Theoretical screening of single atoms anchored on defective graphene for electrocatalytic N2 reduction reactions: a DFT study

Pingping Liu, Cheng Fu, Yafei Li and Haiyan Wei

Phys. Chem. Chem. Phys., 2020, 22, 9322
DOI: 10.1039/C9CP06112F

Efficient electrohydrogenation of N2 to NH3 by oxidized carbon nanotubes under ambient conditions

Jinxiu Zhao, Bo Wang, Qiang Zhou, Huanbo Wang, Xianghong Li, Hongyu Chen, Qin Wei, Dan Wu, Yonglan Luo, Jinmao You, Feng (Frank) Gong and Xuping Sun

Chem. Commun., 2019, 55, 4997
DOI: 10.1039/C9CC00726A

Nitrogen reduction through confined electro-catalysis with carbon nanotube inserted metal–organic frameworks

Yang Lv, Yiqi Wang, Miao Yang, Zhangyan Mu, Shengtang Liu, Weiping Ding and Mengning Ding

J. Mater. Chem. A, 2021, 9, 1480
DOI: 10.1039/D0TA11797H

Screening of effective NRR electrocatalysts among the Si-based MSi2N4 (M = Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W) monolayers

Yao Luo, Mengyuan Li, Yuxin Dai, Xiaoli Zhang, Renqiang Zhao, Fan Jiang, Chongyi Ling and Yucheng Huang

J. Mater. Chem. A, 2021, 9, 15217
DOI: 10.1039/D1TA02998C

Single transition atom-doped antimonene as a highly efficient electrocatalyst for the nitrogen reduction reaction: a DFT study

Xiaopeng Shen, Chao Liu and Qinfang Zhang

Mater. Adv., 2024, 5, 730
DOI: 10.1039/D3MA00917C

2D MXene-derived Nb2O5/C/Nb2C/g-C3N4 heterojunctions for efficient nitrogen photofixation

Heyan Jiang, Cuicui Zang, Yinglan Zhang, Wenhai Wang, Chaofen Yang, Bin Sun, Yu Shen and Fengxia Bian

Catal. Sci. Technol., 2020, 10, 5964
DOI: 10.1039/D0CY00656D

Construction of PdO–Pd interfaces assisted by laser irradiation for enhanced electrocatalytic N2 reduction reaction

Jiali Lv, Shouliang Wu, Zhenfei Tian, Yixing Ye, Jun Liu and Changhao Liang

J. Mater. Chem. A, 2019, 7, 12627
DOI: 10.1039/C9TA02045D

Exploring the source of ammonia generation in electrochemical nitrogen reduction using niobium nitride

So Young Park, So Eun Jang, Chang Woo Kim, Youn Jeong Jang and Duck Hyun Youn

RSC Adv., 2023, 13, 34410
DOI: 10.1039/D3RA06475A

Bimetallic Ag3Cu porous networks for ambient electrolysis of nitrogen to ammonia

Hongjie Yu, Ziqiang Wang, Dandan Yang, Xiaoqian Qian, You Xu, Xiaonian Li, Hongjing Wang and Liang Wang

J. Mater. Chem. A, 2019, 7, 12526
DOI: 10.1039/C9TA03297E

Atomically dispersed metal catalysts for the electrochemical nitrogen reduction reaction

Hongfei Gu, Wenxing Chen and Xinyuan Li

J. Mater. Chem. A, 2022, 10, 22331
DOI: 10.1039/D2TA06187B

Electrocatalysis enabled transformation of earth-abundant water, nitrogen and carbon dioxide for a sustainable future

Kaili Liu, Pengfei Cao, Wei Chen, Collins I. Ezeh, Zijian Chen, Yonglan Luo, Qian Liu, Haitao Zhao, Zhenhua Rui, Shuyan Gao, Zongyou Yin, Xuping Sun and Xuefeng Yu

Mater. Adv., 2022, 3, 1359
DOI: 10.1039/D1MA00814E

Photoelectrochemical reduction of N2 to NH3 under ambient conditions through hierarchical MoSe2@g-C3N4 heterojunctions

Muhammad Asim Mushtaq, Muhammad Arif, Xiaoyu Fang, Ghulam Yasin, Wen Ye, Majid Basharat, Bo Zhou, Shiyu Yang, Shengfu Ji and Dongpeng Yan

J. Mater. Chem. A, 2021, 9, 2742
DOI: 10.1039/D0TA10620H

Strategies to suppress hydrogen evolution for highly selective electrocatalytic nitrogen reduction: challenges and perspectives

