L. Anders Hammarback, Jonathan B. Eastwood, Thomas J. Burden, Callum J. Pearce, Ian P. Clark, Michael Towrie, Alan Robinson, Ian J. S. Fairlamb and Jason M. Lynam

Chem. Sci., 2022, 13, 9902
DOI: 10.1039/D2SC02562K

Cobalt-catalyzed C–H annulation of aliphatic amides with maleimides: chemodivergent (4 + 1) and (3 + 2) pathways

Celia Sánchez-González, Juan C. Carretero, Inés Alonso, Nuria Rodríguez and Javier Adrio

Org. Chem. Front., 2026
DOI: 10.1039/D6QO00080K

Cp*Co(iii)-catalysed selective alkylation of C–H bonds of arenes and heteroarenes with α-diazocarbonyl compounds

Jayanta Ghorai, Manthena Chaitanya and Pazhamalai Anbarasan

Org. Biomol. Chem., 2018, 16, 7346
DOI: 10.1039/C8OB02111B

Cobalt-catalyzed multisubstituted allylation of the chelation-assisted C–H bond of (hetero)arenes with cyclopropenes

Kuppan Ramachandran and Pazhamalai Anbarasan

Chem. Sci., 2021, 12, 13442
DOI: 10.1039/D1SC03476F

Modification of [2.2]paracyclophane through cobalt-catalyzed ortho-C–H allylation and acyloxylation

Hong Song, Ya Li, Qi-Jun Yao and Bing-Feng Shi

Org. Chem. Front., 2022, 9, 4823
DOI: 10.1039/D2QO00848C

Cobalt(iii)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides

Xiangxiang Chen, Jiangtao Ren, Hu Xie, Wei Sun, Meng Sun and Biao Wu

Org. Chem. Front., 2018, 5, 184
DOI: 10.1039/C7QO00687J

Cobalt(III)-Catalyzed C–H Activation: Azo Directed Selective 1,4-Addition of Ortho C–H Bond to Maleimides

Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

J. Org. Chem., 2017, 82, 6913
DOI: 10.1021/acs.joc.7b01094

Cp*CoIII‐Catalyzed Bis‐isoquinolone Synthesis by C−H Annulation of Arylamide with 1,3‐Diyne

Malay Sen, Rajib Mandal, Ashis Das, Deepti Kalsi and Basker Sundararaju

Chemistry A European J, 2017, 23, 17454
DOI: 10.1002/chem.201704155

Versatile Utility of Cp*Co(III) Catalysts in C–H Amination under Inner- and Outer-Sphere Pathway

Jeonghyo Lee and Sukbok Chang

Synlett, 2023, 34, 1356
DOI: 10.1055/a-1987-6464

Capturing Elusive Cobaltacycle Intermediates: A Real‐Time Snapshot of the Cp*CoIII‐Catalyzed Oxidative Alkyne Annulation

Jesús Sanjosé‐Orduna, Daniel Gallego, Alèria Garcia‐Roca, Eddy Martin, Jordi Benet‐Buchholz and Mónica H. Pérez‐Temprano

Angewandte Chemie, 2017, 129, 12305
DOI: 10.1002/ange.201704744

Reverse Regioselective Cp*Co(III)-Catalyzed [4 + 2] C–H Annulation of N-Chloroamides with Vinylsilanes: Synthesis of 4-Silylated Isoquinolones and Their Synthetic Utilities

Arijit Ghosh, Tamanna Rana, Nilanjan Bhaduri and Amit B. Pawar

Org. Lett., 2023, 25, 7878
DOI: 10.1021/acs.orglett.3c03115

Unravelling Molecular Aspects of the Migratory Insertion Step in Cp*CoIII Metallacyclic Systems

Jesús Sanjosé-Orduna, Jordi Benet-Buchholz and Mónica H. Pérez-Temprano

Inorg. Chem., 2019, 58, 10569
DOI: 10.1021/acs.inorgchem.9b01111

Cobalt(III)‐Catalyzed Enantioselective Intermolecular Carboamination by C−H Functionalization

Kristers Ozols, Shunsuke Onodera, Łukasz Woźniak and Nicolai Cramer

Angew Chem Int Ed, 2021, 60, 655
DOI: 10.1002/anie.202011140

RhI, IrIII ,and CoIII Complexes with Atropchiral Biaryl Cyclopentadienyl Ligands: Syntheses, Structures, and Catalytic Activities

Coralie Duchemin, Gints Smits and Nicolai Cramer

Organometallics, 2019, 38, 3939
DOI: 10.1021/acs.organomet.9b00365

Cobalt(III)-Catalyzed [4 + 2] Annulation of N-Chlorobenzamides with Maleimides

Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

Org. Lett., 2019, 21, 1068
DOI: 10.1021/acs.orglett.8b04117

Cp*CoIII–Catalyzed Alkylation of Primary and Secondary C(sp3)-H Bonds of 8-Alkylquinolines with Maleimides

Rakesh Kumar, Rohit Kumar, Devesh Chandra and Upendra Sharma

J. Org. Chem., 2019, 84, 1542
DOI: 10.1021/acs.joc.8b02974

Rhodium-Catalyzed Enantio- and Diastereoselective Synthesis of Allenyl Alcohols via Three-Component Dicarbofunctionalization of 1,3-Enynes

Heng Song, Ruijie Mi and Xingwei Li

ACS Catal., 2025, 15, 15350
DOI: 10.1021/acscatal.5c05041

Cobalt-Catalyzed Decarboxylative C–H (Hetero)Arylation for the Synthesis of Arylheteroarenes and Unsymmetrical Biheteroaryls

Yanrong Li, Fen Qian, Mengshi Wang, Hongjian Lu and Guigen Li

Org. Lett., 2017, 19, 5589
DOI: 10.1021/acs.orglett.7b02730

Charting the influence of deuterium sources in hydrogen isotope exchange using a cobalt(III) catalytic platform

Sergio Barranco, Inbal L. Eshel, Jiayu Zhang, Marco Di Matteo, Anat Milo and Mónica H. Pérez-Temprano

Nat Catal, 2025, 8, 1306
DOI: 10.1038/s41929-025-01447-x

Recent Advances in Transition‐Metal‐Catalyzed C−H Functionalization of Ferrocene Amides

Qi Mou, Ruyuan Zhao and Bo Sun

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200818

Cp*Co(III)-Catalyzed Regioselective Synthesis of Cyclopenta[b]carbazoles via Dual C(sp2)–H Functionalization of 1-(Pyridin-2-yl)-indoles with Diynes

Qiuyun Li, Yanwei Wang, Bin Li and Baiquan Wang

Org. Lett., 2018, 20, 7884
DOI: 10.1021/acs.orglett.8b03438

Cobalt-Catalyzed Cross-Dehydrogenative Coupling Reaction between Unactivated C(sp2)–H and C(sp3)–H Bonds

