Impact of a polymer modifier on directing the non-classical crystallization pathway of TS-1 zeolite: accelerating nucleation and enriching active sites

Jiani Zhang, Risheng Bai, Yida Zhou, Ziyi Chen, Peng Zhang, Jiyang Li and Jihong Yu

Chem. Sci., 2022, 13, 13006
DOI: 10.1039/D2SC04544C

Ethanol-assisted synthesis of titanium-rich TS-1 zeolite: a new hexa-coordinated Ti site for efficient propylene epoxidation

Dapeng Hao, Xintong Li, Guangyuan He, Risheng Bai, Yang Bai, Tianjun Zhang, Lisu Bai, Jialiang Li, Qiang Zhang, Donghai Mei, Zhaochi Feng and Jihong Yu

Chem. Sci., 2025, 16, 4661
DOI: 10.1039/D4SC08720H

The synthesis of pure and uniform nanosized TS-1 crystals with a high titanium content and a high space–time yield

Lejian Zhang, Xiaoxiao Zhu, Xinping Wang and Chuan Shi

Inorg. Chem. Front., 2021, 8, 5260
DOI: 10.1039/D1QI01022K

A review on the active sites for titanium species in zeolites: coordination structure, synthetic strategies and activity

Yihao Wang, Kaiwei Wang, Fumin Wang, Yi Zhai, Changhao Bing, Xiaolu Fan, Qi Shen and Xubin Zhang

Mater. Chem. Front., 2025, 9, 8
DOI: 10.1039/D4QM00759J

Coupling electrochemical H2O2 production and the in situ selective oxidation of organics over a bifunctional TS-1@Co–N–C catalyst

Shutao Wu, Hongliang Zhang, Xun Huang and Zidong Wei

Chem. Commun., 2022, 58, 8942
DOI: 10.1039/D2CC03181G

Synthesis of ultra-fine TS-1 catalyst with high titanium content and its performance in phenol hydroxylation

Safoura Bakhodaye Dehghanpour, Mansour Razavi and Fahimeh Parvizian

New J. Chem., 2023, 47, 19439
DOI: 10.1039/D3NJ03744D

Morphology and Microstructural Optimization of Zeolite Crystals Utilizing Polymer Growth Modifiers for Enhanced Catalytic Application

Junling Zhan, Chongyao Bi, Xiaohui Du, Tao Liu and Mingjun Jia

Catalysts, 2024, 14, 375
DOI: 10.3390/catal14060375

Preparation of anatase-free hierarchical titanosilicalite-1 in favor of allyl chloride epoxidation

Meng Liu, Jieqiong Li, Xingchi Chen, Jie Song, Wei Wei, Yiqiang Wen and Xiangyu Wang

Microporous and Mesoporous Materials, 2021, 326, 111388
DOI: 10.1016/j.micromeso.2021.111388

Z-scheme Heterojunction on TS-1 Zeolite Boosting Ultrafast Visible-Light-Driven Degradation of Cr(VI) and Tetracycline

Jiayi Chen, Junxue Liu, Minghao Qin, Qinhe Pan and Jiyang Li

Inorg. Chem., 2025, 64, 19068
DOI: 10.1021/acs.inorgchem.5c03337

Synthesis of Sheet‐like Zeolite TS‐1 with Short b‐Axis for Epoxidation of 1‐Hexene

Min Zhang, Shenyong Ren, Qiaoxia Guo and Baojian Shen

ChemistrySelect, 2023, 8
DOI: 10.1002/slct.202203687

Effective incorporation of Ti atom into TS-1 zeolite assisted with oxalic acid additive

Piyapatch Techasarintr, Liu Yin, Yong Wang, Peipei Xiao, Samya Bekhti, Junko N Kondo and Toshiyuki Yokoi

Chemistry Letters, 2024, 53
DOI: 10.1093/chemle/upae170

Synthesis of High-Quality TS-1 Zeolites Using Precursors of Diol-Based Polymer and Tetrapropylammonium Bromide for 1-Hexene Epoxidation

Yuting Sun, Xinyu Chang, Junling Zhan, Chongyao Bi, Zhehan Dong, Shuaishuai Sun and Mingjun Jia

Catalysts, 2024, 14, 939
DOI: 10.3390/catal14120939

Synthesis of Ti-MWW Zeolite by Refluxing and Implanting Titanium Method and Further Application in 1-Hexene Epoxidation

Jidong Chu, Zhijin Ge, Jiahui Peng, Hui Hu, Shujuan Guo and Xiaohui Chen

Catal Lett, 2023, 153, 348
DOI: 10.1007/s10562-022-03964-x

A review on titanosilicate-1 (TS-1) catalysts: Research progress of regulating titanium species

Baohe Wang, Yanke Guo, Jing Zhu, Jing Ma and Qiaoyun Qin

Coordination Chemistry Reviews, 2023, 476, 214931
DOI: 10.1016/j.ccr.2022.214931

Catalytic Depolymerization of Lignin over B–Ti-Modified Diatomite-Supported Nickel Phosphide Catalysts Using Formic Acid-Assisted Aqueous-Phase Glycerol