Yongwen Ren, Chang Yu, Xinyi Tan, Hongling Huang, Qianbing Wei and Jieshan Qiu

Energy Environ. Sci., 2021, 14, 1176
DOI: 10.1039/D0EE03596C

Electron coupled FeS2/MoS2 heterostructure for efficient electrocatalytic ammonia synthesis under ambient conditions

Bo Wang, Chao Yan, Guangqing Xu, Xia Shu, Jun Lv, Jiewu Cui, Dongbo Yu, Zhiyong Bao and Yucheng Wu

Dalton Trans., 2022, 51, 9720
DOI: 10.1039/D2DT01467J

Efficient ambient ammonia synthesis by Lewis acid pair over cobalt single atom catalyst with suppressed proton reduction

Ngoc Quang Tran, Xinghui Liu, Yunhee Cho, Le Thai Duy, Lirong Zheng, Jianmin Yu, Sara Ajmal, Xiaodong Shao, Jinsun Lee and Hyoyoung Lee

J. Mater. Chem. A, 2022, 10, 8432
DOI: 10.1039/D2TA00308B

Current density in solar fuel technologies

Valentino Romano, Giovanna D’Angelo, Siglinda Perathoner and Gabriele Centi

Energy Environ. Sci., 2021, 14, 5760
DOI: 10.1039/D1EE02512K

Ambient dinitrogen electrocatalytic reduction for ammonia synthesis

Aling Chen and Bao Yu Xia

J. Mater. Chem. A, 2019, 7, 23416
DOI: 10.1039/C9TA05505C

Electrochemically shape-controlled synthesis of great stellated dodecahedral Au nanocrystals with high-index facets for nitrogen reduction to ammonia

Yu-Chen Jiang, Yu-Jie Mao, Jin Zou, Hong-Hui Wang, Feng Liu, Yong-Sheng Wei, Tian Sheng, Xin-Sheng Zhao and Lu Wei

Chem. Commun., 2020, 56, 12162
DOI: 10.1039/D0CC04326E

Operando scanning electrochemical microscopic investigation and visualization of NRR-HER competition in electrochemical NH3 synthesis

Divyani Gupta, Alankar Kafle, Man Singh, Devyani Dahare and Tharamani C. Nagaiah

J. Mater. Chem. A, 2023, 11, 24812
DOI: 10.1039/D3TA04976K

Self-powered NH3 synthesis by trifunctional Co2B-based high power density Zn–air batteries

Divyani Gupta, Alankar Kafle, Prajna Parimita Mohanty, Tisita Das, Sudip Chakraborty, Rajeev Ahuja and Tharamani C. Nagaiah

J. Mater. Chem. A, 2023, 11, 12223
DOI: 10.1039/D3TA02178E

Elongated heterometal double-sites promote nitrogen reduction on two-dimensional MM′B7 monolayers

Changyan Zhu, Chaoxia Wen, Cong Wang, Min Zhang, Yun Geng and Zhongmin Su

J. Mater. Chem. A, 2021, 9, 10855
DOI: 10.1039/D1TA01796A

Metal–organic frameworks as promising electrocatalysts for the nitrogen reduction reaction: mapping the research landscape and identifying future trends

Riki Nakatani, Saikat Das and Yuichi Negishi

J. Mater. Chem. A, 2024, 12, 26350
DOI: 10.1039/D4TA04817B

Carbon dioxide and nitrogen reduction reactions using 2D transition metal dichalcogenide (TMDC) and carbide/nitride (MXene) catalysts

Zhaodong Li, Nuwan H. Attanayake, Jeffrey L. Blackburn and Elisa M. Miller

Energy Environ. Sci., 2021, 14, 6242
DOI: 10.1039/D1EE03211A

Ultrafine Co6W6C as an efficient anode catalyst for direct hydrazine fuel cells

Mengrui Zhang, Jianping Zhu, Bin Liu, Yongkang Hou, Chao Zhang, Jingping Wang and Jingyang Niu

Chem. Commun., 2021, 57, 10415
DOI: 10.1039/D1CC03446D

Sb2S3 nanoparticles anchored on SnO2 nanofibers: a high-performance hybrid electrocatalyst toward ammonia synthesis under ambient conditions

Di Li Di Li, Xingxing Chen, Yi-Tao Liu, Jianyong Yu and Bin Ding

Chem. Commun., 2019, 55, 13892
DOI: 10.1039/C9CC07847A

Enhancing electrocatalytic nitrogen reduction to ammonia with rare earths (La, Y, and Sc) on high-index faceted platinum alloy concave nanocubes

Yu-Jie Mao, Feng Liu, You-Hu Chen, Xin Jiang, Xin-Sheng Zhao, Tian Sheng, Jin-Yu Ye, Hong-Gang Liao, Lu Wei and Shi-Gang Sun

