Alkynyl functionalized Al/P-based frustrated Lewis pairs – aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-PCC(H)-tBu]

Hans Klöcker, Steffi Roters, Alexander Hepp and Werner Uhl

Dalton Trans., 2015, 44, 12670
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N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

T.-G. Kocsor, G. Nemes, N. Saffon, S. Mallet-Ladeira, D. Madec, A. Castel and J. Escudié

Dalton Trans., 2014, 43, 2718
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Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

Jordann A. L. Wells, Muhammad Anwar Shameem, Arvind Kumar Gupta and Andreas Orthaber

Inorg. Chem. Front., 2020, 7, 4052
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Catalytic applications of transition-metal complexes bearing diphosphinidenecyclobutenes (DPCB)

Fumiyuki Ozawa and Masaaki Yoshifuji

Dalton Trans., 2006, 4987
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Unusual Phosphorus−Phosphorus Double Bond Contraction upon Mono- and Di-auration of a Diphosphene

David V. Partyka, Marlena P. Washington, Thomas G. Gray, James B. Updegraff III, John F. Turner and John D. Protasiewicz

J. Am. Chem. Soc., 2009, 131, 10041
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π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

Roland C. Fischer and Philip P. Power

Chem. Rev., 2010, 110, 3877
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Coordination Behavior of Sterically Protected Phosphaalkenes on the AuCl Moiety Leading to Catalytic 1,6‐Enyne Cycloisomerization

Matthias Freytag, Shigekazu Ito and Masaaki Yoshifuji

Chemistry An Asian Journal, 2006, 1, 693
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Facile [3+2] dimerization and formal dehydrogenative coupling mode of a cyanophenylphosphaallene

Shigekazu Ito, Sou Hashino, Noboru Morita, Masaaki Yoshifuji, Daisuke Hirose, Masae Takahashi and Yoshiyuki Kawazoe

Tetrahedron, 2007, 63, 10246
DOI: 10.1016/j.tet.2007.07.063

Aspects of Phosphaallene Chemistry: Heat-Induced Formation of 1,2-Dihydrophosphetes by Intramolecular Nucleophilic Aromatic Substitution and Photochemical Generation of Tricyclic Phosphiranes

Jonas C. Tendyck, Hans Klöcker, Lina Schürmann, Ernst-Ulrich Würthwein, Alexander Hepp, Marcus Layh and Werner Uhl

J. Org. Chem., 2020, 85, 14315
DOI: 10.1021/acs.joc.9b03056

Cooperative Gold Nanoparticle Stabilization by Acetylenic Phosphaalkenes

Andreas Orthaber, Henrik Löfås, Elisabet Öberg, Anton Grigoriev, Andreas Wallner, S. Hassan M. Jafri, Marie‐Pierre Santoni, Rajeev Ahuja, Klaus Leifer, Henrik Ottosson and Sascha Ott

Angewandte Chemie, 2015, 127, 10780
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Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond

Masaaki Yoshifuji

Molecules, 2022, 27, 1557
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Dynamic Chirality Control of tropos DPCB‐digold Skeleton by Chiral Binaphthyldicarboxylate

Shigekazu Ito, Masaki Nanko, Tomokazu Shinozaki, Masafumi Kojima, Kohsuke Aikawa and Koichi Mikami

Chemistry An Asian Journal, 2016, 11, 823
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3H‐Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β‐Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms

Hans Klöcker, Jonas C. Tendyck, Lukas Keweloh, Alexander Hepp and Werner Uhl

Chemistry A European J, 2019, 25, 4793
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Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing a 1,2-Diphenyl-3,4-diphosphinidenecyclobutene Ligand (DPCB)

Masaaki Okazaki, Akito Hayashi, Ching-Feng Fu, Shiuh-Tzung Liu and Fumiyuki Ozawa

Organometallics, 2009, 28, 902
DOI: 10.1021/om8010799

Preparation via Sterically Promoted SN2′ Substitution and Structural Characteristics of a Mes*‐Substituted Tertiary Ethynylphosphine