Qun Li, Weipeng Hu, Renjian Hu, Hongjian Lu and Guigen Li

Org. Lett., 2017, 19, 4676
DOI: 10.1021/acs.orglett.7b02316

Palladium-Catalyzed Late-Stage ortho-C–H Bond Aroylation of Anilines Using 4-Methoxy-2-pyridinyl as a Removable Directing Group

Jean-Ho Chu, Meng-Fan Chiang, Chin-Wei Li, Zhe-Hong Su, Shao-Chi Lo and Ming-Jung Wu

Organometallics, 2019, 38, 2105
DOI: 10.1021/acs.organomet.9b00119

Cp*Co(III)-Catalyzed Ketone-Directed ortho-C–H Activation for the Synthesis of Indene Derivatives

Dattatraya H. Dethe, Nagabhushana C B and Arsheed Ahmad Bhat

J. Org. Chem., 2020, 85, 7565
DOI: 10.1021/acs.joc.0c00727

Ir-Catalyzed ortho-C-H Borylation of Aromatic C(sp2)-H Bonds of Carbocyclic Compounds Assisted by N-Bearing Directing Groups

Hamad H. Al Mamari

Reactions, 2024, 5, 318
DOI: 10.3390/reactions5020016

Cp*Co(III)-Catalyzed C–H Functionalization Cascade of N-Methoxyamides with Alkynedione for the Synthesis of Indolizidines

Lahu N. Chavan, Krishna Kumar Gollapelli, Rambabu Chegondi and Amit B. Pawar

Org. Lett., 2017, 19, 2186
DOI: 10.1021/acs.orglett.7b00904

Aldehyde‐Directed C(sp2)−H Functionalization under Transition‐Metal Catalysis

Junfei Luo and Qiang Fu

Adv Synth Catal, 2021, 363, 3868
DOI: 10.1002/adsc.202100325

Linear Selective C–H Bond Alkylation with Activated Olefins Catalyzed by Cp*CoIII

Nagaraju Barsu, Balakumar Emayavaramban and Basker Sundararaju

Eur J Org Chem, 2017, 2017, 4370
DOI: 10.1002/ejoc.201700696

Synthesis of 1,2-Dihydroquinolines by Co(III)-Catalyzed [3 + 3] Annulation of Anilides with Benzylallenes

Ramajayam Kuppusamy, Rajagopal Santhoshkumar, Ramadoss Boobalan, Hsin-Ru Wu and Chien-Hong Cheng

ACS Catal., 2018, 8, 1880
DOI: 10.1021/acscatal.7b04087

Cp*CoIII-Catalyzed C(7)–H Bond Annulation of Indolines with Alkynes

Rajib Mandal, Bholanath Garai and Basker Sundararaju

J. Org. Chem., 2021, 86, 9407
DOI: 10.1021/acs.joc.1c00713

Enantioselective Cobalt-Catalyzed C–H Functionalization

Weiwei Xu and Mengchun Ye

Synthesis, 2022, 54, 4773
DOI: 10.1055/a-1801-2595

Unique Reactivity of High-valent Cobalt Catalysis in C-H Functionalization and Development of Catalytic Asymmetric C-H Functionalization Reactions

Tatsuhiko Yoshino and Shigeki Matsunaga

J. Synth. Org. Chem. Jpn., 2019, 77, 330
DOI: 10.5059/yukigoseikyokaishi.77.330

Thioamide‐Directed Cobalt(III)‐Catalyzed Selective Amidation of C(sp3)−H Bonds

Peng Wen Tan, Adrian M. Mak, Michael B. Sullivan, Darren J. Dixon and Jayasree Seayad

Angew Chem Int Ed, 2017, 56, 16550
DOI: 10.1002/anie.201709273

Cp*Co(III)-Catalyzed C-7 C–C Coupling of Indolines with Aziridines: Merging C–H Activation and Ring Opening

Pinaki Bhusan De, Sayan Atta, Sourav Pradhan, Sonbidya Banerjee, Tariq A. Shah and Tharmalingam Punniyamurthy

J. Org. Chem., 2020, 85, 4785
DOI: 10.1021/acs.joc.0c00010

Cp*Co(III)‐Catalyzed Coupling of Benzamides with α,β‐Unsaturated Carbonyl Compounds: Preparation of Aliphatic Ketones and Azepinones

Paula G. Chirila, Joshua Adams, Amir Dirjal, Alex Hamilton and Christopher J. Whiteoak

Chemistry A European J, 2018, 24, 3584
DOI: 10.1002/chem.201705785

Mechanistic DFT Study on Rhodium(III)‐Catalyzed Double C−H Activation for Oxidative Annulations of 2‐Substituted Imidazoles and Alkynes

Peipei Xie, Mengmeng Jia, Xiao‐Hua Xu, Fan Chen and Yuanzhi Xia

Asian J Org Chem, 2018, 7, 586
DOI: 10.1002/ajoc.201700625

Cp*Co(III)-Catalyzed Regioselective C2 Amidation of Indoles Using Acyl Azides

Tariq A. Shah, Pinaki Bhusan De, Sourav Pradhan, Sonbidya Banerjee and Tharmalingam Punniyamurthy

J. Org. Chem., 2019, 84, 16278
DOI: 10.1021/acs.joc.9b02244

Mechanistic Investigations on Cp*CoIII-Catalyzed Quinoline Transfer Hydrogenation with Formic Acid

Nidhi Garg, Pardeep Dahiya, Sonia Mallet-Ladeira, Rinaldo Poli and Basker Sundararaju

ACS Catal., 2024, 14, 17556
DOI: 10.1021/acscatal.4c05271

A C–H Activation-Based Strategy for N-Amino Azaheterocycle Synthesis

Pengfei Shi, Lili Wang, Shan Guo, Kehao Chen, Jie Wang and Jin Zhu

Org. Lett., 2017, 19, 4359
DOI: 10.1021/acs.orglett.7b02066

Iron‐Catalyzed C−C Bond Formation via Chelation‐Assisted C−H Activation

Naohiko Yoshikai

Israel Journal of Chemistry, 2017, 57, 1117
DOI: 10.1002/ijch.201700047

Carboxylate-Assisted Formation of Aryl-Co(III) Masked-Carbenes in Cobalt-Catalyzed C–H Functionalization with Diazo Esters

Oriol Planas, Steven Roldán-Gómez, Vlad Martin-Diaconescu, Teodor Parella, Josep M. Luis, Anna Company and Xavi Ribas

J. Am. Chem. Soc., 2017, 139, 14649
DOI: 10.1021/jacs.7b07880

Cobalt-Catalyzed Regioselective Direct C-4 Alkenylation of 3-Acetylindole with Michael Acceptors Using a Weakly Coordinating Functional Group

Shyam Kumar Banjare, Tanmayee Nanda and P. C. Ravikumar

Org. Lett., 2019, 21, 8138
DOI: 10.1021/acs.orglett.9b03243

Cyclobutadiene nickel complex as a catalyst for CH-activation reactions: computational study