J. Mater. Chem. A, 2021, 9, 26277
DOI: 10.1039/D1TA05515A

Electrocatalytic reduction of nitrogen to ammonia under ambient conditions using a nanorod-structured MoN catalyst

Guoqiang Liu, Cuijiao Zhao and Shimin Ding

New J. Chem., 2020, 44, 21070
DOI: 10.1039/D0NJ04244G

Selective electroreduction of dinitrogen to ammonia on a molecular iron phthalocyanine/O-MWCNT catalyst under ambient conditions

Fanfan Xu, Linlin Zhang, Xin Ding, Meiyu Cong, Yu Jin, Lin Chen and Yan Gao

Chem. Commun., 2019, 55, 14111
DOI: 10.1039/C9CC06574A

Renaissance of elemental phosphorus materials: properties, synthesis, and applications in sustainable energy and environment

Haijiang Tian, Jiahong Wang, Gengchang Lai, Yanpeng Dou, Jie Gao, Zunbin Duan, Xiaoxiao Feng, Qi Wu, Xingchen He, Linlin Yao, Li Zeng, Yanna Liu, Xiaoxi Yang, Jing Zhao, Shulin Zhuang, Jianbo Shi, Guangbo Qu, Xue-Feng Yu, Paul K. Chu and Guibin Jiang

Chem. Soc. Rev., 2023, 52, 5388
DOI: 10.1039/D2CS01018F

Defect-tailored ZnO nanoflowers enable efficient, metal-free ammonia synthesis through coupled piezoelectric and photocatalytic activation

Jyh-Xuan Wang, Hsun-Yen Lin, Kuang Yuan Tu and Jyh-Ming Wu

J. Mater. Chem. A, 2026, 14, 10633
DOI: 10.1039/D5TA08002A

Selective nitrogen reduction to ammonia on iron porphyrin-based single-site metal–organic frameworks

Meiyu Cong, Xuyang Chen, Kai Xia, Xin Ding, Linlin Zhang, Yu Jin, Yan Gao and Lixue Zhang

J. Mater. Chem. A, 2021, 9, 4673
DOI: 10.1039/D0TA08741F

Influence of CeO2 support morphology on the structural and NO2−RR performance of CeO2@Au catalyst

Jin Li, Wei Zhang, Xiujing Xing, Yaokang Lv, Renliang Lyu, Wei Xiong and Hao Li

Mater. Chem. Front., 2025, 9, 223
DOI: 10.1039/D4QM00798K

Modulation strategies of Cu-based electrocatalysts for efficient nitrogen reduction

Hangyan Zhou, Bingyan Xiong, Lisong Chen and Jianlin Shi

J. Mater. Chem. A, 2020, 8, 20286
DOI: 10.1039/D0TA06776H

Nitrogen electroreduction performance of transition metal dimers embedded into N-doped graphene: a theoretical prediction

Hongyan Li, Zhifeng Zhao, Qinghai Cai, Lichang Yin and Jingxiang Zhao

J. Mater. Chem. A, 2020, 8, 4533
DOI: 10.1039/C9TA13599E

Multifunctional inorganic nanomaterials for energy applications

Huilin Wang, Xitong Liang, Jiutian Wang, Shengjian Jiao and Dongfeng Xue

Nanoscale, 2020, 12, 14
DOI: 10.1039/C9NR07008G

Frontier advances in synthesis strategies and catalytic performances of ZnO-supported single-atom catalysts

Kun Fu, Ping Rong, Liyun Jiang, Ping Wang and Qi Yu

Catal. Sci. Technol., 2025, 15, 4048
DOI: 10.1039/D5CY00254K

Electrocatalytic nitrogen reduction: mechanisms, system-level optimization, and future perspectives

Zichao Chen, Xueyao Meng, Guanze Su, Ning Wang, Li-Li Zhang, Hao Wan, Renzhi Ma, Wei Ma and Zhen Zhou

Nanoscale, 2025, 17, 16100
DOI: 10.1039/D5NR01582K

Chemically coupled NiCoS/C nanocages as efficient electrocatalysts for nitrogen reduction reactions

Xueke Wu, Zuochao Wang, Yi Han, Dan Zhang, Minghui Wang, Hongdong Li, Huan Zhao, Yue Pan, Jianping Lai and Lei Wang

J. Mater. Chem. A, 2020, 8, 543
DOI: 10.1039/C9TA10142J

Defect engineering of nanostructured electrocatalysts for enhancing nitrogen reduction

Xin Kong, Hui-Qing Peng, Shuyu Bu, Qili Gao, Tianpeng Jiao, Junye Cheng, Bin Liu, Guo Hong, Chun-Sing Lee and Wenjun Zhang

