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Formamidation of a wide range of substituted and functionalized amines with CO and a base

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Recent advances in N-formylation of amines and nitroarenes using efficient (nano)catalysts in eco-friendly media

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Catalyst-free highly regioselective hydrated ring-opening and formylation of quinazolinones

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Metal-Free N-Formylation of Amines Using Carbohydrates as C1 Synthon via C–C Bond Cleavage

Shital Atpadkar and Manjinder Singh Gill

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An ultrasound-promoted green approach for the N-formylation of amines under solvent- and catalyst-free conditions at room temperature

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Carbon Nanotube–Gold Nanohybrid Catalyzed N‐Formylation of Amines by using Aqueous Formaldehyde

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Substrate-controlled selective acylation of quinazolinones: Access to 2-benzamido-N-formylbenzamides and 3-benzoylquinazolinones

Xianglin Yu, Peng Chen, Ling Jiang, Jun Lin and Yi Jin

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The DMSO-Catalyzed CO2 Reduction with 9-BBN as a Source for the Selective N-Formylation, Room Temperature N-Methylation of Amines, N-Hydroxymethylation of Heterocycles, and C–N Couplings

Ashok Kumar, Rohit Gupta and Ganesan Mani

J. Org. Chem., 2025, 90, 10316
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Direct acylation of aryl amines using dimethylformamide and dimethylacetamide as the acyl resources

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Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe3O4 Nanoparticles

Sabyuk Yang, Ahra Cho, Jin Hee Cho and Byeong Moon Kim

Nanomaterials, 2021, 11, 2101
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Catalytic reaction of methyl formate with amines to formamides

Jens Deutsch, Reinhard Eckelt, Angela Köckritz and Andreas Martin

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Mild Access to N‐Formylation of Primary Amines using Ethers as C1 Synthons under Metal‐Free Conditions

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A very simple and highly efficient procedure for N-formylation of primary and secondary amines at room temperature under solvent-free conditions

Goutam Brahmachari and Sujay Laskar

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Sustainable Catalyst-free N-formylation using CO2 as a Carbon Source

Zhengyi Li, Song Yang and Hu Li

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Synthesis of 3-benzylquinoxalin-2(1H)-ones and 4-formyl-3-benzyl-3,4-dihydroquinoxalin-2(1H)-ones from 3-aryloxirane-2-carboxamides via 5-arylidene-2,2-dimethyl-1,3-oxazolidin-4-ones

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Approach for the synthesis of N-phenylamides from β-ketobutylanilides using dimethylformamide and dimethylacetamide as the acyl donors

Cui Chen, Liquan Tan and Peng Zhou

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Biocatalytic N‐Acylation of Amines in Water Using an Acyltransferase from Mycobacterium smegmatis

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Deep eutectic solvent promoted highly efficient synthesis of N, N’-diarylamidines and formamides

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Solvent‐Free Iridium‐Catalyzed Reactivity of CO2 with Secondary Amines and Hydrosilanes

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Metallophytes for organic synthesis: towards new bio-based selective protection/deprotection procedures

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Protic [TBD][TFA] ionic liquid as a reusable and highly efficient catalyst for N-formylation of amines using formic acid under solvent-free condition

Seyed Meysam Baghbanian and Maryam Farhang

Journal of Molecular Liquids, 2013, 183, 45
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Rapid, solvent- and catalyst-free transamidation of aliphatic amines with formamide

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Synthesis of N-arylcarboxamides by the efficient transamidation of DMF and derivatives with anilines

Da-Wei Gu and Xun-Xiang Guo

Tetrahedron, 2015, 71, 9117
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A capable cobalt nano‐catalyst for the N‐formylation of various amines and its biological activity studies

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Deep eutectic solvents (DESs) as eco-friendly and sustainable solvent/catalyst systems in organic transformations

Sarita Khandelwal, Yogesh Kumar Tailor and Mahendra Kumar

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A Practical and General Base‐Catalyzed Carbonylation of Amines for the Synthesis of N‐Formamides

Wanfang Li and Xiao‐Feng Wu

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Silver-Catalyzed, N-Formylation of Amines Using Glycol Ethers

Bradley H. King, Michelle L. Wang, Kate A. Jesse, Guneet Kaur, Brianna Tran, Ryan Walser-Kuntz, Robert G. Iafe and Anna G. Wenzel

J. Org. Chem., 2020, 85, 13256
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ChemInform Abstract: A Novel Type of N‐Formylation and Related Reactions of Amines via Cyanides and Esters as Formylating Agents.

Kai Bao, Weige Zhang, Xiujuan Bu, Zhichun Song, Liang Zhang and Maosheng Cheng

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Recent developments on ultrasound assisted catalyst-free organic synthesis

Bubun Banerjee

Ultrasonics Sonochemistry, 2017, 35, 1
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