Nikita M. Ankudinov and Dmitry S. Perekalin

Mendeleev Communications, 2019, 29, 263
DOI: 10.1016/j.mencom.2019.05.007

Developments in Cp*CoIII‐Catalyzed C−H Bond Functionalizations

Jayanta Ghorai and Pazhamalai Anbarasan

Asian J Org Chem, 2019, 8, 430
DOI: 10.1002/ajoc.201800452

Isolation of Cp*CoIII–Alkenyl Intermediate in Efficient Cobalt‐Catalyzed C−H Alkenylation with Alkynes

Malay Sen, Nimmakuri Rajesh, Balakumar Emayavaramban, J. Richard Premkumar and Basker Sundararaju

Chemistry A European J, 2018, 24, 342
DOI: 10.1002/chem.201705183

Roads Not Taken: Mechanism and Origins of Regio- and Chemoselectivity of Directed CoIII-Catalyzed Alkenylation of N-Pyridyl 2-Pyridone

Supreeth Prasad and Dean J. Tantillo

Organometallics, 2022, 41, 937
DOI: 10.1021/acs.organomet.1c00662

Weakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*CoIIICatalysis

Sara Martínez de Salinas, Jesús Sanjosé‐Orduna, Carlota Odena, Sergio Barranco, Jordi Benet‐Buchholz and Mónica H. Pérez‐Temprano

Angewandte Chemie, 2020, 132, 6298
DOI: 10.1002/ange.201916387

C−H Bond Functionalization by Mechanochemistry

José G. Hernández

Chemistry A European J, 2017, 23, 17157
DOI: 10.1002/chem.201703605

Recent advances of allenes in the first-row transition metals catalyzed C H activation reactions

Xiang-Lei Han, Peng-Peng Lin and Qingjiang Li

Chinese Chemical Letters, 2019, 30, 1495
DOI: 10.1016/j.cclet.2019.04.027

Direct Hiyama Cross-Coupling of (Hetero)arylsilanes with C(sp2)–H Bonds Enabled by Cobalt Catalysis

Ming-Zhu Lu, Xin Ding, Changdong Shao, Zhengsong Hu, Haiqing Luo, Sanjun Zhi, Huayou Hu, Yuhe Kan and Teck-Peng Loh

Org. Lett., 2020, 22, 2663
DOI: 10.1021/acs.orglett.0c00631

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)‐Catalyzed Enantioselective C−H Functionalization

Luqing Lin, Seiya Fukagawa, Daichi Sekine, Eiki Tomita, Tatsuhiko Yoshino and Shigeki Matsunaga

Angewandte Chemie, 2018, 130, 12224
DOI: 10.1002/ange.201807610

Co-Catalyzed C(sp3)–H Oxidative Coupling of Glycine and Peptide Derivatives

Marcos San Segundo, Itziar Guerrero and Arkaitz Correa

Org. Lett., 2017, 19, 5288
DOI: 10.1021/acs.orglett.7b02567

Cobalt(III)‐Catalyzed, DMSO‐Involved, and TFA‐Controlled Regioselective C−H Functionalization of Anilines with Alkynes for Specific Assembly of 3‐Arylquinolines

Peiquan Zhang, Yurong Yang, Zhiyong Chen, Zhang Xu, Xuefeng Xu, Zhi Zhou, Xiyong Yu and Wei Yi

Adv Synth Catal, 2019, 361, 3002
DOI: 10.1002/adsc.201801709

A Facile Route to Ortho‐Hydroxyanilnes through an IrIII‐Catalyzed Direct C−H Amidation of 2‐Phenoxypyridines

Lianhui Wang, Zi Yang, Mengqi Yang, Miaodou Tian, Changsheng Kuai and Xiuling Cui

Chemistry An Asian Journal, 2017, 12, 2634
DOI: 10.1002/asia.201701028

Cp*Co(III)-Catalyzed C–H Hydroarylation of Alkynes and Alkenes and Beyond: A Versatile Synthetic Tool

Asier Carral-Menoyo, Nuria Sotomayor and Esther Lete

ACS Omega, 2020, 5, 24974
DOI: 10.1021/acsomega.0c03639

Cobalt(III)-Catalyzed Diastereo- and Enantioselective Three-Component C–H Functionalization

Ana G. Herraiz and Nicolai Cramer

ACS Catal., 2021, 11, 11938
DOI: 10.1021/acscatal.1c03153

Imidate as the Intact Directing Group for the Cobalt-Catalyzed C–H Allylation

Ryo Tanaka, Iku Tanimoto, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

J. Org. Chem., 2019, 84, 13203
DOI: 10.1021/acs.joc.9b01972

Selective C(sp2)‐H Amination Catalyzed by High‐Valent Cobalt(III)/(IV)‐bpy Complex Immobilized on Silica Nanoparticles

Yulia Budnikova, Olga Bochkova, Mikhail Khrizanforov, Irek Nizameev, Kirill Kholin, Tatyana Gryaznova, Artem Laskin, Yulia Dudkina, Sofia Strekalova, Svetlana Fedorenko, Aleksandr Kononov and Asia Mustafina

ChemCatChem, 2019, 11, 5615
DOI: 10.1002/cctc.201901391

Rh(III)‐Catalyzed C−H Acylmethylation of 6‐Arylpurines Using Sulfoxonium Ylides as Carbene Precursors

Zhibing Chen, Xianqiang Kong and Bo Xu

ChemistrySelect, 2020, 5, 2465
DOI: 10.1002/slct.201904754

Cobalt‐Catalyzed Enantio‐ and Regioselective C(sp3)−H Alkenylation of Thioamides

Lucia Staronova, Ken Yamazaki, Xing Xu, Heyao Shi, F. Matthias Bickelhaupt, Trevor A. Hamlin and Darren J. Dixon

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202316021

Cobalt‐Catalyzed Oxyalkylation of Styrenes via α‐C(Sp3)−H Bond Activation of Ethers Without Organic Peroxides

Juanjuan Li, Jiale Li, Songdong Yuan, Qian Zhang and Dong Li

Asian J Org Chem, 2019, 8, 1842
DOI: 10.1002/ajoc.201900454

Cp*CoIII/Chiral Carboxylic Acid‐Catalyzed Enantioselective 1,4‐Addition Reactions of Indoles to Maleimides

Takumaru Kurihara, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

Asian J Org Chem, 2020, 9, 368
DOI: 10.1002/ajoc.201900565

Heterometallic CoIIIZnII Schiff Base Catalyst for Mild Hydroxylation of C(sp3)–H Bonds of Unactivated Alkanes: Evidence for Dual Mechanism Controlled by the Promoter

Oksana V. Nesterova, Katerina V. Kasyanova, Elena A. Buvaylo, Olga Yu. Vassilyeva, Brian W. Skelton, Dmytro S. Nesterov and Armando J.L. Pombeiro

