-Long Xu

Nano-Micro Lett., 2026, 18
DOI: 10.1007/s40820-025-01881-3

Manganese-based polyanionic cathode materials for sodium-ion batteries with high energy and long lifespan

Muhammad Munaim Khan, Yanshuo Zhao, Qi Liu, Wenxiu He, Daobin Mu, Li Li, Renjie Chen and Feng Wu

Journal of Energy Storage, 2025, 116, 116038
DOI: 10.1016/j.est.2025.116038

NASICON-Structured Na2VTi(PO4)3@C for Symmetric Aqueous Rechargeable Na-Ion Batteries with Long Lifespan

Liuxue Shen, Huiya Yang, Yu Jiang, Junlin Ma, Tongrui Sun, Minwei Zhang and Nan Zhu

ACS Sustainable Chem. Eng., 2021, 9, 3490
DOI: 10.1021/acssuschemeng.0c07755

Iron-Doped Sodium–Vanadium Fluorophosphates: Na3V2–yO2–yFey(PO4)2F1+y (y < 0.3)

Verónica Palomares, Amaia Iturrondobeitia, Paula Sanchez-Fontecoba, Damian Goonetilleke, Neeraj Sharma, Luis Lezama and Teófilo Rojo

Inorg. Chem., 2020, 59, 854
DOI: 10.1021/acs.inorgchem.9b03111

Boosting rate and cycling performance of K-doped Na3V2(PO4)2F3 cathode for high-energy-density sodium-ion batteries

Jiexin Zhang, YangYang Lai, Peng Li, Yanxia Wang, Faping Zhong, Xiangming Feng, Weihua Chen, Jianjun Liu, Xinping Ai, Hanxi Yang and Yuliang Cao

Green Energy & Environment, 2022, 7, 1253
DOI: 10.1016/j.gee.2021.01.001

Effect of Crystal Structure and Morphology on Na3V2(PO4)2F3 Performances for Na‐Ion Batteries

Ayan Mukherjee, Tali Sharabani, Rosy Sharma, Sivan Okashy and Malachi Noked

Batteries & Supercaps, 2020, 3, 510
DOI: 10.1002/batt.201900202

Dual‐Carbon‐Coated Na2FeP2O7 Cathode Materials for Na‐Ion Batteries with Superior High‐Rate and Cycling Stability

Linlin Zhou, Haifeng Yu, Bin Zhou, Jinxun Yu, Ling Chen and Hao Jiang

Adv Energy and Sustain Res, 2024, 5
DOI: 10.1002/aesr.202400120

Monitoring the Crystal Structure and the Electrochemical Properties of Na3(VO)2(PO4)2F through Fe3+ Substitution

Long H. B. Nguyen, Jacob Olchowka, Stéphanie Belin, Paula Sanz Camacho, Mathieu Duttine, Antonella Iadecola, François Fauth, Dany Carlier, Christian Masquelier and Laurence Croguennec

ACS Appl. Mater. Interfaces, 2019, 11, 38808
DOI: 10.1021/acsami.9b14249

Effect of chromium doping on Na3V2(PO4)2F3@C as promising positive electrode for sodium-ion batteries

A. Criado, P. Lavela, C. Pérez-Vicente, G.F. Ortiz and J.L. Tirado

Journal of Electroanalytical Chemistry, 2020, 856, 113694
DOI: 10.1016/j.jelechem.2019.113694

Experimental and computational advancement of cathode materials for futuristic sodium ion batteries

Jena Akash Kumar Satrughna, Archana Kanwade, Abhishek Srivastava, Manish Kumar Tiwari, Subhash Chand Yadav, Surya Teja Akula and Parasharam M. Shirage

Materials Today, 2025, 91, 375
DOI: 10.1016/j.mattod.2023.06.013

Nanoparticles Assembled Microspheres as a High-Rate Cathode Material for Sodium Ion Batteries

Yi Zhuo, Tao Chen, Weifang Liu, Hang Hu, Jianwen Zhang, Penggao Liu, Ruizheng Cai, Xinxin Chen, Jun Yan and Kaiyu Liu

