Construction of axially chiral 2-arylpyrroles using catalytic asymmetric Suzuki–Miyaura cross-coupling: an efficient approach to esaxerenone

Abstract

An efficient method has been developed to access axially chiral 2-arylpyrroles using catalytic asymmetric Suzuki–Miyaura cross-coupling. The catalytic asymmetric synthesis of esaxerenone was carried out in a faster way.

Catalytic activity of a palladium(II) complex modified on multi-wall carbon nanotubes: an efficient catalyst for the Suzuki cross-coupling reaction

Abstract

We prepared a novel palladium (Pd) catalyst by loading palladium chloride onto novel functionalized multi-wall carbon nanotubes (MWCNTs). The Pd(II)/MWCNT complex efficiently and selectively catalyzed large-scale synthesis of target molecules with high yield and large turnover numbers.

Iridium-catalyzed P(III)-directed ortho-C–H silylation of arylphosphines with hydrosilanes

Abstract

An iridium-catalyzed, P(III)-directed C–H silylation of commercial monophosphine ligands has been developed, providing modular access to ortho-silylated ligands.

CHAPTER 4
Ligand Replacement Reactions of Octahedral Complexes

CHAPTER 5
Catalysed Reactions and Formation Reactions

CHAPTER 3
Ligand Replacement Reactions of Metal Complexes of Coordination Number Four and Higher

CHAPTER 1
Reactions of Metal Complexes

CHAPTER 7
Electron Transfer Reactions