Mingqiang Chen, Yupei Li, Yishuang Wang, Defang Liang, Chang Li, Haosheng Xin and Jun Wang

Energy Fuels, 2025
DOI: 10.1021/acs.energyfuels.5c00625

Fully utilizing seeds solution for solvent-free synthesized nanosized TS-1 zeolites with efficient epoxidation of chloropropene

Hanfang Liu, Yu Wang, Tiantian Ye, Fupeng Wang, Saisai Ran, Huijie Xie, Jia Liu, Yichuan Li, Bin Li, Yanru Liu, Yongming Chai and Lei Wang

Journal of Solid State Chemistry, 2022, 307, 122844
DOI: 10.1016/j.jssc.2021.122844

Preparation of hierarchical TS-1 molecular sieve membrane catalyst and its catalytic performance for chloropropylene epoxidation

Zhaosheng Yang, Guoqiang Tang, Yichuan Li, Xiaoyue Niu, Lingyao Cheng and Yongming Chai

J Porous Mater, 2024, 31, 793
DOI: 10.1007/s10934-023-01551-y

Charge transformation of framework titanium (Ⅳ) into titanium (Ⅲ) in vanadium-titanium doped MFI zeolite for enhanced alkene epoxidation

Guojun Lv, Yan Chen, Xuyang Zou, Jiangzhang Wang, Tao Wang, Fumin Wang and Xubin Zhang

Microporous and Mesoporous Materials, 2022, 341, 112035
DOI: 10.1016/j.micromeso.2022.112035

Synthesis of Plate-Like TS-1 Zeolites with a Controllable b-Axis Thickness and Ti Coordination States

Hongyu Wang, Fumin Wang, Kaiwei Wang, Xubin Zhang, Changhao Bing, Xiaolu Fan, Tongxue Zhang and Syed Mujtaba ul Hassan

Crystal Growth & Design, 2025, 25, 4112
DOI: 10.1021/acs.cgd.4c01282

Lithocholic acid-modulated synthesis of anatase-free TS-1 zeolite with Ti-rich framework for superior alkene oxidation

Xiaojing Song, Shuang Liu, Shuang Gao, Zuochao Wang and Hao Zhang

Microporous and Mesoporous Materials, 2026, 399, 113853
DOI: 10.1016/j.micromeso.2025.113853

(NH4)2SO4-assisted synthesis of thin-walled Ti-rich hollow titanium silicalite-1 zeolite for 1-hexene epoxidation

Mengyao Li, Yi Zhai, Xubin Zhang, Fumin Wang, Guojun Lv, Ahishakiye Rosine, Mengyue Li, Qing Zhang and Yongkui Liu

Microporous and Mesoporous Materials, 2022, 331, 111655
DOI: 10.1016/j.micromeso.2021.111655

Addition of polyethylene glycol for the synthesis of anatase-free TS-1 zeolites with excellent catalytic activity in 1-hexene epoxidation

Xinyu Chang, Xiaotong Yang, Xiaojing Song, Lifen Xu, Dianwen Hu, Yuting Sun and Mingjun Jia

J Porous Mater, 2022, 29, 641
DOI: 10.1007/s10934-021-01186-x

Efficient and Eco-friendly Photocatalyst from TS-1 Decorated with Carbon Dots for Degradation of Organic Dyes

Jiani Zhang, Siyu Zong, Shiyu Zhou, Wenyan Ma and Jiyang Li

Crystal Growth & Design, 2025, 25, 5720
DOI: 10.1021/acs.cgd.5c00015

Recent advances in the synthesis of TS-1 zeolite

Huimin Luan, Cheng Xu, Qinming Wu and Feng-Shou Xiao

Front. Chem., 2022, 10
DOI: 10.3389/fchem.2022.1080554

Anatase-Free Nanosized Hierarchical Titanosilicate TS-1 Synthesis via Nitric Acid-Catalyzed Gel Preparation

Vera R. Bikbaeva, Sergey V. Bubennov, Dmitry V. Serebrennikov, Daria A. Ogurechnikova, Evgenii V. Vakulin, Boris I. Kutepov, Nellia G. Grigoreva and Anton L. Maximov

Gels, 2025, 11, 605
DOI: 10.3390/gels11080605

Aromatic compounds‐mediated synthesis of anatase‐free hierarchical TS‐1 zeolite: Exploring design strategies via machine learning and enhanced catalytic performance

Chang'an Wang, Guoqing An, Jing Lin, Xiaowei Zhang, Zhiyuan Liu, Yibin Luo, Siqi Liu, Zhixiang Cheng, Tingting Guo, Hongyi Gao, Ge Wang and Xingtian Shu

Aggregate, 2023, 4
DOI: 10.1002/agt2.318

Accelerated Synthesis of TS‐2 Zeolite via 2D Heterogeneous Nucleation for Efficient H2O2 Production

Xuguang Liu, Kai Huo, Junze Zhuang, Ling Shi, Zhenhua Yao, Maocong Hu, Guicun Li, Wengang Liu and Kangqing Deng

