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Aryl sulfonyl fluoride synthesisviapalladium-catalyzed fluorosulfonylation of aryl thianthrenium salts

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Recent advances in photochemical and electrochemical strategies for the synthesis of sulfonyl fluorides

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Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones

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Electrochemically promoted defluorinative sulfoximination and fluorosulfonylation of non-activated aryl fluorides at room temperature

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Photocatalytic hydro-fluorosulfonylation of alkenes with N-fluorosulfonyl aldimines

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Photoredox-catalyzed radical fluorosulfonylation of allyl sulfones

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Direct electrochemical synthesis of arenesulfonyl fluorides from nitroarenes: a dramatic ionic liquid effect

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Green Chem., 2024, 26, 3435
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Aryl sulfonyl fluoride synthesis via organophotocatalytic fluorosulfonylation of diaryliodonium salts

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Org. Biomol. Chem., 2023, 21, 7597
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Amidation of β‐Keto Sulfonyl Fluorides via C−C Bond Cleavage

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Recent Advances in Developing Radical Methods for the Synthesis of Aliphatic Sulfonyl Fluorides

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Eur J Org Chem, 2024, 27
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Radical Ring-Opening Fluorosulfonylation of Methylenecyclobutanols via Electron Donor–Acceptor Photoactivation

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Frontiers of Synthesis Methodology and Application of Sulfonyl Fluorides (R–SO2F): Green Transformation and Target Expansion Driven by Click Chemistry

Qingqing Zhao, Xiaoxi Chen, Hanhan Song and Yadong Zhang

ChemistrySelect, 2026, 11
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Electrochemical Radical Fluorosufonylation of Allyl Bromides

Bingcong Liu, Hui Liang, Yanju Lu and Shenlin Huang

Org. Lett., 2025, 27, 2170
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Copper-mediated assembly of SO2F group via radical fluorine-atom transfer strategy

Yu-Yu Tan, Lin-Heng He and Wei-Min He

Chinese Chemical Letters, 2024, 35, 109986
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Imidazolium and benzimidazolium sulfonyl salts: Versatile functional group transfer reagents

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Electrochemical Conversion of N‐Sulfinylamines to Sulfonimidoyl Fluorides

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Chin. J. Chem., 2025, 43, 769
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Sulfonyl fluoride synthesis via visible-light-mediated fluorosulfonylation of thianthrenium salts

Lingling Shan, Zhanhu Ma, Caiyun Ou, Yinxia Cai, Yuyang Ma, Yong Guo, Xiaoyu Ma and Chao Liu

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Synthesis of Multisubstituted 4H-Chromenes via Brønsted Base- Mediated Tandem Cyclization Reactions of β-(2-Hydroxyaryl) Ethenesulfonyl Fluorides and β,γ-Unsaturated Ketoesters (Ynones)

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Chinese Journal of Organic Chemistry, 2024, 44, 3365
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Visible Light‐Mediated Radical Hydro‐Fluorosulfonylation of Propargylamines

Hangbing Liu, Yingyin Zhang, Yi Duan, Qixin Jia, Tianyu He, Yu Zheng and Shenlin Huang

Chemistry An Asian Journal, 2025, 20
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Unconventional reactivity of sulfonyl fluorides

Juan J. Rojas and James A. Bull

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Photoinduced Double 1,2-Carbon Migration toward All-Carbon Tetrasubstituted Olefins

Tianyu He, Chao Kong, Yukai Liu, Yu Zheng, Yanju Lu, Xiaoxiang Zhang and Shenlin Huang

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Copper-Mediated Radical Fluorine-Atom Transfer to Sulfonyl Radical: A Dramatic 4-Methoxypyridine 1-Oxide Ligand Effect

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Progress in Radical Fluorosulfonyl Reagents

Heyin Li and Yi Wang

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Photoredox-Catalyzed Three-Component Construction of Aryl Sulfonyl Fluoride Using KHF2: Late-Stage Drug Fluorosulfonylation

Hanhan Sun, Wanqing Meng, Xiaoxu Ma, Zhiling Cheng, Cheng Chen, Yan Ni, Fengying Yan, Qiaomei Zhu, Ping Zhang and Xianwei Sui

J. Org. Chem., 2024, 89, 16594
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Aliphatic Sulfonyl Fluoride Synthesis via Decarboxylative Fluorosulfonylation of Hypervalent Iodine(III) Carboxylates

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Org. Lett., 2023, 25, 6751
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Selective Fluorosulfonylation of Thianthrenium Salts Enabled by Electrochemistry

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Synthesis of β‐Alkynyl Sulfonyl Fluorides from Olefins: A Fluorosulfonyl Radical Ternary Reaction via Metallo/Photoredox Synergy†

Rongbiao Wei, Yao Huang, Honghai Zhang, Yuanming Li and Saihu Liao

Chin. J. Chem., 2026, 44, 1965
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Photoredox-Catalyzed Radical–Radical Cross-Coupling of Sulfonyl Chlorides with Trifluoroborate Salts