Catalysts, 2019, 9, 209
DOI: 10.3390/catal9030209

An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

Qian Zhang, Juanjuan Li, Jiale Li, Songdong Yuan and Dong Li

Tetrahedron Letters, 2020, 61, 152399
DOI: 10.1016/j.tetlet.2020.152399

Cobalt‐Catalyzed Directed sp2 C−H Acetoxylation of Arenes Employing Mn(OAc)3 ⋅ 2H2O as Acetoxy Source

Writhabrata Sarkar, Arup Bhowmik, Aniket Mishra, Tripta Kumari Vats and Indubhusan Deb

Adv Synth Catal, 2018, 360, 3228
DOI: 10.1002/adsc.201800398

Co(III)-Catalyzed C–H Activation: A Site-Selective Conjugate Addition of Maleimide to Indole at the C-2 Position

Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

ACS Omega, 2017, 2, 4470
DOI: 10.1021/acsomega.7b00870

Enantiodivergent Desymmetrization in the Rhodium(III)‐Catalyzed Annulation of Sulfoximines with Diazo Compounds

Bingxue Shen, Boshun Wan and Xingwei Li

Angewandte Chemie, 2018, 130, 15760
DOI: 10.1002/ange.201810472

Cobalt‐Catalyzed Temperature‐Dependent Annulation of 3‐Aryl‐1,2,4‐oxadiazolones with 1,3‐Diynes: An Approach to π‐Conjugated Molecules

Wenge Zhang, Hongji Li and Lei Wang

Adv Synth Catal, 2019, 361, 2885
DOI: 10.1002/adsc.201801165

Hydroarylations by cobalt-catalyzed C–H activation

Rajagopal Santhoshkumar and Chien-Hong Cheng

Beilstein J. Org. Chem., 2018, 14, 2266
DOI: 10.3762/bjoc.14.202

Non‐Noble Metal Catalysis in Focus: Unlocking Latest Emergent Frontiers in Amide Annulation Through C─H/C─X Activation

Prakash K. Mandal, Md Tanjul Hoque, Anindya S. Manna, Ramlal Baidya, Rajesh Nandi, Subhasis Pal, Nilay Karchaudhuri and Dilip K. Maiti

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500478

Weakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*CoIIICatalysis

Sara Martínez de Salinas, Jesús Sanjosé‐Orduna, Carlota Odena, Sergio Barranco, Jordi Benet‐Buchholz and Mónica H. Pérez‐Temprano

Angew Chem Int Ed, 2020, 59, 6239
DOI: 10.1002/anie.201916387

Ru‐Catalyzed C(sp2)−H Bond Arylation of Benzamides Bearing a Novel 4‐Aminoantipyrine as a Directing Group

Hamad H. Al Mamari, Diana Al Kiumi, Tamadher Al Rashdi, Huda Al Quraini, Malak Al Rashdi, Sumayya Al Sheraiqi, Sara Al Harmali, Mohammed Al Lamki, Ahmed Al Sheidi and Asma Al Zadjali

Eur J Org Chem, 2021, 2021, 3598
DOI: 10.1002/ejoc.202100513

Cobalt Catalyst‐Controlled Selective Dioxygenation of Styrenes Using N‐Hydroxyphthalimide with Molecular Oxygen

Xiaosong Hao, Huihui Ji, Hongju Zhan, Qian Zhang and Dong Li

Adv Synth Catal, 2022, 364, 193
DOI: 10.1002/adsc.202100921

Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C–H Activation: Efficient Access to α-gem-Vinylindoles

Xukai Zhou, Yixin Luo, Lingheng Kong, Youwei Xu, Guangfan Zheng, Yu Lan and Xingwei Li

ACS Catal., 2017, 7, 7296
DOI: 10.1021/acscatal.7b02248

Recent Advances in the Nickel-Catalyzed Alkylation of C-H Bonds

Franc Požgan, Uroš Grošelj, Jurij Svete, Bogdan Štefane and Hamad H. Al Mamari

Molecules, 2024, 29, 1917
DOI: 10.3390/molecules29091917

OrthoC H amidations enabled by a recyclable manganese-ionic liquid catalytic system

Xianqiang Kong and Bo Xu

Tetrahedron Letters, 2020, 61, 151521
DOI: 10.1016/j.tetlet.2019.151521

Cobalt-Catalyzed Aerobic Oxidative C–H/C–H Cross-Coupling of Unactivated Arenes for the Synthesis of Biaryls

Ningning Lv, Zhengkai Chen, Yue Liu, Zhanxiang Liu and Yuhong Zhang

Org. Lett., 2018, 20, 5845
DOI: 10.1021/acs.orglett.8b02526

Pentacarboxycyclopentadienes in Organic Synthesis

I. E. Mikhailov, G. A. Dushenko and V. I. Minkin

Russ J Org Chem, 2021, 57, 1757
DOI: 10.1134/S1070428021110014

Thioamide‐Directed Cobalt(III)‐Catalyzed Selective Amidation of C(sp3)−H Bonds

Peng Wen Tan, Adrian M. Mak, Michael B. Sullivan, Darren J. Dixon and Jayasree Seayad

Angewandte Chemie, 2017, 129, 16777
DOI: 10.1002/ange.201709273

Cyclopentadienyl cobalt(III) complexes: Synthetic and catalytic chemistry

Dmitry A. Loginov, Lidia S. Shul'pina, Dmitry V. Muratov and Georgiy B. Shul'pin

Coordination Chemistry Reviews, 2019, 387, 1
DOI: 10.1016/j.ccr.2019.01.022

Ligand-Dependent Multi-State Reactivity in Cobalt(III)-Catalyzed C–H Activations

Pengchen Ma and Hui Chen

ACS Catal., 2019, 9, 1962
DOI: 10.1021/acscatal.8b04532

Cobalt‐Catalyzed Double C−H Activation of Imidazopyridines with Vinylene Carbonate for the Synthesis of Pyrido[1,2‐a]benzimidazoles

Min Liu, Xinlei Sui, Jiangwei Wen, Qiuyun Li, Xiao Liu, Xiaoyu Wang, Xiu Wang and Kelu Yan

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202201349

Cobalt catalyzed alkenylation/annulation reactions of alkynes via C–H activation: A review

Jyotismita Bora, Mayuri Dutta and Bolin Chetia

Tetrahedron, 2023, 132, 133248
DOI: 10.1016/j.tet.2023.133248

Comparison of the Reactivities and Selectivities of Group 9 [Cp*MIII] Catalysts in C−H Functionalization Reactions

Juhyeon Park and Sukbok Chang

Chemistry An Asian Journal, 2018, 13, 1089
DOI: 10.1002/asia.201800204

Amide-Directed Cobalt(III)-Catalyzed C–H Amidation of Ferrocenes

Dan-Ying Huang, Qi-Jun Yao, Shuo Zhang, Xue-Tao Xu, Kun Zhang and Bing-Feng Shi

Org. Lett., 2019, 21, 951
DOI: 10.1021/acs.orglett.8b03938

Thioamide-Directed Cp*Co(III)-Catalyzed C–H Allylation of Ferrocenes

Zhuo-Zhuo Zhang, Gang Liao, Hao-Ming Chen and Bing-Feng Shi

Org. Lett., 2021, 23, 2626
DOI: 10.1021/acs.orglett.1c00533

Mechanistic Exploration of Cp*CoIII/RhIII-Catalyzed Carboamination/Olefination of N-Phenoxyacetamides with Alkenes

