Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges

Masahide Tominaga; Shoyo Shinkawa; Tadashi Hyodo; Kentaro Yamaguchi

doi:10.1039/D1CE01003D

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Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges†

Masahide Tominaga,

*^a Shoyo Shinkawa,^a Tadashi Hyodo^a and Kentaro Yamaguchi

*^a

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* Corresponding authors

^a Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan
E-mail: tominagam@kph.bunri-u.ac.jp, kyamaguchi@kph.bunri-u.ac.jp

Abstract

An adamantane-based macrocycle with pyrazine parts produced three inclusion crystals possessing different shapes and sizes of one-dimensional channels. Single-crystal to single-crystal guest exchanges occurred for two crystals. The supramolecular organic frameworks were structurally changed for one crystal and preserved for the other.

This article is part of the themed collection: Supramolecular & Polymorphism

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DOI: https://doi.org/10.1039/D1CE01003D
Article type: Communication
Submitted: 09 مرداد 1400
Accepted: 01 مهر 1400
First published: 07 مهر 1400

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CrystEngComm, 2021,23, 7039-7043

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Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges

M. Tominaga, S. Shinkawa, T. Hyodo and K. Yamaguchi, CrystEngComm, 2021, 23, 7039 DOI: 10.1039/D1CE01003D

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CrystEngComm

Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges†

Abstract

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Dynamic behavior of macrocycle-based organic frameworks in single-crystal to single-crystal guest exchanges

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