Shigekazu Ito, Masaki Nanko and Koichi Mikami

Heteroatom Chemistry, 2014, 25, 422
DOI: 10.1002/hc.21182

Transition Metal-Induced Cyclization of 1-Phosphabutadienes: Selective Formation of 1-Phosphet-2-ene or P═C-Substituted Phosphacyclohexene Ligands

Henry T. G. Walsgrove, Brian O. Patrick and Derek P. Gates

Organometallics, 2022, 41, 3399
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New Reactivity Patterns in 3H‐Phosphaallene Chemistry [Aryl‐P=C=C(H)‐tBu]: Hydroboration of the C=C Bond, Deprotonation and Trimerisation

Jonas C. Tendyck, Alexander Hepp, Ernst‐Ulrich Würthwein and Werner Uhl

Chemistry A European J, 2020, 26, 15977
DOI: 10.1002/chem.202002506

Low coordinate phosphorus compounds for 40 years in memory of the late professor François Mathey, Ecole Polytechnique

Masaaki Yoshifuji

Phosphorus, Sulfur, and Silicon and the Related Elements, 2022, 197, 408
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Preparation and X-ray analyses of siloxane-bridged acyclic and 8-membered cyclic phosphaethenes

Shigekazu Ito, Hiromichi Jin and Masaaki Yoshifuji

Journal of Organometallic Chemistry, 2007, 692, 243
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Neutral and Cationic Gold(I) Complexes with π-Conjugated Phosphasilene Ligands

Baolin Li, Tsukasa Matsuo, Takeo Fukunaga, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka and Kohei Tamao

Organometallics, 2011, 30, 3453
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Cooperative Gold Nanoparticle Stabilization by Acetylenic Phosphaalkenes

Andreas Orthaber, Henrik Löfås, Elisabet Öberg, Anton Grigoriev, Andreas Wallner, S. Hassan M. Jafri, Marie‐Pierre Santoni, Rajeev Ahuja, Klaus Leifer, Henrik Ottosson and Sascha Ott

Angew Chem Int Ed, 2015, 54, 10634
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Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems

Aleksandra Ziółkowska, Justyna Doroszuk and Łukasz Ponikiewski

Organometallics, 2023, 42, 505
DOI: 10.1021/acs.organomet.2c00379

Group 14 and 15 Heteroallenes ECC and ECE‘

Jean Escudié and Henri Ranaivonjatovo

Organometallics, 2007, 26, 1542
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Gold(I) Complexation of Phosphanoxy‐Substituted Phosphaalkenes for Activation‐Free LAuCl Catalysis

Miki Kato, Yasuhiro Ueta and Shigekazu Ito

Chemistry A European J, 2021, 27, 2469
DOI: 10.1002/chem.202004281

Improved Preparative Method for 1,2-Diaryl-3,4-diphosphinidenecyclobutenes and Its Application to the Studies of 1,2-Bis(arylthienyl)-3,4-diphosphinidenecyclobutenes

Kozo Toyota, Keiko Horikawa, Rader S Jensen, Kouhei Omori, Subaru Kawasaki, Shigekazu Ito, Masaaki Yoshifuji and Noboru Morita

Bulletin of the Chemical Society of Japan, 2007, 80, 1580
DOI: 10.1246/bcsj.80.1580

π‐Extended DPCB for Activation‐Free Homogeneous Gold Catalysis

Shigekazu Ito, Masaki Nanko and Koichi Mikami

ChemCatChem, 2014, 6, 2292
DOI: 10.1002/cctc.201402158

Design, Synthesis, and Application of Phosphaalkenes to Unique Palladium and Gold Catalysts

Shigekazu Ito, Matthias Freytag, Hongze Liang, Katsunori Nishide and Masaaki Yoshifuji

Phosphorus, Sulfur, and Silicon and the Related Elements, 2008, 183, 555
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