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Catalytic Atroposelective Dynamic Kinetic Resolution of Biaryl Lactones with Activated Isocyanides

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Catalytic Atroposelective Electrophilic Amination to Access Axially Chiral Diaryl Phenols

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Enantioselective Rhodium‐Catalyzed C−H Arylation Enables Direct Synthesis of Atropisomeric Phosphines

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Organocatalytic Atroposelective Cross‐Coupling of 1‐Azonaphthalenes and 2‐Naphthols

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Synthesis of Axially Chiral Biaryls via Enantioselective Ullmann Coupling ofortho‐Chlorinated Aryl Aldehydes Enabled by a Chiral 2,2′‐Bipyridine Ligand

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Atroposelective Synthesis of Enamine‐Based Axially Chiral Styrenes via CuH‐Catalyzed Hydroamination of Internal Alkynes

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A Dynamic Kinetic Resolution Approach to Axially Chiral Diaryl Ethers by Catalytic Atroposelective Transfer Hydrogenation

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Towards Axially Chiral Pyrazole‐Based Phosphorus Scaffolds by Dipeptide‐Phosphonium Salt Catalysis

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Organocatalytic Si–CAryl Bond Functionalization-Enabled Atroposelective Synthesis of Axially Chiral Biaryl Siloxanes

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Design and Catalytic Asymmetric Synthesis of Furan‐Indole Compounds Bearing both Axial and Central Chirality

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Advances in Catalytic Asymmetric Reactions Involving o-Hydroxybenzyl Alcohols

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Enantioselective Construction of Anthracenylidene-Based Axial Chirality by Asymmetric Heck Reaction

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Atroposelective Access to Dihydropyridinones with C–N Axial and Point Chirality via NHC-Catalyzed [3 + 3] Annulation

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Organocatalytic Enantioselective Synthesis of Axially Chiral N,N′‐Bisindoles

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Dynamic Kinetic Resolution of Indole-Based Sulfenylated Heterobiaryls by Rhodium-Catalyzed Atroposelective Reductive Aldol Reaction

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Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles

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Atroposelective Synthesis of N–N Axially Chiral Indoles and Pyrroles via NHC-Catalyzed Diastereoselective (3 + 3) Annulation Strategy

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Development of Configurationally Labile Biaryl Reagents for Atropisomer Synthesis

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Catalytic Atroposelective Synthesis of N–N Axially Chiral Indolylamides

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Chiral Phosphoric Acid–Palladium(II) Complex Catalyzed Asymmetric Desymmetrization of Biaryl Compounds by C(sp3)–H Activation

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Catalytic Atroposelective Nucleophilic Chlorination for the Synthesis of Chlorinated Atropisomers via Dual Photoredox/Nickel Catalysis

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Chemically Driven Rotatory Molecular Machines

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Construction of C‐N Atropisomers by Aminocatalytic Enantioselective Addition of Indole‐2‐carboxaldehydes to o‐Quinone Derivatives

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Chemistry A European J, 2022, 28
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Rhodium(I)‐Catalyzed Asymmetric Hydroarylative Cyclization of 1,6‐Diynes to Access Atropisomerically Labile Chiral Dienes

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Modular Assembly of Axially Chiral QUINAP Derivatives via Nickel-Catalyzed Enantioselective C–P Cross-Coupling

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Construction of Axially Chiral Indoles by Cycloaddition–Isomerization via Atroposelective Phosphoric Acid and Silver Sequential Catalysis

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From Peripheral Stereogenic Center to Axial Chirality: Synthesis of 3‐Arylthiophene Atropisomers

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Towards Axially Chiral Pyrazole‐Based Phosphorus Scaffolds by Dipeptide‐Phosphonium Salt Catalysis

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N-Heterocyclic Carbene-Catalyzed Atroposelective Synthesis of N–N Axially Chiral 3-Amino Quinazolinones

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Cobalt‐Catalyzed Regio, Diastereo, and Enantioselective C–H Annulation of Aminoquinoline Amides with Internal Alkynes for the Construction of Diaxes

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Synthesis of Alkene Atropisomers with Multiple Stereogenic Elements via Catalytic Asymmetric Rearrangement of 3‐Indolylmethanols