J. Mater. Chem. A, 2020, 8, 7457
DOI: 10.1039/D0TA01453B

Carbon-based metal-free electrocatalysts: from oxygen reduction to multifunctional electrocatalysis

Chuangang Hu, Rajib Paul, Quanbin Dai and Liming Dai

Chem. Soc. Rev., 2021, 50, 11785
DOI: 10.1039/D1CS00219H

Interface engineering in transition metal carbides for electrocatalytic hydrogen generation and nitrogen fixation

Min Kuang, Wenjing Huang, Chidanand Hegde, Wei Fang, Xianyi Tan, Chuntai Liu, Jianming Ma and Qingyu Yan

Mater. Horiz., 2020, 7, 32
DOI: 10.1039/C9MH01094G

Dealloying layered PdBi2 nanoflakes to palladium hydride leads to enhanced electrocatalytic N2 reduction

Nikolas Antonatos, Joshua D. Elliott, Vlastimil Mazánek, Petr Marvan, Paola Carbone, Weixiang Geng, Yu Jing and Zdeněk Sofer

J. Mater. Chem. A, 2022, 10, 11904
DOI: 10.1039/D1TA07395H

Multi-yolk–shell bismuth@porous carbon as a highly efficient electrocatalyst for artificial N2fixation under ambient conditions

Yu Qiu, Sen Zhao, Mingxin Qin, Jinxiang Diao, Shuangquan Liu, Lanxin Dai, Wenhua Zhang and Xiaohui Guo

Inorg. Chem. Front., 2020, 7, 2006
DOI: 10.1039/D0QI00153H

Recent advances in electrocatalytic NOx reduction into ammonia

Harish Reddy Inta, Dinesh Dhanabal, Sridhar Sethuram Markandaraj and Sangaraju Shanmugam

EES Catal., 2023, 1, 645
DOI: 10.1039/D3EY00090G

Mixture screening strategy of efficient transition metal heteronuclear dual-atom electrocatalysts toward nitrogen fixation

Zhouhao Zhu, Mengshan Chen, Mingyuzhi Sun, Jinhu Wang, Yingtang Zhou, Xibao Li and Hengcong Tao

Phys. Chem. Chem. Phys., 2022, 24, 26776
DOI: 10.1039/D2CP04302E

Highly efficient electrochemical ammonia synthesis using superhydrophobic nanoporous silver

Yating Qi, Ming Yang, Tian-En Zhao, Guorui Tang, Hongming He, Hongming Sun, Yijie Yang and Cheng-Peng Li

Inorg. Chem. Front., 2023, 10, 2978
DOI: 10.1039/D3QI00315A

Cyanogel auto-reduction induced synthesis of PdCo nanocubes on carbon nanobowls: a highly active electrocatalyst for ethanol electrooxidation

Guang-Rui Xu, Ya-Nan Zhai, Fu-min Li, Guang-Tao Zhao, Shu-Ni Li, Hong-Chang Yao, Jia-Xing Jiang and Yu Chen

Nanoscale, 2019, 11, 13477
DOI: 10.1039/C9NR04767K

Surface oxidized two-dimensional antimonene nanosheets for electrochemical ammonia synthesis under ambient conditions

Munkhjargal Bat-Erdene, Guangrui Xu, Munkhbayar Batmunkh, Abdulaziz S. R. Bati, Jessica J. White, Md J. Nine, Dusan Losic, Yu Chen, Yun Wang, Tianyi Ma and Joseph G. Shapter

J. Mater. Chem. A, 2020, 8, 4735
DOI: 10.1039/C9TA13485A

Efficient modulation of the catalytic performance of electrocatalytic nitrogen reduction with transition metals anchored on N/O-codoped graphene by coordination engineering

Xiaolin Wang and Li-Ming Yang

J. Mater. Chem. A, 2022, 10, 1481
DOI: 10.1039/D1TA08877G

Highly boosted gas diffusion for enhanced electrocatalytic reduction of N2to NH3on 3D hollow Co–MoS2nanostructures

Libin Zeng, Xinyong Li, Shuai Chen, Jiali Wen, Farnood Rahmati, Joshua van der Zalm and Aicheng Chen

Nanoscale, 2020, 12, 6029
DOI: 10.1039/C9NR09624H

Two dimensional electrocatalyst engineering via heteroatom doping for electrocatalytic nitrogen reduction

Yuanyuan Yang, Ruguang Wang, Liujing Yang, Yan Jiao and Tao Ling

Chem. Commun., 2020, 56, 14154
DOI: 10.1039/D0CC05635A

Unlocking the potential of ruthenium catalysts for nitrogen fixation with subsurface oxygen

