Recent advances in transition metal-catalysed cross-coupling of (hetero)aryl halides and analogues under ligand-free conditions

Jude I. Ayogu and Efeturi A. Onoabedje

Catal. Sci. Technol., 2019, 9, 5233
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Mono- and dinuclear palladium(ii) complexes containing both N-heterocyclic carbenes and tetrazole ligands as catalysts for Hiyama coupling

Jin Yang

New J. Chem., 2016, 40, 9739
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Dimeric palladium 1,2,3-triazol-5-ylidene complexes – synthesis, structure, reactivity and catalytic properties in Suzuki coupling

Jan Lorkowski, Patrycja Żak, Maciej Kubicki, Cezary Pietraszuk, Dawid Jędrzkiewicz and Jolanta Ejfler

New J. Chem., 2018, 42, 10134
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Synthesis of zwitterionic palladium complexes and their application as catalysts in cross-coupling reactions of aryl, heteroaryl and benzyl bromides with organoboron reagents in neat water

V. Ramakrishna and N. Dastagiri Reddy

Dalton Trans., 2017, 46, 8598
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Bimetallic Cu(i) complex with a pyridine-bridged bis(1,2,3-triazole-5-ylidene) ligand

Haruka Iwasaki, Yuta Teshima, Yuji Yamada, Ryuta Ishikawa, Yuji Koga and Kouki Matsubara

Dalton Trans., 2016, 45, 5713
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The Heck reaction of allylic alcohols catalysed by an N-heterocyclic carbene-Pd(ii) complex and toxicity of the ligand precursor for the marine benthic copepod Amphiascoides atopus

Jorge Cárdenas, Ruben Gaviño, Eréndira García-Ríos, Lucero Rios-Ruiz, Ana C. Puello-Cruz, Francisco Neptalí Morales-Serna, Samuel Gómez, Adolfo López-Torres and José Antonio Morales-Serna

RSC Adv., 2021, 11, 20278
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Accessing a Biologically Relevant Benzofuran Skeleton by a One-Pot Tandem Heck Alkynylation/Cyclization Reaction Using Well-Defined Palladium N-Heterocyclic Carbene Complexes

Anuj Kumar, Manoj Kumar Gangwar, A. P. Prakasham, Darshan Mhatre, Alok Ch. Kalita and Prasenjit Ghosh

Inorg. Chem., 2016, 55, 2882
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Triazolylidene Iridium Complexes for Highly Efficient and Versatile Transfer Hydrogenation of C═O, C═N, and C═C Bonds and for Acceptorless Alcohol Oxidation

Zahra Mazloomi, René Pretorius, Oscar Pàmies, Martin Albrecht and Montserrat Diéguez

Inorg. Chem., 2017, 56, 11282
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Catalytic cross-coupling reaction of aryl iodides with triarylbismuths by an N-heterocyclic carbene-PdCl2 based on benzo-9-crown-3 catalyst at room temperature

Jia-Qi Liu, Jun-Juan Yang, Jun-Fei Li, Kai Li, Xue-Dong Xiao, Ya-Li Bai and Jun-Wen Wang

Molecular Catalysis, 2017, 443, 125
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Mechanistic Exploration of the Transmetalation and Reductive Elimination Events Involving PdIV–Abnormal NHC Complexes in Suzuki–Miyaura Coupling Reactions: A DFT Study

Totan Mondal, Sriman De, Sayan Dutta and Debasis Koley

Chemistry A European J, 2018, 24, 6155
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Exploring the Oxidative‐Addition Pathways of Phenyl Chloride in the Presence of PdIIAbnormal N‐Heterocyclic Carbene Complexes: A DFT Study

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Chemistry A European J, 2016, 22, 15778
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Synthesis, hemilability, and catalytic transfer hydrogenation activity of iridium(III) and ruthenium(II) complexes containing oxygen-functionalised triazolylidene ligands

René Pretorius, Zahra Mazloomi and Martin Albrecht

Journal of Organometallic Chemistry, 2017, 845, 196
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Suzuki–Miyaura and Hiyama coupling catalyzed by PEPPSI-type complexes with non-bulky NHC ligand

Marta Osińska, Andrzej Gniewek and Anna M. Trzeciak

Journal of Molecular Catalysis A: Chemical, 2016, 418-419, 9
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One-Pot Tandem Hiyama Alkynylation/Cyclizations by Palladium(II) Acyclic Diaminocarbene (ADC) Complexes Yielding Biologically Relevant Benzofuran Scaffolds

Chandan Singh, A. P. Prakasham, Manoj Kumar Gangwar, Raymond J. Butcher and Prasenjit Ghosh

ACS Omega, 2018, 3, 1740
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Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents

