Issue 19, 2020

Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Abstract

Herein, novel photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O is reported. The protocol was compatible with a variety of functionalities, including halogen, alkoxy, cyano, sulfonyl, trimethylsilyl, trifluoromethoxy, alkyl, hydroxyl, free acid, amide, and heteroaromatic rings. A wide range of deuterated products were obtained in good yields with a high level of deuteration. This method provides a green and practical pathway to synthesize deuterium labelled compounds under mild conditions.

Graphical abstract: Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Supplementary files

Article information

Article type
Communication
Submitted
26 اردیبهشت 1399
Accepted
11 تیر 1399
First published
20 تیر 1399

Green Chem., 2020,22, 6323-6327

Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Y. Lang, X. Peng, C. Li and H. Zeng, Green Chem., 2020, 22, 6323 DOI: 10.1039/D0GC01649G

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