Xin Mao, Zhengxiang Gu, Cheng Yan and Aijun Du

J. Mater. Chem. A, 2021, 9, 6575
DOI: 10.1039/D0TA11621A

Bimetal–MOF nanosheets as efficient bifunctional electrocatalysts for oxygen evolution and nitrogen reduction reaction

Weixin Li, Wei Fang, Chen Wu, Khang Ngoc Dinh, Hao Ren, Lei Zhao, Chuntai Liu and Qingyu Yan

J. Mater. Chem. A, 2020, 8, 3658
DOI: 10.1039/C9TA13473E

Electrosynthesis of NH3 from N2 using nanostructured Bi4Ti3O12 catalyst

Meera Sebastian, Subrata Das and Nishanth Karimbintherikkal Gopalan

Sustainable Energy Fuels, 2024, 8, 4838
DOI: 10.1039/D4SE01040J

An electrocatalyst prepared via a metal–polyphenol assembly strategy for efficient nitrate reduction

Jing Jiang, Xiaoli Jiang, Lin Zhao and Yagang Zhang

Dalton Trans., 2026, 55, 4700
DOI: 10.1039/D6DT00202A

Ruthenium(iii) polyethyleneimine complexes for bifunctional ammonia production and biomass upgrading

Guang-Rui Xu, Munkhbayar Batmunkh, Scott Donne, Hongni Jin, Jia-Xing Jiang, Yu Chen and Tianyi Ma

J. Mater. Chem. A, 2019, 7, 25433
DOI: 10.1039/C9TA10267A

Computational screening of MBene monolayers with high electrocatalytic activity for the nitrogen reduction reaction

Yameng Li, Lei Li, Rao Huang and Yuhua Wen

Nanoscale, 2021, 13, 15002
DOI: 10.1039/D1NR04652G

High-loading metal atoms on graphdiyne for efficient nitrogen fixation to ammonia

Yan Fang, Yurui Xue, Lan Hui, Xi Chen and Yuliang Li

J. Mater. Chem. A, 2022, 10, 6073
DOI: 10.1039/D1TA08241H

Recent advances on electrocatalytic fixation of nitrogen under ambient conditions

Bin Wu, Yichao Lin, Xuezhen Wang and Liang Chen

Mater. Chem. Front., 2021, 5, 5516
DOI: 10.1039/D1QM00269D

Isolated diatomic Zn–Fe in N-doped carbon for electrocatalytic nitrogen reduction to ammonia

Le Zhang, Guilan Fan, Wence Xu, Meng Yu, Lei Wang, Zhenhua Yan and Fangyi Cheng

Chem. Commun., 2020, 56, 11957
DOI: 10.1039/D0CC04843G

A new strategy for engineering a hierarchical porous carbon-anchored Fe single-atom electrocatalyst and the insights into its bifunctional catalysis for flexible rechargeable Zn–air batteries

Cheng Du, Yijing Gao, Jianguo Wang and Wei Chen

J. Mater. Chem. A, 2020, 8, 9981
DOI: 10.1039/D0TA03457F

Boosting the acidic electrocatalytic nitrogen reduction performance of MoS2 by strain engineering

Jiawei Liang, Shuangxiu Ma, Jing Li, Yangang Wang, Junli Wu, Quan Zhang, Zhao Liu, Zehui Yang, Konggang Qu and Weiwei Cai

J. Mater. Chem. A, 2020, 8, 10426
DOI: 10.1039/D0TA03622F

Defective Mo2C as a promising electrocatalyst for the nitrogen reduction reaction

Xuanyue Zhang, Tingting Zhao, Likai Yan and Zhongmin Su

Phys. Chem. Chem. Phys., 2023, 25, 12371
DOI: 10.1039/D3CP00277B

High-performance N2-to-NH3 fixation by a metal-free electrocatalyst

Jinxiu Zhao, Xiang Ren, Xianghong Li, Dawei Fan, Xu Sun, Hongmin Ma, Qin Wei and Dan Wu

Nanoscale, 2019, 11, 4231
DOI: 10.1039/C8NR10401H

Multi-layer core–shell metal oxide/nitride/carbon and its high-rate electroreduction of nitrate to ammonia

Xiaoyu Li, Ping Deng, Mengqiu Xu, Zhenbo Peng, Yuhu Zhou, Gan Jia, Wei Ye, Peng Gao and Wei Wang

Nanoscale, 2023, 15, 14439
DOI: 10.1039/D3NR02972G

In silico design of novel NRR electrocatalysts: cobalt–molybdenum alloys

Blanca Castellano-Varona, Moussab Harb, Javier Araña, Luigi Cavallo and Luis Miguel Azofra