J. Electrochem. Soc., 2019, 166, A10
DOI: 10.1149/2.0251902jes

Doping Regulation in Polyanionic Compounds for Advanced Sodium‐Ion Batteries

Lifen Xiao, Fangjie Ji, Jiexin Zhang, Xumiao Chen and Yongjin Fang

Small, 2023, 19
DOI: 10.1002/smll.202205732

Crystal defect modulation in cathode materials for non-lithium ion batteries: Progress and challenges

Fangyu Xiong, Shuangshuang Tan, Xuhui Yao, Qinyou An and Liqiang Mai

Materials Today, 2021, 45, 169
DOI: 10.1016/j.mattod.2020.12.002

Facile Synthesis of High Electrochemical Performance Na2FePO4F@CNT&GN Cathode Material as Sodium Ion Batteries

Jiahong Xun, Yu Zhang, Bo Zhang, Huayun Xu and Liqiang Xu

ACS Appl. Energy Mater., 2020, 3, 6232
DOI: 10.1021/acsaem.0c00323

A Comprehensive Review on Strategies for Enhancing the Performance of Polyanionic-Based Sodium-Ion Battery Cathodes

Anupama Joy, Khusboo Kumari, Fatma Parween, Mst Shubnur Sultana and Ganesh Chandra Nayak

ACS Omega, 2024, 9, 22509
DOI: 10.1021/acsomega.4c02709

A facile strategy for developing uniform hierarchical Na3V2(PO4)2F3@carbonized polyacrylonitrile multi-clustered hollow microspheres for high-energy-density sodium-ion batteries

Kang Liang, Shijie Wang, Hongshun Zhao, Xiaobing Huang, Yurong Ren, Zhenjiang He, Jing Mao and Junchao Zheng

Chemical Engineering Journal, 2022, 428, 131780
DOI: 10.1016/j.cej.2021.131780

Reversible Na+-extraction/insertion in nitrogen-doped graphene-encapsulated Na3V2(PO4)2F3@C electrode for advanced Na-ion battery

Xujiao Yang, Xianli Wang and Wanzhu Zhen

Ceramics International, 2020, 46, 9170
DOI: 10.1016/j.ceramint.2019.12.167

Effect of Cr3+ doping on the electrochemical performance of Na3V2(PO4)2F3/C cathode materials for sodium ion battery

Xiaoli Yi, Hongyue Luo, Yongmao Zhou, Shihao Feng, Jiexi Wang, Zhixing Wang, Jianguo Duan, Ding Wang, Huajun Guo and Guochun Yan

Electrochimica Acta, 2023, 437, 141491
DOI: 10.1016/j.electacta.2022.141491

Ultra-Fast-Charging, Long-Duration, and Wide-Temperature-Range Sodium Storage Enabled by Multiwalled Carbon Nanotube-Hybridized Biphasic Polyanion-Type Phosphate Cathode Materials

Wen-Long Ma, Yue Zhou, Xiao-Wen Zhao, Xin Cao, Ping Wu, Xiao-Shu Zhu, Shao-Hua Wei, Kang Sun, Haoshen Zhou and Yi-Ming Zhou

ACS Appl. Mater. Interfaces, 2024, 16, 34819
DOI: 10.1021/acsami.4c02565

High-entropy strategy to suppress volumetric strain and enhance diffusion rate of Na3V2(PO4)2F3 cathode for durable and high-areal-capacity zinc-ion battery pouch cells

Jia Xu, Musanna Galib, Zhenrui Wu, Li Tao, Yijia Shao, Yue Zhang, Xiaolong Guo, Evan J. Hansen, Yujin Chen, Zhenbo Wang, Chang Liu, Mauricio Ponga and Jian Liu

Nano Energy, 2024, 132, 110373
DOI: 10.1016/j.nanoen.2024.110373

Hydrothermal Microwave-Assisted Synthesis of Na3+xV2–yMny(PO4)2F3 Solid Solutions as Potential Positive Electrodes for Na-Ion Batteries

Anna R. Iarchuk, Denis V. Sheptyakov and Artem M. Abakumov

ACS Appl. Energy Mater., 2021, 4, 5007
DOI: 10.1021/acsaem.1c00579

Mechanism and enhanced performance of low-dose low-valence molybdenum-doped Na3V2(PO4)2F2O cathodes for sodium batteries