Sheng-Ping Liu, Yan-Hong He and Zhi Guan

J. Org. Chem., 2023, 88, 11161
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Iron-catalyzed sulfur alkylation of sulfenamides with in situ-generated 2,2,2-trifluorodiazoethane

Xianda Wu, Minghong Chen, Shuiyun Zheng, Fu-Sheng He and Jie Wu

Journal of Fluorine Chemistry, 2024, 273, 110219
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Shuttle Hydrogen Atom Transfer for Hydro-Fluorosulfonylation of Haloalkynes without β-Scission

Tianyu He, Yi Duan, Qixin Jia, Yanju Lu, Xiaoxiang Zhang, Yan Zhao and Shenlin Huang

Org. Lett., 2025, 27, 13591
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Synthesis and Structural Insights into 1,4‐Bis(phenylsulfonyl)‐1H‐pyrazol‐5‐amine Derivatives via a One‐Pot Domino Reaction

Lingyun Li, Li Hu and Zhengyu Zhang

ChemistrySelect, 2025, 10
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Electro-Oxidative Three-Component Synthesis of 3,5-Disubstituted-1,2,4-Thiadiazoles from Amines, Amidines, and CS2

Peng-Fei Huang, Ying Peng, Jia-Le Fu, Bo Li, Quan Zhou and Yu Liu

J. Org. Chem., 2025, 90, 4819
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Visible-Light-Enabled Fluorosulfonylalkynylation of Alkenes

Yucai Tang, Qiangsheng He, Jiale Liu, Jiaming Huang, Yonghao Li, Yao-Dan Xu, Jun-Ji Lu, Hai-Tao Zhu and Wei-Min He

Org. Lett., 2026, 28, 1042
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Cyano-Fluorosulfonylation of Unactivated Alkenes by Photoredox and Copper Dual Catalysis

Rongbiao Wei, Yao Huang, Oleg I. Afanasyev, Yuanming Li, Denis Chusov and Saihu Liao

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Organophotocatalytic Radical Chloro-fluorosulfonylation of Alkynyl Cyclohexadienones

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Org. Lett., 2026, 28, 6109
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Research Progress in Free Radical Fluorosulfonylation

Jia Zhao, Qiuyun Gan and Yaofeng Yuan

Chinese Journal of Organic Chemistry, 2025, 45, 1206
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Radical Fluorosulfonylation/Double Diels–Alder Sequence to Access Tricyclo[3.2.1.02,7]octanes

Hui Liang, Shengchun Hu, Shuai Shi, Yingyin Zhang, Tianyu He, Yu Zheng and Shenlin Huang

Org. Lett., 2025, 27, 5894
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Fluorosulfonyl Arylation of Alkynes via Electron Donor–Acceptor Photoactivation

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Org. Lett., 2024, 26, 3581
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Switchable carbo-fluorosulfonylation and hydro-fluorosulfonylation of alkenes enabled by bifunctional fluorosulfonyl radical precursors

Ting Xiong, Qi-Long Chen, Zhi-Da Chen, Ji-Tao Yi, Sheng-Cai Wang, Gui Lu, Albert S.C. Chan and Jiang Weng

Chem Catalysis, 2023, 3, 100821
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Electrochemical Synthesis of 5-Amino-1,2,4-thiadiazoles from Elemental Sulfur, Isocyanides, and Amidines

Peng-Fei Huang, Ying Peng, Zhi-Gang Quan, Ke-Wen Tang and Yu Liu

J. Org. Chem., 2025, 90, 10048
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Recent Advancement in the Synthesis of Sulfonyl Fluorides with Heterocyclic Skeletons

Yi‐Chen Dong and Li‐Jing Wang

Adv Synth Catal, 2025, 367
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Aminofluorosulfonylation of β,γ-Unsaturated Hydrazones with Sulfur Dioxide and N-Fluorobenzenesulfonimide: Accessing Pyrazoline-Functionalized Aliphatic Sulfonyl Fluorides

Zhi-Min Yan, Lin Qi, Tong-Yang Cao, Jia-Li Liu, Hui-Jie Du, Yi-Chen Dong, Wei Li and Li-Jing Wang

Org. Lett., 2023, 25, 3910
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Recent progress in sulfonyl fluoride synthesis via the radical sulfur dioxide insertion and fluorination strategy

Haozhen Zhang, Wangchuan Xiao, Fanhong Wu, Xiaoyu Ma and Chao Liu

Sci. China Chem., 2025, 68, 1763
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Electrochemical Continuous-Flow Fluorosulfonylation of Allenols

Tianyu He, Fengrui Xiang, Yi Duan, Qian Liu, Yu Zheng, Xiaoxiang Zhang, Minyan Wang and Shenlin Huang

Org. Lett., 2025, 27, 8099
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