Chem. Commun., 2020, 56, 13343
DOI: 10.1039/D0CC05921H

Polyoxometalate-based metal–organic framework-derived bimetallic hybrid materials for upgraded electrochemical reduction of nitrogen

Xinming Wang, Zemin Feng, Boxin Xiao, Jingxiang Zhao, Huiyuan Ma, Yu Tian, Haijun Pang and Lichao Tan

Green Chem., 2020, 22, 6157
DOI: 10.1039/D0GC01149E

Silver nanomaterials: synthesis and (electro/photo) catalytic applications

Rakesh Kumar Sharma, Sneha Yadav, Sriparna Dutta, Hanumant B. Kale, Indrajeet R. Warkad, Radek Zbořil, Rajender S. Varma and Manoj B. Gawande

Chem. Soc. Rev., 2021, 50, 11293
DOI: 10.1039/D0CS00912A

MBenes: emerging 2D materials as efficient electrocatalysts for the nitrogen reduction reaction

Xiaowei Yang, Chanjuan Shang, Si Zhou and Jijun Zhao

Nanoscale Horiz., 2020, 5, 1106
DOI: 10.1039/D0NH00242A

Self-organized growth of flower-like SnS2 and forest-like ZnS nanoarrays on nickel foam for synergistic superiority in electrochemical ammonia synthesis

Xingxing Chen, Yi-Tao Liu, Chunlan Ma, Jianyong Yu and Bin Ding

J. Mater. Chem. A, 2019, 7, 22235
DOI: 10.1039/C9TA04382A

Emerging two-dimensional nanomaterials for electrochemical nitrogen reduction

Yingping Pang, Chao Su, Guohua Jia, Liqiang Xu and Zongping Shao

Chem. Soc. Rev., 2021, 50, 12744
DOI: 10.1039/D1CS00120E

Dopant-site lattice turbulence of Cu-substituted Nb2O5 for efficient nitrogen electroreduction

Jia Wang, Guangkai Li, Tao Wei, Shizheng Zhou, Xuqiang Ji and Xien Liu

Nanoscale, 2021, 13, 3036
DOI: 10.1039/D0NR07885A

Boosting electrocatalytic nitrogen fixation via energy-efficient anodic oxidation of sodium gluconate

Lu Zhao, Xuan Kuang, Cheng Chen, Xu Sun, Zhiling Wang and Qin Wei

Chem. Commun., 2019, 55, 10170
DOI: 10.1039/C9CC04378K

Electrochemical nitration for organic C–N bond formation: a current view on possible N-sources, mechanisms, and technological feasibility

Nils Kurig and Regina Palkovits

Green Chem., 2023, 25, 7508
DOI: 10.1039/D3GC02084C

Nitrogen reduction reaction under ambient conditions by K3Ti8O17 nanorod electrocatalyst

Meera Sebastian, Subrata Das and Nishanth Karimbintherikkal Gopalan

Sustainable Energy Fuels, 2022, 6, 1519
DOI: 10.1039/D1SE01932E

Recent advances in structural engineering of MXene electrocatalysts

Hao Wang and Jong-Min Lee

J. Mater. Chem. A, 2020, 8, 10604
DOI: 10.1039/D0TA03271A

Electrocatalysis in confined spaces: interplay between well-defined materials and the microenvironment

Xue Han, Qiang Gao, Zihao Yan, Mengxia Ji, Christopher Long and Huiyuan Zhu

Nanoscale, 2021, 13, 1515
DOI: 10.1039/D0NR08237F

Heterojunction-based photocatalytic nitrogen fixation: principles and current progress

Hassan Ali, Milan Masar, Ali Can Guler, Michal Urbanek, Michal Machovsky and Ivo Kuritka

Nanoscale Adv., 2021, 3, 6358
DOI: 10.1039/D1NA00565K

Photocatalytic nitrogen fixation: the role of defects in photocatalysts

Ming Cheng, Chong Xiao and Yi Xie

J. Mater. Chem. A, 2019, 7, 19616
DOI: 10.1039/C9TA06435D

Enhanced N2affinity of 1T-MoS2with a unique pseudo-six-membered ring consisting of N–Li–S–Mo–S–Mo for high ambient ammonia electrosynthesis performance

Shivaraj B. Patil, Hung-Lung Chou, Yu-Mei Chen, Shang-Hsien Hsieh, Chia-Hao Chen, Chia-Che Chang, Shin-Ren Li, Yi-Cheng Lee, Ying-Sheng Lin, Hsin Li, Yuan Jay Chang, Ying-Huang Lai and Di-Yan Wang