Lingzhi Wang, Anastase Ndahimana, Xiaofei Sun, Qinghe Bo, Quansheng Li, Haitao Wang and Xuesong Mei

Journal of Power Sources, 2024, 608, 234594
DOI: 10.1016/j.jpowsour.2024.234594

Improved Electrochemical Performance of NASICON Type Na3V2–xCox(PO4)3/C (x = 0–0.15) Cathode for High Rate and Stable Sodium-Ion Batteries

Simranjot K. Sapra, Jeng-Kuei Chang and Rajendra S. Dhaka

ACS Appl. Mater. Interfaces, 2024, 16, 43535
DOI: 10.1021/acsami.4c07348

Critical roles of RuO2 nano-particles in enhancing cyclic and rate performance of LISICON Li3V2(PO4)3 cathode materials

Linnan Bi, Zhicui Song, Xiaoqin Liu, Zhuang Miao, Qiaoji Zheng, Chenggang Xu and Dunmin Lin

Journal of Alloys and Compounds, 2020, 845, 156271
DOI: 10.1016/j.jallcom.2020.156271

Highly dispersed oleic-induced nanometric C@Na3V2(PO4)2F3 composites for efficient Na-ion batteries

A. Criado, P. Lavela, G. Ortiz, J.L. Tirado, C. Pérez-Vicente, N. Bahrou and Z. Edfouf

Electrochimica Acta, 2020, 332, 135502
DOI: 10.1016/j.electacta.2019.135502

Mnx+ Substitution to Improve Na3V2(PO4)2F3-Based Electrodes for Sodium-Ion Battery Cathode

Renyuan Su, Weikai Zhu, Kang Liang, Peng Wei, Jianbin Li, Wenjun Liu and Yurong Ren

Molecules, 2023, 28, 1409
DOI: 10.3390/molecules28031409

Enabling boosted Na+ migration of sodium vanadium fluorophosphate by V-site doping for advanced sodium-ion batteries

Xiaodong Hou, Qiao Wu, Xianmeng Wang, Xiaojie Liu and Jinxiang Diao

J Nanopart Res, 2026, 28
DOI: 10.1007/s11051-026-06551-y

Regulation on Morphology and Electronic Structure Design of Vanadium‐Based Sodium Phosphate Cathodes for High‐Performance Sodium‐Ion Batteries

Xinran Qi, Baoxiu Hou, Ruifang Zhang, Xiaocui Chen, Zhenrong Fu, Xin Zhou, Haiyan Liu, Ningzhao Shang, Shuaihua Zhang, Longgang Wang, Chunsheng Li, Jianjun Song, Shuangqiang Chen and Xiaoxian Zhao

Carbon Energy, 2025, 7
DOI: 10.1002/cey2.70030

Manipulating the Phase Compositions of Na3(VO1–xPO4)2F1+2x (0 ≤ x ≤ 1) and Their Synergistic Effects with Reduced Graphene Oxide toward High-Rate Sodium-Ion Batteries

Jiarong He, Tao Tao, Fan Yang and Zhipeng Sun

ACS Appl. Mater. Interfaces, 2021, 13, 60099
DOI: 10.1021/acsami.1c21271

Ti Substitution Strategy Improves Electrochemical Performance of Na3V2(PO4)2F3 Cathode

Qingxia Hu, Mengjiao Sun, Yunchun Zha, Guiquan Zhao, Hanlin Tang, Li Yang, Mou Yang, Bohuai Pang, Yongjiang Sun and Hong Guo

ACS Energy Lett., 2025, 10, 1840
DOI: 10.1021/acsenergylett.5c00315

Modification of the morphology of Na3V2(PO4)2F3 as cathode material for sodium-ion batteries by polyvinylpyrrolidone

Weikai Zhu, Kang Liang and Yurong Ren

Ceramics International, 2021, 47, 17192
DOI: 10.1016/j.ceramint.2021.03.030

Construction of superior performance Na3V2-xCrx(PO4)2F3/C cathode by homovalent doping strategy toward enhanced sodium ion storage

Caiwang Cai, Qianyi Liu, Zhuang Hu, Shilin Chen, Weihua Zhang, Zhiyong Wang, Jilei Liu and Changling Fan