Xavier Marset, Beatriz Saavedra, Nerea González-Gallardo, Alexander Beaton, Martín M. León, Raúl Luna, Diego J. Ramón and Gabriela Guillena

Front. Chem., 2019, 7
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1,4‐Conjugate Addition of Aryl boronic Acids on Cyclohexenone as Catalyzed by Rhodium(I) Complexes of C2‐Symmetric Bioxazoline Fused N‐heterocyclic Carbenes

Balasubramaniyam Ramasamy, A. P. Prakasham, Manoj Kumar Gangwar and Prasenjit Ghosh

ChemistrySelect, 2019, 4, 8526
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Chiral Oxazolidine‐Fused N‐Heterocyclic Carbene Complexes of Rhodium and Iridium and Their Utility in the Asymmetric Transfer Hydrogenation of Ketones

Balasubramaniyam Ramasamy, Manoj Kumar Gangwar and Prasenjit Ghosh

Eur J Inorg Chem, 2017, 2017, 3253
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Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis, Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction

Lara Hettmanczyk, Bianca Schmid, Stephan Hohloch and Biprajit Sarkar

Molecules, 2016, 21, 1561
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Transition Metal Catalyzed Hiyama Cross-Coupling: Recent Methodology Developments and Synthetic Applications

Rida Noor, Ameer Fawad Zahoor, Muhammad Irfan, Syed Makhdoom Hussain, Sajjad Ahmad, Ali Irfan, Katarzyna Kotwica-Mojzych and Mariusz Mojzych

Molecules, 2022, 27, 5654
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Synthesis, characterization and the catalytic application of the N -heterocyclic carbene-PdCl 2 -cyanopyridine complexes

Jin Yang

Journal of Coordination Chemistry, 2024, 77, 1769
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Preparation and catalytic properties of the triphenylarsine and triphenylstibine-stabilized tri-heteroleptic NHC Pd‒allyl complexes

Jin Yang

Journal of Organometallic Chemistry, 2019, 883, 35
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[(NHC)Pd(allyl)Cl] Precatalysts in The Hiyama Reaction of Aryl Chlorides with Aryl Trimethoxysilanes: A Study in Side Reactions

Kasandra J. Brick, Meilin Q. Lim and Eric C. Keske

Organometallics, 2023, 42, 3192
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Accessing Heteroannular Benzoxazole and Benzimidazole Scaffolds via Carbodiimides Using Azide–Isocyanide Cross-Coupling as Catalyzed by Mesoionic Singlet Palladium Carbene Complexes Derived from a Phenothiazine Moiety

Shreyata Dey and Prasenjit Ghosh

ACS Omega, 2023, 8, 11039
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Mesoionic and Related Less Heteroatom-Stabilized N-Heterocyclic Carbene Complexes: Synthesis, Catalysis, and Other Applications

Ángela Vivancos, Candela Segarra and Martin Albrecht

Chem. Rev., 2018, 118, 9493
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PEPPSI-type palladium 1,2,3-triazolin-5-ylidene complexes – Synthesis, structure and catalytic properties in Suzuki-Miyaura coupling

Sylwia Ostrowska, Maciej Kubicki and Cezary Pietraszuk

Inorganica Chimica Acta, 2018, 482, 317
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A General Palladium‐Catalyzed Hiyama Cross‐Coupling Reaction of Aryl and Heteroaryl Chlorides

On Ying Yuen, Chau Ming So, Ho Wing Man and Fuk Yee Kwong

Chemistry A European J, 2016, 22, 6471
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An Efficient Synthetic Approach to trans‐(NHC)2Pd(R)Br Type Complexes and Their Use in Suzuki–Miyaura Cross‐Coupling Reactions

Anuj Kumar, A. P. Prakasham, Manoj Kumar Gangwar, Pratap Vishnoi, Raymond J. Butcher and Prasenjit Ghosh

Eur J Inorg Chem, 2017, 2017, 2144
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Competition between the Hiyama and Suzuki–Miyaura Pd-catalyzed cross-coupling reaction mechanisms for the formation of some regioselective derivatives of quinoxaline and benzofuran; Which reaction mechanism is more favorable?