Yang-Yang Xing, Jian-Biao Liu, Chuan-Zhi Sun, Fang Huang and De-Zhan Chen

Inorg. Chem., 2018, 57, 10726
DOI: 10.1021/acs.inorgchem.8b01352

Catalyst-Controlled [3 + 2] and [4 + 2] Annulations of Oximes with Propargyl Alcohols: Divergent Access to Indenamines and Isoquinolines

Wanchun Gong, Zhi Zhou, Jingjing Shi, Bo Wu, Biyun Huang and Wei Yi

Org. Lett., 2018, 20, 182
DOI: 10.1021/acs.orglett.7b03546

Cp*Co(III)-Catalyzed Annulation of Carboxylic Acids with Alkynes

Rajib Mandal and Basker Sundararaju

Org. Lett., 2017, 19, 2544
DOI: 10.1021/acs.orglett.7b00801

Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination

Vladimir B. Kharitonov, Evgeniya Podyacheva, Yulia V. Nelyubina, Dmitry V. Muratov, Alexander S. Peregudov, Gleb Denisov, Denis Chusov and Dmitry A. Loginov

Organometallics, 2019, 38, 3151
DOI: 10.1021/acs.organomet.9b00378

Cobalt-Catalyzed Vinylic C–H Addition to Formaldehyde: Synthesis of Butenolides from Acrylic Acids and HCHO

Shuling Yu, Chao Hong, Zhanxiang Liu and Yuhong Zhang

Org. Lett., 2021, 23, 8359
DOI: 10.1021/acs.orglett.1c03095

Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*CoIII‐Catalyzed C−H Alkenylation/Directing Group Migration Sequence

Hideya Ikemoto, Ryo Tanaka, Ken Sakata, Motomu Kanai, Tatsuhiko Yoshino and Shigeki Matsunaga

Angew Chem Int Ed, 2017, 56, 7156
DOI: 10.1002/anie.201703193

Enantiodivergent Desymmetrization in the Rhodium(III)‐Catalyzed Annulation of Sulfoximines with Diazo Compounds

Bingxue Shen, Boshun Wan and Xingwei Li

Angew Chem Int Ed, 2018, 57, 15534
DOI: 10.1002/anie.201810472

Manganese-Catalyzed ortho-C-H Amidation of Weakly Coordinating Aromatic Ketones

Xianqiang Kong and Bo Xu

Org. Lett., 2018, 20, 4495
DOI: 10.1021/acs.orglett.8b01770

Cobaltaelectro-Catalyzed Oxidative C–H/N–H Activation with 1,3-Diynes by Electro-Removable Hydrazides

Ruhuai Mei, Wenbo Ma, Yin Zhang, Xiaoqiang Guo and Lutz Ackermann

Org. Lett., 2019, 21, 6534
DOI: 10.1021/acs.orglett.9b02463

Regioselective Synthesis of 5-Aminooxazoles via Cp*Co(III)-Catalyzed Formal [3 + 2] Cycloaddition of N-(Pivaloyloxy)amides with Ynamides

Xiang-Lei Han, Chu-Jun Zhou, Xu-Ge Liu, Shang-Shi Zhang, Honggen Wang and Qingjiang Li

Org. Lett., 2017, 19, 6108
DOI: 10.1021/acs.orglett.7b02959

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)‐Catalyzed Enantioselective C−H Functionalization

Luqing Lin, Seiya Fukagawa, Daichi Sekine, Eiki Tomita, Tatsuhiko Yoshino and Shigeki Matsunaga

Angew Chem Int Ed, 2018, 57, 12048
DOI: 10.1002/anie.201807610

Ni‐Catalyzed Chelation‐AssistedDirect Functionalization of Inert C—H Bonds

Yan‐Hua Liu, Yu‐Nong Xia and Bing‐Feng Shi

Chin. J. Chem., 2020, 38, 635
DOI: 10.1002/cjoc.201900468

Os(II)-catalyzed γ-C(sp3)–H amidation and meta-C(sp2)–H alkylation by fine-tuning the characteristics of in-situ-generated C–Os σ bonds

Wei Yi, Weijie Chen, Huiying Xu, Kaifeng Chen, Xiuhua Zhong and Zhi Zhou

Cell Reports Physical Science, 2023, 4, 101423
DOI: 10.1016/j.xcrp.2023.101423

Olefin Hydroarylation Catalyzed by a Single-Component Cobalt(-I) Complex

Benjamin A. Suslick and T. Don Tilley

Org. Lett., 2021, 23, 1495
DOI: 10.1021/acs.orglett.1c00258

Building molecular complexity through transition-metal-catalyzed oxidative annulations/cyclizations: Harnessing the utility of phenols, naphthols and 1,3-dicarbonyl compounds

Imtiaz Khan, Aliya Ibrar and Syeda Aaliya Shehzadi

Coordination Chemistry Reviews, 2019, 380, 440
DOI: 10.1016/j.ccr.2018.11.001

Cp*Co(III)‐Catalyzed o‐Amidation of Benzaldehydes with Dioxazolones Using Transient Directing Group Strategy

Bhuttu Khan, Vikas Dwivedi and Basker Sundararaju

Adv Synth Catal, 2020, 362, 1195
DOI: 10.1002/adsc.201901267

Cp*Co(III) catalyzed annulation of N-Cbz hydrazones for the redox-neutral synthesis of isoquinolines via C–H/N–N bond activation

Dnyaneshwar D. Subhedar, Dewal S. Deshmukh and Bhalchandra M. Bhanage

Synthetic Communications, 2019, 49, 3121
DOI: 10.1080/00397911.2019.1655765

Regioselective Direct C‐Alkenylation of Indoles

Marino Petrini

Chemistry A European J, 2017, 23, 16115
DOI: 10.1002/chem.201702124

Direct ortho‐Acyloxylation of Arenes and Alkenes by Cobalt Catalysis

Cong Lin, Zhengkai Chen, Zhanxiang Liu and Yuhong Zhang

Adv Synth Catal, 2018, 360, 519
DOI: 10.1002/adsc.201701144

Directed Cp*RhIII-Catalyzed Fluorosulfonylvinylation of Arenes

Gqwetha Ncube and Malcolm P. Huestis

Organometallics, 2019, 38, 76
DOI: 10.1021/acs.organomet.8b00327

Pd‐Catalyzed C(sp2)─H Bond Arylation of Benzamides Assisted by 4‐Aminoantipyrine as a Directing Group

Hamad H. Al Mamari, Raneem R. Abdel‐Jalil, Al Zahraa S. Al Athmani, Fatma A. Al Nabhani, Maisa A. Al Namani and Afnan B. Al Abdali