J. Mater. Chem. A, 2021, 9, 1230
DOI: 10.1039/D0TA10696H

Nonmetal-doping of noble metal-based catalysts for electrocatalysis

Zhao Li, Xinhua Lu, Jingrui Teng, Yingmei Zhou and Wenchang Zhuang

Nanoscale, 2021, 13, 11314
DOI: 10.1039/D1NR02019F

Tailoring hydrophilic and hydrophobic microenvironments for gas–liquid–solid triphase electrochemical reactions

Jungki Ryu and Dong Woog Lee

J. Mater. Chem. A, 2024, 12, 10012
DOI: 10.1039/D4TA00453A

Recent progress in the development of electrocatalysts for the electrochemical N2reduction reaction

Kousik Bhunia, Sanjeev Kumar Sharma, Biraj Kanta Satpathy and Debabrata Pradhan

Mater. Adv., 2022, 3, 888
DOI: 10.1039/D1MA00680K

Emerging techniques and scenarios of scanning electrochemical microscopy for the characterization of electrocatalytic reactions

Jinming Xu, Ran Chen, Juanxian Song, Songqin Liu, Yanfei Shen and Yuanjian Zhang

Chem. Sci., 2025, 16, 9564
DOI: 10.1039/D5SC01854D

Bimetallic metal–organic framework-derived MoFe-PC microspheres for electrocatalytic ammonia synthesis under ambient conditions

Silong Chen, Haeseong Jang, Jia Wang, Qing Qin, Xien Liu and Jaephil Cho

J. Mater. Chem. A, 2020, 8, 2099
DOI: 10.1039/C9TA10524G

Electrochemical ammonia synthesis under ambient conditions using TM-embedded porphine-fused sheets as single-atom catalysts

Ying Yao, Sheng-Yao Lv, Guoliang Li and Li-Ming Yang

Phys. Chem. Chem. Phys., 2023, 25, 27131
DOI: 10.1039/D3CP03073C

Modulating catalyst surface wettability to boost electrochemical ammonia synthesis under ambient conditions

Nilam Qureshi, Krishnan Ravi and Jun Ho Shim

J. Mater. Chem. A, 2026, 14, 1468
DOI: 10.1039/D5TA06140G

A Mo–salicylaldehyde-linker (Mo–Tp) based 2D MOF as a single-atom catalyst for the nitrogen reduction reaction

Hassan A. Alhadidi Almheiri, Nirpendra Singh, Dinesh Shetty, Kyriaki Polychronopoulou and Ali A. Alhammadi

J. Mater. Chem. A, 2024, 12, 7058
DOI: 10.1039/D3TA06666E

Regulating spin states of single transition metal atoms on N-doped graphene for efficient ammonia synthesis

Wei Li, Jing Zhang, Xinxin Duan and Ding Yi

J. Mater. Chem. A, 2025, 13, 11760
DOI: 10.1039/D4TA09260K

A tuned Lewis acidic catalyst guided by hard–soft acid–base theory to promote N2 electroreduction

Yongwen Ren, Chang Yu, Xuedan Song, Fengyi Zhou, Xinyi Tan, Yiwang Ding, Qianbing Wei, Jiafu Hong and Jieshan Qiu

J. Mater. Chem. A, 2021, 9, 13036
DOI: 10.1039/D1TA02681J

Synergistically enhanced single-atomic site catalysts for clean energy conversion

Fa Yang and Weilin Xu

J. Mater. Chem. A, 2022, 10, 5673
DOI: 10.1039/D1TA08561A

Enhanced electrocatalytic activity of Cu-modified, high-index single Pt NPs for formic acid oxidation

Ke Huang and Richard M. Crooks

Chem. Sci., 2022, 13, 12479
DOI: 10.1039/D2SC03433F

Ceria-reduced graphene oxide nanocomposite as an efficient electrocatalyst towards artificial N2 conversion to NH3 under ambient conditions

Hongtao Xie, Qin Geng, Xin Li, Ting Wang, Yonglan Luo, Abdulmohsen Ali Alshehri, Khalid Ahmad Alzahrani, Baihai Li, Zhiming Wang and Jian Mao

Chem. Commun., 2019, 55, 10717
DOI: 10.1039/C9CC05309C

Roads less traveled: Nitrogen reduction reaction catalyst design strategies for improved selectivity

Bianca M. Ceballos, Ghanshyam Pilania, Kannan P. Ramaiyan, Amitava Banerjee, Cortney Kreller and Rangachary Mukundan

Current Opinion in Electrochemistry, 2021, 28, 100723
DOI: 10.1016/j.coelec.2021.100723

Oxidation State Modulation of Bismuth for Efficient Electrocatalytic Nitrogen Reduction to Ammonia