Small, 2024, 20
DOI: 10.1002/smll.202406294

Accelerated synthesis of TS-1 zeolite for epoxidation of 1-hexene under ambient environment: Role of sodium persulfate in inhibiting the formation of anatase species

Mengqi Wang, Bo Chen, Yan He, Zhili Li and Yuanyuan Ge

Applied Catalysis A: General, 2024, 679, 119730
DOI: 10.1016/j.apcata.2024.119730

TS-1 zeolite encapsulated Pt clusters with enhanced electronic metal-support interaction of Pt−O(H)−Ti for nearly-zero-carbon-emitting photocatalytic hydrogen production from methanol

Shangkun Tian, Hongxia Guo, Qiao Zhao, Li Liu, Huan Wang, Xiao Wang, Sheng Zhang and Wenquan Cui

Applied Catalysis B: Environment and Energy, 2024, 355, 124201
DOI: 10.1016/j.apcatb.2024.124201

Application of Mixed Acid-Modified Hollow TS-1 Zeolite to Vapor-Phase Beckman Rearrangement Reaction

Pengyu Yin, Jiayuan Nie, Xiangyu Wen, Zhihui Li, Dongsheng Zhang, Xinqiang Zhao and Yanji Wang

Catal Lett, 2024, 154, 6035
DOI: 10.1007/s10562-024-04780-1

Review and perspectives on TS-1 catalyzed propylene epoxidation

Jimei Yang, Shuling Liu, Yanyan Liu, Limin Zhou, Hao Wen, Huijuan Wei, Ruofan Shen, Xianli Wu, Jianchun Jiang and Baojun Li

iScience, 2024, 27, 109064
DOI: 10.1016/j.isci.2024.109064

Formation and Stability of μ2-Peroxo on Titanosilicates, Anatase, and Rutile: Implications for Zeotype Catalysts

Lukas Lätsch, Imke B. Müller, Christoph J. Kaul, Trees De Baerdemaeker, Andrei-Nicolae Parvulescu, Karsten Seidel, J. Henrique Teles, Natalia Trukhan and Christophe Copéret

J. Phys. Chem. C, 2024, 128, 5553
DOI: 10.1021/acs.jpcc.3c08292

Novel titanium-containing precursors for the fabrication of hierarchical TS-1 and the enhanced catalytic performance for olefins

Chang'an Wang, Ying Ouyang, Yibin Luo, Kunfeng Gao, Xing Chen, Shuya Zhao, Qibin Yang and Hongyi Gao

Chemical Physics Letters, 2024, 835, 140995
DOI: 10.1016/j.cplett.2023.140995

A Review on Understanding and Strengthening of Active Species in Titanium Silicalite‐1 (TS‐1) Catalysts

Yan Xue, Shuling Liu, Jiaqi Wang, Huanhuan Zhang, Huijuan Wei, Yanyan Liu, Xiangyu Wang, Jinjun Tian, Jianchun Jiang and Baojun Li

Advanced Science, 2025, 12
DOI: 10.1002/advs.202512531

Zeolite Nanocrystals (MOR, EU-1, and ZSM-12) Synthesized Using a Versatile Diquaternary Ammonium Template as Robust Catalysts

Shaojie Li, Anna Liutkova, Nikolay Kosinov and Emiel J. M. Hensen

ACS Appl. Nano Mater., 2022, 5, 16862
DOI: 10.1021/acsanm.2c03805

A novel MOFs-induced strategy for preparing anatase-free hierarchical TS-1 zeolite:synthesis routes, growth mechanisms and enhanced catalytic performance

Guoqing An, Chang'an Wang, Hongyi Gao, Ge Wang, Yibin Luo, Zhiyuan Liu, Changjiu Xia, Siqi Liu, Xinxin Peng, Zhixiang Cheng and Xingtian Shu

Journal of Colloid and Interface Science, 2023, 633, 291
DOI: 10.1016/j.jcis.2022.10.113

Optimization of MOFs-induced strategy for preparing anatase-free hierarchical TS-1 towards 1-hexene epoxidation: TPAOH dosage regulation, silanization and stabilizing acidic sites

Guoqing An, Hongyi Gao, Yibin Luo, Ying Ouyang, Ge Wang, Siqi Liu, Chang'an Wang, Zhiyuan Liu, Zhixiang Cheng and Xingtian Shu

Microporous and Mesoporous Materials, 2023, 360, 112704
DOI: 10.1016/j.micromeso.2023.112704

Tetrapropylammonium Hydroxide Treatment of Aged Dry Gel to Make Hierarchical TS-1 Zeolites for Catalysis

Zhenyuan Yang, Yanan Guan, Lei Xu, Yangtao Zhou, Xiaolei Fan and Yilai Jiao

Crystal Growth & Design, 2023, 23, 1775
DOI: 10.1021/acs.cgd.2c01291

Framework Zr-enriched hierarchical Zr-Si zeolites photocatalysts: Effects and mechanism of CTAB amount on photocatalytic performance

Hong-Ji Li, Wen-Juan Wang, Liu-Qing Wang, Li-Jun Chen and Cong Liu

Journal of Alloys and Compounds, 2025, 1013, 178563
DOI: 10.1016/j.jallcom.2025.178563