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202504016

Stereoselective Synthesis of Tetrasubstituted Alkenes via a Cp*CoIII‐Catalyzed C−H Alkenylation/Directing Group Migration Sequence

Hideya Ikemoto, Ryo Tanaka, Ken Sakata, Motomu Kanai, Tatsuhiko Yoshino and Shigeki Matsunaga

Angewandte Chemie, 2017, 129, 7262
DOI: 10.1002/ange.201703193

One-Step Synthesis of 4H-3,1-Benzoxazin-4-ones from Weinreb Amides and 1,4,2-Dioxazol-5-ones via Cobalt-Catalyzed C–H Bond Activation

Shigeki Matsunaga, Tatsuhiko Yoshino, Iku Tanimoto, Kentaro Kawai and Akane Sato

HETEROCYCLES, 2019, 99, 118
DOI: 10.3987/COM-18-S(F)48

Diverse Approaches for Enantioselective C−H Functionalization Reactions Using Group 9 CpxMIII Catalysts

Tatsuhiko Yoshino, Shun Satake and Shigeki Matsunaga

Chemistry A European J, 2020, 26, 7346
DOI: 10.1002/chem.201905417

Cobalt-Catalyzed Oxidant-Free Spirocycle Synthesis by Liberation of Hydrogen

Ningning Lv, Yue Liu, Chunhua Xiong, Zhanxiang Liu and Yuhong Zhang

Org. Lett., 2017, 19, 4640
DOI: 10.1021/acs.orglett.7b02266

Comprehensive Mechanistic Insight into Cooperative Lewis Acid/Cp*CoIII-Catalyzed C–H/N–H Activation for the Synthesis of Isoquinolin-3-ones

Qiong Wang, Fang Huang, Langhuan Jiang, Chuanxue Zhang, Chuanzhi Sun, Jianbiao Liu and Dezhan Chen

Inorg. Chem., 2018, 57, 2804
DOI: 10.1021/acs.inorgchem.7b03216

Cp*Co(III)-Catalyzed C–H Acylmethylation of Arenes by Employing Sulfoxonium Ylides as Carbene Precursors

Shuying Ji, Kelu Yan, Bin Li and Baiquan Wang

Org. Lett., 2018, 20, 5981
DOI: 10.1021/acs.orglett.8b02796

Synthesis of 1H-Indole-2,3-dicarboxylates via Rhodium-Catalyzed C–H Annulation of Arylhydrazines with Maleates

Sheng Zhang, He Li, Yoshinori Yamamoto and Ming Bao

J. Org. Chem., 2020, 85, 12544
DOI: 10.1021/acs.joc.0c01727

Breaking the Trend: Insight into Unforeseen Reactivity of Alkynes in Cobalt-Catalyzed Weak Chelation-Assisted Regioselective C(4)–H Functionalization of 3-Pivaloyl Indole

Shyam Kumar Banjare, Tanmayee Nanda, Bedadyuti Vedvyas Pati, Gopal Krushna Das Adhikari, Juhi Dutta and Ponneri C. Ravikumar

ACS Catal., 2021, 11, 11579
DOI: 10.1021/acscatal.1c02689

Cp*Co(III)-Catalyzed C–H Alkylation with Maleimides Using Weakly Coordinating Carbonyl Directing Groups

Rajib Mandal, Balakumar Emayavaramban and Basker Sundararaju

Org. Lett., 2018, 20, 2835
DOI: 10.1021/acs.orglett.8b00761

Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C–H Functionalizations

Kristers Ozols, Yun-Suk Jang and Nicolai Cramer

J. Am. Chem. Soc., 2019, 141, 5675
DOI: 10.1021/jacs.9b02569

Cobalt(III)‐Catalyzed Direct ortho‐Alkenylation of Arylpyrazoles: A Comparative Study on Decarboxylation and Desilylation

Anil Kumar, Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

Eur J Org Chem, 2019, 2019, 2735
DOI: 10.1002/ejoc.201900270

Weinreb Amide Directed Versatile C−H Bond Functionalization under (η5‐Pentamethylcyclopentadienyl)cobalt(III) Catalysis

Kentaro Kawai, Youka Bunno, Tatsuhiko Yoshino and Shigeki Matsunaga

Chemistry A European J, 2018, 24, 10231
DOI: 10.1002/chem.201801750

Transition Metal‐Catalyzed Intermolecular Cascade C−H Activation/Annulation Processes for the Synthesis of Polycycles

Liangliang Song and Erik V. Van der Eycken

Chemistry A European J, 2021, 27, 121
DOI: 10.1002/chem.202002110

Co(III)‐Catalyzed [4+1] Annulation of Amides with Allenes via C−H Activation

Ramadoss Boobalan, Rajagopal Santhoshkumar and Chien‐Hong Cheng

Adv Synth Catal, 2019, 361, 1140
DOI: 10.1002/adsc.201801335

First Cp*Co(III)-catalyzed Mizoroki-Heck coupling reactions of alkenes and aryl bromide/iodide

Avinash K. Srivastava, Naveen Satrawala, Munsaf Ali, Charu Sharma and Raj K. Joshi

Tetrahedron Letters, 2019, 60, 151283
DOI: 10.1016/j.tetlet.2019.151283

Cobalt‐Catalyzed Enantio‐ and Regioselective C(sp3)−H Alkenylation of Thioamides

Lucia Staronova, Ken Yamazaki, Xing Xu, Heyao Shi, F. Matthias Bickelhaupt, Trevor A. Hamlin and Darren J. Dixon

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202316021

Asymmetric C(sp3)−H dienylation of thioamides under Cp*Co(III)/chiral acid catalysis

Bholanath Garai, Arka Ghosh, Sayan Dutta, Bholanath Maity, Luigi Cavallo and Basker Sundararaju

Journal of Catalysis, 2026, 456, 116779
DOI: 10.1016/j.jcat.2026.116779

Cobalt(III)−Catalyzed C−H Activation: A Secondary Amide Directed Decarboxylative Functionalization of Alkynyl Carboxylic Acids Wherein Amide NH‐group Remains Unreactive

Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

Adv Synth Catal, 2018, 360, 1370
DOI: 10.1002/adsc.201701406

Cp*Co(III)-Catalyzed Dearomative [3 + 2] Spiroannulation of 2-Alkenylphenols with Ynamides via C–H Activation

Peng-Peng Lin, Xiang-Lei Han, Guo-Hua Ye, Ji-Lin Li, Qingjiang Li and Honggen Wang

J. Org. Chem., 2019, 84, 12966
DOI: 10.1021/acs.joc.9b01750

A challenging redox neutral Cp*Co(III)-catalysed alkylation of acetanilides with 3-buten-2-one: synthesis and key insights into the mechanism through DFT calculations

Andrew Kenny, Alba Pisarello, Arron Bird, Paula G Chirila, Alex Hamilton and Christopher J Whiteoak

Beilstein J. Org. Chem., 2018, 14, 2366
DOI: 10.3762/bjoc.14.212

Photochemistry regulated fluorescent dyes for real-time tracing subcellular migration in living cells

