Issue 18, 2020

Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry

Abstract

We provide an overview of chemical transformations that proceed spontaneously, by mixing of initially solid reactants, and are accelerated and/or directed through gentle stimuli in the form of mild heating, exposure to diverse gas or vapour environments, brief mechanical milling, and/or the presence of catalysts. This broad overview illustrates how such accelerated ageing (AA) reactions could provide a route to develop operationally simple, as well as safe, inexpensive and materials- and energy-efficient processes for the environmentally-friendly synthesis of diverse organic and metal–organic materials and molecules.

Graphical abstract: Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry

Article information

Article type
Critical Review
Submitted
12 تیر 1399
Accepted
06 شهریور 1399
First published
07 شهریور 1399

Green Chem., 2020,22, 5881-5901

Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry

I. Huskić, C. B. Lennox and T. Friščić, Green Chem., 2020, 22, 5881 DOI: 10.1039/D0GC02264K

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