Zeinab Ahmadvand and Mehdi Bayat

Journal of Molecular Liquids, 2021, 325, 115174
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New (NHC)Pd(II)(PPh3) complexes: synthesis, characterization, crystal structure and its application on Sonogashira and Mizoroki–Heck cross-coupling reactions

Fatoş Erdemir, Aydın Aktaş, Duygu Barut Celepci and Yetkin Gök

Chem. Pap., 2020, 74, 99
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Metal Complexes of Click-Derived Triazoles and Mesoionic Carbenes: Electron Transfer, Photochemistry, Magnetic Bistability, and Catalysis

David Schweinfurth, Lara Hettmanczyk, Lisa Suntrup and Biprajit Sarkar

Z. Anorg. Allg. Chem., 2017, 643, 554
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A comparison between (a/n-NHC)PdX2(pyridine) and (a/n-NHC)2PdX2 (X = I, Cl) type complexes of abnormal fused-bicyclic imidazo[1,2-a]pyridine based N-heterocyclic carbene (a-NHC) and of normal imidazole based N-heterocyclic carbene (n-NHC) ligands in the Suzuki-Miyaura coupling reactions

Sudipta Modak, Suchibrata Borah, A.P. Prakasham, Mobin M. Shaikh, Raymond J. Butcher, Manoj Gangwar and Prasenjit Ghosh

Inorganica Chimica Acta, 2019, 498, 119090
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Carbohydrate-Functionalized 1,2,3-Triazolylidene Complexes for Application in Base-Free Alcohol and Amine Oxidation

René Pretorius, Juan Olguín and Martin Albrecht

Inorg. Chem., 2017, 56, 12410
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Palladium Acyclic Diaminocarbene (ADC) Triflate Complexes as Effective Precatalysts for the Hiyama Alkynylation/Cyclization Reaction Yielding Benzofuran Compounds: Probing the Influence of the Triflate Co‐Ligand in the One‐Pot Tandem Reaction

Chandan Singh, A. P. Prakasham and Prasenjit Ghosh

ChemistrySelect, 2019, 4, 329
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Mono- and dinuclear palladium(II) complexes incorporating 1,2,3-triazole-derived mesoionic carbenes: syntheses, solid-state structures and catalytic applications

Xin Zhang, Xuechao Yan, Bo Zhang, Ran Wang, Shuai Guo and Shiyong Peng

Transit Met Chem, 2019, 44, 39
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Accessing Bioactive Hydrazones by the Hydrohydrazination of Terminal Alkynes Catalyzed by Gold(I) Acyclic Aminooxy Carbene Complexes and Their Gold(I) Arylthiolato and Gold(III) Tribromo Derivatives: A Combined Experimental and Computational Study

Jyoti Singh, Sunita Sharma, A. P. Prakasham, Gopalan Rajaraman and Prasenjit Ghosh

ACS Omega, 2023, 8, 21042
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Isolation and Structures of 1,2,3‐Triazole‐Derived Mesoionic Biscarbenes with Bulky Aromatic Groups

Haruka Iwasaki, Yuji Yamada, Ryuta Ishikawa, Yuji Koga and Kouki Matsubara

Eur J Org Chem, 2016, 2016, 1651
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Theoretical study of formation mechanism for 4-methyl-3-phenylbenzonitrile in the course of the Hiyama and Suzuki–Miyaura reactions

Zeinab Ahmadvand and Mehdi Bayat

Mendeleev Communications, 2023, 33, 252
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Cyanosilylation of Aromatic Aldehydes by Cationic Ruthenium(II) Complexes of Benzimidazole-Derived O-Functionalized N-Heterocyclic Carbenes at Ambient Temperature under Solvent-Free Conditions

Dharmendra Kumar, A. P. Prakasham, Sharmistha Das, Anindya Datta and Prasenjit Ghosh

ACS Omega, 2018, 3, 1922
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Prospects and Applications of Palladium Nanoparticles in the Cross‐coupling of (hetero)aryl Halides and Related Analogues

Jude I. Ayogu and Efeturi A. Onoabedje

ChemistryOpen, 2021, 10, 430
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Palladium(II), Rhodium(I), and Iridium(I) Complexes Containing O‐Functionalized 1,2,3‐Triazol‐5‐ylidene Ligands

René Pretorius, Ava McDonald, Ligia Regueira Beltrão da Costa, Helge Müller‐Bunz and Martin Albrecht

Eur J Inorg Chem, 2019, 2019, 4263
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Convenient access to amidines by mesoionic singlet palladium carbene catalyzed hydrazone-isocyanide-amine (HIA) coupling: Scope and mechanistic insights

Shreyata Dey, Chandra Sekhar Nettem, Gopalan Rajaraman and Prasenjit Ghosh

Molecular Catalysis, 2024, 553, 113735
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Piperazine‐ and DABCO‐bridged dinuclear N‐heterocyclic carbene palladium complexes: synthesis, structure and application to Hiyama coupling reaction

Haozhen Wang and Jin Yang

Applied Organom Chemis, 2017, 31
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Magnetic Lignosulfonate-Supported Pd Complex: Renewable Resource-Derived Catalyst for Aqueous Suzuki–Miyaura Reaction

Mahmoud Nasrollahzadeh, Zahra Issaabadi and Rajender S. Varma

ACS Omega, 2019, 4, 14234
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