Ao Wang, Ding-Heng Zhou, Hong Zhang, Xing Zeng, Nan Wang, Ming-Yu Wu, Xiao-Qi Yu, Kun Li and Shan-Yong Chen

Chinese Chemical Letters, 2026, 37, 111358
DOI: 10.1016/j.cclet.2025.111358

HFIP‐Assisted C−H Functionalization by Cp*CoIII: Access to Key Reactive Cobaltacycles and Implication in Catalysis

Jesús Sanjosé‐Orduna, Juan Manuel Sarria Toro and Mónica H. Pérez‐Temprano

Angew Chem Int Ed, 2018, 57, 11369
DOI: 10.1002/anie.201806847

Cobalt‐Catalyzed Regioselective [4+2] Annulation/Lactonization of Benzamides with 4‐Hydroxy‐2‐Alkynoates under Aerobic Conditions

Nachimuthu Muniraj, Anil Kumar and Kandikere Ramaiah Prabhu

Adv Synth Catal, 2020, 362, 152
DOI: 10.1002/adsc.201901119

Cobalt(II)‐Catalyzed [5+2] C−H Annulation of o‐Arylanilines with Alkynes: An Expedient Route to Dibenzo‐[b,d]azepines

Fei Ling, Zhen Xie, Jiachen Chen, Chongren Ai, Haiwei Shen, Ze Wang, Xiao Yi and Weihui Zhong

Adv Synth Catal, 2019, 361, 3094
DOI: 10.1002/adsc.201900261

Cobalt(II)-Catalyzed Acyloxylation of C–H Bonds in Aromatic Amides with Carboxylic Acids

Rina Ueno, Satoko Natsui and Naoto Chatani

Org. Lett., 2018, 20, 1062
DOI: 10.1021/acs.orglett.7b04020

Domino C–H/N–H Allylations of Imidates by Cobalt Catalysis

Hui Wang, Mélanie M. Lorion and Lutz Ackermann

ACS Catal., 2017, 7, 3430
DOI: 10.1021/acscatal.7b00756

Manganese‐Catalyzed C−H Amidation of Heteroarenes in Water

Xianqiang Kong, Long Lin and Bo Xu

Adv Synth Catal, 2018, 360, 2801
DOI: 10.1002/adsc.201800544

Cp*CoIII-Catalyzed C–H Alkenylation/Annulation Reactions of Indoles with Alkynes: A DFT Study

Ken Sakata, Masami Eda, Yuri Kitaoka, Tatsuhiko Yoshino and Shigeki Matsunaga

J. Org. Chem., 2017, 82, 7379
DOI: 10.1021/acs.joc.7b01047

Development of Pseudo-C2-symmetric Chiral Binaphthyl Monocarboxylic Acids for Enantioselective C(sp3)–H Functionalization Reactions under Rh(III) Catalysis

Yoshimi Kato, Luqing Lin, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

ACS Catal., 2021, 11, 4271
DOI: 10.1021/acscatal.1c00765

Recent Advances in Cobalt‐catalyzed Functionalization of Unactivated Olefins

Monak Patel, Uppuluru Ajay, Kishor Padala and Togati Naveen

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200201

Cobalt-Catalyzed Enantioselective C–H Annulation with Alkenes

Dandan Yang, Xian Zhang, Xinghua Wang, Xiao-Ju Si, Jingtao Wang, Donghui Wei, Mao-Ping Song and Jun-Long Niu

ACS Catal., 2023, 13, 4250
DOI: 10.1021/acscatal.2c06355

Towards a Sequential One‐Pot Preparation of 1,2,3‐Benzotriazin‐4(3H)‐ones Employing a Key Cp*Co(III)‐catalyzed C−H Amidation Step

Paula G. Chirila, Lauren Skibinski, Keith Miller, Alex Hamilton and Christopher J. Whiteoak

Adv Synth Catal, 2018, 360, 2324
DOI: 10.1002/adsc.201800133

Mechanistic Interrogation of Alkyne Hydroarylations Catalyzed by Highly Reduced, Single-Component Cobalt Complexes

Benjamin A. Suslick and T. Don Tilley

J. Am. Chem. Soc., 2020, 142, 11203
DOI: 10.1021/jacs.0c04072

Cobalt-Catalyzed Annulation Reactions of Alkylidenecyclopropanes: Access to Spirocyclopropanes at Room Temperature

Arnab Dey, Neetipalli Thrimurtulu and Chandra M. R. Volla

Org. Lett., 2019, 21, 3871
DOI: 10.1021/acs.orglett.9b01392

Cobalt(III)-Catalyzed Regioselective [4 + 2]-Annulation of N-Chlorobenzamides with Substituted Alkenes

Suresh Kumar Yadav and Masilamani Jeganmohan

J. Org. Chem., 2022, 87, 13073
DOI: 10.1021/acs.joc.2c01588

Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides

Daichi Sekine, Kazuki Ikeda, Seiya Fukagawa, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

Organometallics, 2019, 38, 3921
DOI: 10.1021/acs.organomet.9b00407

Harnessing Vinyl Acetate as an Acetylene Equivalent in Redox-Neutral Cp*Co(III)-Catalyzed C–H Activation/Annulation for the Synthesis of Isoquinolones and Pyridones

Tamanna Rana, Arijit Ghosh, Yogesh N. Aher and Amit B. Pawar

ACS Omega, 2023, 8, 25262
DOI: 10.1021/acsomega.3c02352

Ag/Co-Bimetallic Cooperation in the C–H Functionalization of Aliphatic Amides with Propiolic Acids

Andrés García-Viada, Emma Duro, Celia Sánchez-González, Inés Alonso, Nuria Rodríguez, Javier Adrio and Juan C. Carretero

ACS Catal., 2025, 15, 148
DOI: 10.1021/acscatal.4c05918

Redefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*CoIV Species

Sara López‐Resano, Sara Martínez de Salinas, Felipe A. Garcés‐Pineda, Andrea Moneo‐Corcuera, José Ramón Galán‐Mascarós, Feliu Maseras and Mónica H. Pérez‐Temprano

Angew Chem Int Ed, 2021, 60, 11217
DOI: 10.1002/anie.202101390

Recent Advances in Base Metal (Copper, Cobalt and Nickel)-Catalyzed Directed C—H Amination

Ya-Lan Feng and Bing-Feng Shi

Chinese Journal of Organic Chemistry, 2021, 41, 3753
DOI: 10.6023/cjoc202104004

Synthesis of Fluorine-Containing 6-Arylpurine Derivatives via Cp*Co(III)-Catalyzed C–H Bond Activation

Nanami Murakami, Misaki Yoshida, Tatsuhiko Yoshino and Shigeki Matsunaga

Chem. Pharm. Bull., 2018, 66, 51
DOI: 10.1248/cpb.c17-00797

Pentamethylcyclopentadienyl rhodium(III)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization