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Torsional Strain‐Independent Catalytic Enantioselective Synthesis of Biaryl Atropisomers

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Atroposelective desymmetrization of 2-arylresorcinols via Tsuji-Trost allylation

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Dynamic Kinetic Resolution of 2‐Hydroxybiaryl Atropisomers via Lipase‐Catalyzed Enantioselective O‐Acylation

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Application of Chiral Lewis Base/Brønsted Acid Synergistic Catalysis Strategy in Enantioselective Synthesis of Organic Sulfides

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Combinatorial Ligand Assisted Simultaneous Control of Axial and Central Chirality in Highly Stereoselective C−H Allylation

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Organocatalytic dynamic kinetic resolution of N-arylindole lactams: atroposelective construction of axially chiral amino acids bearing a C-N chiral axis

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Annulative π‐Extension by Rhodium(III)‐Catalyzed Ketone‐Directed C−H Activation: Rapid Access to Pyrenes and Related Polycyclic Aromatic Hydrocarbons (PAHs)

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Brønsted Acid‐Catalyzed Atroposelective Coupling of Carboxylic Acids with Amines and Alcohols via Ynamide Mediation

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Atroposelective Palladium‐Catalyzed γ‐C–H Olefination of BODIPYs

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Pd-Catalyzed Dynamic Kinetic Asymmetric Cross-Coupling of Heterobiaryl Bromides with N-Tosylhydrazones

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Atropisomeric Carboxylic Acids Synthesis via Nickel‐Catalyzed Enantioconvergent Carboxylation of Aza‐Biaryl Triflates with CO2

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N‐Heterocyclic carbene‐catalyzed Atroposelective Annulation for Access to Pyrrolo[3,4‐b]pyridines Derivatives with C−N Axial Chirality

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Stereogenic S-Induced Generation of Axially Chiral Cyclic Vinyl Sulfinamides and Serendipitous Diastereomeric Enrichment

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Bifunctional Photoactive Chiral Ligands Enable Visible‐Light‐Induced Nickel‐Catalyzed Enantioselective C−O Coupling

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Iridium‐Catalyzed Enantioselective and Diastereoselective Hydrogenation of Racemic β’‐Keto‐β‐Amino Esters via Dynamic Kinetic Resolution

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Organocatalytic Atroposelective Dynamic Kinetic Resolution Involving Ring Manipulations

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Construction of N–N Atropisomers Bearing Multiple Stereocenters via Desymmetrization of Indole-Derived Maleimides

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Construction of C−C Axial Chirality via Asymmetric Carbene Insertion into Arene C−H Bonds

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Asymmetric Olefin Isomerization via Phase-Transfer-Catalyzed [1,3]-Hydrogen Transfer for Access to Axially Chiral Furan-Benzimidazoles

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Catalytic Asymmetric Construction of Axially and Centrally Chiral Heterobiaryls by Minisci Reaction

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Enantioselective Construction of Chiral Azahelicenes through Catalytic Asymmetric Povarov-Type Cycloaddition Involving Alkynes

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Developing Biarylhemiboronic Esters for Biaryl Atropisomer Synthesis via Dynamic Kinetic Atroposelective Suzuki–Miyaura Cross-Coupling

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Atroposelective Synthesis of 1,1′‐Bipyrroles Bearing a Chiral N−N Axis: Chiral Phosphoric Acid Catalysis with Lewis Acid Induced Enantiodivergence

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Scalable Atroposelective Synthesis of MRTX1719: An Inhibitor of the PRMT5/MTA Complex

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Bifunctional Squaramide‐Catalyzed Oxidative Kinetic Resolution: Simultaneous Access to Axially Chiral Thioether and Sulfoxide

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Catalytic Atroposelective aza-Grob Fragmentation: An Approach toward Axially Chiral Biarylnitriles

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Asymmetric synthesis of chiral boronic esters featuring nonadjacent axial and flexible, acyclic central chirality

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Catalytic Asymmetric Synthesis of Axially Chiral 3,3'‐Bisindoles by Direct Coupling of Indole Rings

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Tri- and Tetra-ortho-Substituted Biaryls via Lithium Cuprate-Catalyzed Reductive Desymmetrization of Isophthaldehydes

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Organocatalytic Atroposelective Hydroselenation of Alkynes To Access Axially Chiral Vinyl Selenides