Journal of Power Sources, 2023, 571, 233080
DOI: 10.1016/j.jpowsour.2023.233080

Strategies to increase the stability and energy density of NVPF– A comprehensive review

Ramon Alberto Paredes Camacho, Xinyu Wang, Xiaoyu Xu, Yumei Wang, Qiang Yi, Tian Wu and Li Lu

Funct. Mater. Lett., 2023, 16
DOI: 10.1142/S1793604723400076

Ration design of porous Mn-doped Na3V2(PO4)3 cathode for high rate and super stable sodium-ion batteries

Junqi Fang, Suqing Wang, Xiang Yao, Xinchao Hu, Ying Wang and Haihui Wang

Electrochimica Acta, 2019, 295, 262
DOI: 10.1016/j.electacta.2018.10.150

Dynamic Fluorine Compensation Strategy Purifies Na3V2(PO4)2F3 Phase Toward High‐Energy and Stable Sodium Storage

Peifeng Wang, Xiao Ma, Pu Yang, Jingyi An and Youlong Xu

Small, 2025, 21
DOI: 10.1002/smll.202506046

Research progress on Na3V2(PO4)2F3-based cathode materials for sodium-ion batteries

Kang Liang, Daxiong Wu, Yurong Ren, Xiaobing Huang and Jianmin Ma

Chinese Chemical Letters, 2023, 34, 107978
DOI: 10.1016/j.cclet.2022.107978

Advancements in Chemical Vapor Deposited Carbon Films for Secondary Battery Applications

Jiwoo Kim, Young‐Wook Cho, Sang‐Gil Woo, Je‐Nam Lee and Gwan‐Hyoung Lee

Small, 2025, 21
DOI: 10.1002/smll.202410570

F-Doping improves the electrochemical performance of Na2VTi(PO4)3 as the cathode for sodium-ion battery

Kexin Song, Yulong Zhu, Yingying Jiang, Xiuli Wang, Jifu Ma, Changsong Dai and Li Zhao

Journal of Electroanalytical Chemistry, 2021, 900, 115597
DOI: 10.1016/j.jelechem.2021.115597

Yolk‐Shell Construction of Na3V2(PO4)2F3 with Copper Substitution Microsphere as High‐Rate and Long‐Cycling Cathode Materials for Sodium‐Ion Batteries

Qingbo Zhou, Yingshuai Wang, Runqing Ou, Xiangyu Ding, Yuhang Xin, Feng Wu and Hongcai Gao

Small, 2024, 20
DOI: 10.1002/smll.202310699

Recent research progress in the application of Na3V2(PO4)2F3 cathode materials in sodium-ion batteries: synthesis, modification, and battery optimization

Yining Liang, Lin Xu, Zhengjian Chen, De Ning and Zhipeng Sun

Energy Mater., 2025, 5
DOI: 10.20517/energymater.2024.306

Three-dimensional porous Na4MnV(PO4)3 constructed by Aspergillus niger biological template as a high performance cathode for sodium ion batteries

Jiepeng Chen, Yun Huang, Jiapin liu, Chengwei Li, He Zheng, Xi Xu, Lei Fu, Xing Li, Mingshan Wang, Yuanhua Lin and Haijun Cao

Electrochimica Acta, 2023, 458, 142521
DOI: 10.1016/j.electacta.2023.142521

Structural innovation and electrochemical progress in phosphate-based polyanionic oxide cathodes for high-performance sodium-ion batteries

Zeeshan Qayyum, Wenjing Xu, Qi Liu, Maaz Khan, Lijuan Hou, Muhammad Munaim Khan, Wenxiu He, Daobin Mu, Li Li, Renjie Chen and Feng Wu

Materials Today, 2026, 94, 103218
DOI: 10.1016/j.mattod.2026.103218

N-Doped Carbon Nanotubes Decorated Na3V2(PO4)2F3 as a Durable Ultrahigh-rate Cathode for Sodium Ion Batteries

Taosheng Wang, Wei Zhang, Huangxu Li, Junxian Hu, Yanqing Lai and Zhian Zhang

ACS Appl. Energy Mater., 2020, 3, 3845
DOI: 10.1021/acsaem.0c00283