Shun Satake, Takumaru Kurihara, Keisuke Nishikawa, Takuya Mochizuki, Manabu Hatano, Kazuaki Ishihara, Tatsuhiko Yoshino and Shigeki Matsunaga

Nat Catal, 2018, 1, 585
DOI: 10.1038/s41929-018-0106-5

3d Transition Metals for C–H Activation

Parthasarathy Gandeepan, Thomas Müller, Daniel Zell, Gianpiero Cera, Svenja Warratz and Lutz Ackermann

Chem. Rev., 2019, 119, 2192
DOI: 10.1021/acs.chemrev.8b00507

Computational Mechanistic Study on the Nickel-Catalyzed C–H/N–H Oxidative Annulation of Aromatic Amides with Alkynes: The Role of the Nickel (0) Ate Complex

Ken Yamazaki, Atsushi Obata, Akane Sasagawa, Yusuke Ano and Naoto Chatani

Organometallics, 2019, 38, 248
DOI: 10.1021/acs.organomet.8b00684

Enantioselective C(sp3)–H Amidation of Thioamides Catalyzed by a CobaltIII/Chiral Carboxylic Acid Hybrid System

Seiya Fukagawa, Yoshimi Kato, Ryo Tanaka, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

Angewandte Chemie, 2019, 131, 1165
DOI: 10.1002/ange.201812215

A General Cp*CoIII‐Catalyzed Intramolecular C−H Activation Approach for the Efficient Total Syntheses of Aromathecin, Protoberberine, and Tylophora Alkaloids

Andreas Lerchen, Tobias Knecht, Maximilian Koy, Constantin G. Daniliuc and Frank Glorius

Chemistry A European J, 2017, 23, 12149
DOI: 10.1002/chem.201702648

HFIP‐Assisted C−H Functionalization by Cp*CoIII: Access to Key Reactive Cobaltacycles and Implication in Catalysis

Jesús Sanjosé‐Orduna, Juan Manuel Sarria Toro and Mónica H. Pérez‐Temprano

Angewandte Chemie, 2018, 130, 11539
DOI: 10.1002/ange.201806847

Cobalt(III)-Catalyzed C-6 Alkenylation of 2-Pyridones by Using Terminal Alkyne with High Regioselectivity

Smruti Ranjan Mohanty, Namrata Prusty, Lokesh Gupta, Pragati Biswal and Ponneri Chandrababu Ravikumar

J. Org. Chem., 2021, 86, 9444
DOI: 10.1021/acs.joc.1c00769

Sustainable Knowledge‐Driven Approaches in Transition‐Metal‐Catalyzed Transformations

Jesús Sanjosé‐Orduna, Ángel L. Mudarra, Sara Martínez de Salinas and Mónica H. Pérez‐Temprano

ChemSusChem, 2019, 12, 2882
DOI: 10.1002/cssc.201900914

Redefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*CoIV Species

Sara López‐Resano, Sara Martínez de Salinas, Felipe A. Garcés‐Pineda, Andrea Moneo‐Corcuera, José Ramón Galán‐Mascarós, Feliu Maseras and Mónica H. Pérez‐Temprano

Angewandte Chemie, 2021, 133, 11317
DOI: 10.1002/ange.202101390

Synthesis of 7-Amido Indolines by Cp*Co(III)-Catalyzed C–H Bond Amidation

Qingkai Yan, Hai Huang, He Zhang, Meng-Hui Li, Dandan Yang, Mao-Ping Song and Jun-Long Niu

J. Org. Chem., 2020, 85, 11190
DOI: 10.1021/acs.joc.0c01259

Cobalt‐Catalyzed Annulation Reactions via C−H Bond Activation

Sekar Prakash, Ramajayam Kuppusamy and Chien‐Hong Cheng

ChemCatChem, 2018, 10, 683
DOI: 10.1002/cctc.201701559

Reusable Nano-Zirconia-Catalyzed Synthesis of Benzimidazoles and Their Antibacterial and Antifungal Activities

Tentu Nageswara Rao, Suliman Yousef AlOmar, Faheem Ahmed, Fadwa Albalawi, Naushad Ahmad, Nalla Krishna Rao, M. V. Basaveswara Rao, Ravi Kumar Cheedarala, G. Rajasekhar Reddy and Tentu Manohra Naidu

Molecules, 2021, 26, 4219
DOI: 10.3390/molecules26144219

Co(III)-Catalyzed Annulative Vinylene Transfer via C–H Activation: Three-Step Total Synthesis of 8-Oxopseudopalmatine and Oxopalmatine

Xinghua Li, Ting Huang, Ying Song, Yue Qi, Limin Li, Yanping Li, Qi Xiao and Yuanfei Zhang

Org. Lett., 2020, 22, 5925
DOI: 10.1021/acs.orglett.0c02016

Cobalt(III)‐Catalyzed Enantioselective Intermolecular Carboamination by C−H Functionalization

Kristers Ozols, Shunsuke Onodera, Łukasz Woźniak and Nicolai Cramer

Angewandte Chemie, 2021, 133, 665
DOI: 10.1002/ange.202011140

Enantioselective C(sp3)–H Amidation of Thioamides Catalyzed by a CobaltIII/Chiral Carboxylic Acid Hybrid System

Seiya Fukagawa, Yoshimi Kato, Ryo Tanaka, Masahiro Kojima, Tatsuhiko Yoshino and Shigeki Matsunaga

Angew Chem Int Ed, 2019, 58, 1153
DOI: 10.1002/anie.201812215

Cp*RhIII/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes

Jumpei Hirose, Takumi Wakikawa, Shun Satake, Masahiro Kojima, Manabu Hatano, Kazuaki Ishihara, Tatsuhiko Yoshino and Shigeki Matsunaga

ACS Catal., 2021, 11, 15187
DOI: 10.1021/acscatal.1c04699

Cobalt‐Catalyzed C(sp3)−H Functionalization Reactions

Tatsuhiko Yoshino and Shigeki Matsunaga

Asian J Org Chem, 2018, 7, 1193
DOI: 10.1002/ajoc.201800195

Dehydrative Cp*Co(III)-Catalyzed C–H Bond Allenylation

Malay Sen, Pardeep Dahiya, J. Richard Premkumar and Basker Sundararaju

Org. Lett., 2017, 19, 3699
DOI: 10.1021/acs.orglett.7b01415

Cobalt(III)‐Catalyzed C−H Activation: Counter Anion Triggered Desilylative Direct ortho‐Vinylation of Secondary Benzamides

Nachimuthu Muniraj and Kandikere Ramaiah Prabhu

Adv Synth Catal, 2018, 360, 3579
DOI: 10.1002/adsc.201800649

Regioselective Iridium‐Catalyzed C8‐H Borylation of 4‐Quinolones via Transient O‐Borylated Quinolines

Hamad H. Al Mamari, Julie Borel, Aobha Hickey, Eimear Courtney, Julia Merz, Xiaolei Zhang, Alexandra Friedrich, Todd B. Marder and Gerard P. McGlacken

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301734