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Modular synthesis of polyfunctionalized axial-chiral 2-arylpyridines via cobalt-catalyzed asymmetric [2 + 2 + 2] cycloaddition of diynes and nitriles

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Preparation of Optically Active 2,2'‐Dibromo‐6,6'‐diiodo‐1,1'‐biphenyl: A Powerful Precursor for Modular Synthesis of Functionalized Atropisomers†

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Atroposelective Dynamic Kinetic Resolution via In Situ Hemiaminals Catalyzed by N-Heterocyclic Carbene

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Synthesis and biological evaluation of atropisomeric tetrahydroisoquinolines overcoming docetaxel resistance in triple-negative human breast cancer cells

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Advances in Catalytic Asymmetric Reactions Using 2-Indolylmethanols as Platform Molecules

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Bulky α-Diimine Palladium-Based Hyper-Cross-Linked Polymers: Highly Efficient Porous Catalysts for Direct C–H Heteroarylation

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Enantiospecific Syntheses of Congested Atropisomers through Chiral Bis(aryne) Synthetic Equivalents

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Chemistry A European J, 2022, 28
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Copper‐Catalyzed Enantioselective Dehydro‐Diels–Alder Reaction: Atom‐Economical Synthesis of Axially Chiral Carbazoles

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Catalytic Atroposelective Synthesis of Axially Chiral Azomethine Imines and Neuroprotective Activity Evaluation

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Atroposelective Three‐Component Coupling of Cyclic Diaryliodoniums and Sodium Cyanate Enabled by the Dual‐Role of Phenol

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Enantioselective Suzuki–Miyaura Coupling of Unactivated C–O Electrophiles via Nickel Catalysis

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Recent advances in atroposelective synthesis of axially chiral heterobiaryl featuring indole frameworks

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Chiral Phosphoric Acid Catalyzed Asymmetric Hydrolysis of Biaryl Oxazepines for the Synthesis of Axially Chiral Biaryl Amino Phenol Derivatives

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Organocatalytic Asymmetric Construction and Application of Axially Chiral Spiro‐bisindoles

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Copper-Catalyzed Asymmetric Ring-Opening Reaction of Cyclic Diaryliodonium Salts with Imides

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Recent Advances in Palladium-Catalyzed Enantioselective Cyclization for the Construction of Atropisomers

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Enantioconvergent synthesis of axially chiral amides enabled by Pd-catalyzed dynamic kinetic asymmetric aminocarbonylation

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Catalytic Atroposelective Electrophilic Amination of Indoles

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Construction of Axially Chiral 4-Aminoquinolines by Cycloaddition and Central-to-Axial Chirality Conversion

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DFT-Assisted Atroposelective Construction of Indole-Fused N-Heteroaromatic Frameworks through Palladium-Catalyzed C–H Imidoylation

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Iridium-Catalyzed Regiodivergent Atroposelective C–H Alkylation of Heterobiaryls with Alkenes

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Asymmetric synthesis of atropisomers featuring cyclobutane boronic esters facilitated by ring-strained B-ate complexes

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Biocatalytic Atroposelective Synthesis of Axially Chiral N-Arylindoles via Dynamic Kinetic Resolution

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Regiodivergent catalytic asymmetric dearomative cycloaddition of bicyclic heteroaromatics

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Rhodium‐Catalyzed Atroposelective Synthesis of Axially Chiral 1‐Aryl Isoquinolines via De Novo Isoquinoline Formation

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Organocatalytic Asymmetric [5 + 3] Domino Annulation: Direct Access to Enantioenriched Eight-Membered Bridged Dihydroazocino[4,5-b]indolizines

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One-pot borylation/arylation of 4-chloroquinolines and its application for the synthesis of various quinoline-based pharmacophores

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Catalytic Atroposelective Aerobic Oxidation Approaches to Axially Chiral Molecules

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One-Step Construction of Atropisomers Bearing 1,5-Central and Axial Chirality via Catalytic Diastereo- and Atroposelective Remote Desymmetrizing Alkynylation

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Enantioselective Strategies for The Synthesis of N−N Atropisomers

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Atroposelective synthesis of eight-membered lactam-bridged N-arylindoles via stepwise cut-and-sew strategy

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