Yuchi Wan, Hongjiang Zhou, Muyun Zheng, Zheng‐Hong Huang, Feiyu Kang, Jia Li and Ruitao Lv

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202100300

Harnessing bimetallic electrocatalysts for efficient nitrogen molecule reduction in advancing energy solution

Seyyed Mojtaba Mousavi, Masoomeh Yari Kalashgrani, Jui-Yang Lai, Chin Wei Lai, Ming-Kang Tsai and Wei-Hung Chiang

Journal of Environmental Chemical Engineering, 2026, 14, 122067
DOI: 10.1016/j.jece.2026.122067

Two‐Dimensional MXene‐Based Electrocatalysts: Challenges and Opportunities

Muhammad Kaleem Shabbir, Fozia Arif, Haleema Asghar, Sanam Irum Memon, Urooj Khanum, Javeed Akhtar, Akbar Ali, Zeeshan Ramzan, Aliya Aziz, Ayaz Ali Memon and Khalid Hussain Thebo

The Chemical Record, 2024, 24
DOI: 10.1002/tcr.202400047

Recent progress in electrocatalytic nitrogen reduction to ammonia (NRR)

Zanling Huang, Madiha Rafiq, Abebe Reda Woldu, Qing-Xiao Tong, Didier Astruc and Liangsheng Hu

Coordination Chemistry Reviews, 2023, 478, 214981
DOI: 10.1016/j.ccr.2022.214981

Novel design of single transition metal atoms anchored on C6N6 nanosheet for electrochemical and photochemical N2 reduction to Ammonia

Supriti Dutta and Swapan K. Pati

Catalysis Today, 2023, 424, 113804
DOI: 10.1016/j.cattod.2022.06.019

Synergistic tuning of crystal symmetry and eg electrons in LnFeO3 perovskites for efficient nitrate-to-ammonia conversion

Jiaqi Zhao, Dianxue Cao, Jiaxin Yao, Kai Zhu and Hui Zhao

Journal of Alloys and Compounds, 2025, 1045, 184791
DOI: 10.1016/j.jallcom.2025.184791

One-step synthesis of self-standing porous palladium-ruthenium nanosheet array on Ni foam for ambient electrosynthesis of ammonia

Yinghao Li, Hongjie Yu, Ziqiang Wang, Songliang Liu, You Xu, Xiaonian Li, Liang Wang and Hongjing Wang

International Journal of Hydrogen Energy, 2020, 45, 5997
DOI: 10.1016/j.ijhydene.2019.12.098

Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Dimitrij Ješić, Brett Pomeroy, Khaja Mohaideen Kamal, Žan Kovačič, Matej Huš and Blaž Likozar

Adv Energy and Sustain Res, 2024, 5
DOI: 10.1002/aesr.202400083

Modification of black phosphorus with metal substrates: towards single-atom catalysts

A. M. Kuchkaev, V. S. Kashansky, A. M. Kuchkaev, A. V. Sukhov, X. Kang, O. G. Sinyashin and D. G. Yakhvarov

RUSS CHEM REV, 2025, 94, RCR5204
DOI: 10.59761/RCR5204

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Shivaraj B. Patil and Di‐Yan Wang

Small, 2020, 16
DOI: 10.1002/smll.202002885

Effect of nickel oxide morphology on the nitrogen electrochemical reduction reaction

Ping Zhang, Wei Xiong and Min Zhou

Nano Materials Science, 2020, 2, 353
DOI: 10.1016/j.nanoms.2020.03.002

Electrochemical Exfoliation of Janus-like BiTeI Nanosheets for Electrocatalytic Nitrogen Reduction

Nikolas Antonatos, Evgeniya Kovalska, Vlastimil Mazánek, Martin Veselý, David Sedmidubský, Bing Wu and Zdeněk Sofer

ACS Appl. Nano Mater., 2021, 4, 590
DOI: 10.1021/acsanm.0c02860

Computational design of two-dimensional transition metal supported biphenylene as efficient electrocatalysts toward nitrogen reduction reaction

Dinesh Kumar Dhanthala Chittibabu and Hsin-Tsung Chen

Electrochimica Acta, 2024, 497, 144578
DOI: 10.1016/j.electacta.2024.144578

Electrochemical nitrogen fixation in metal-N2 batteries: A paradigm for simultaneous NH3 synthesis and energy generation

Jahidul Islam, Mahmud Shareef, Hossain M. Zabed, Xianghui Qi, Faisal Islam Chowdhury, Jagotamoy Das, Jamal Uddin, Yusuf Valentino Kaneti, Mayeen Uddin Khandaker, Md. Habib Ullah and Mostafa Kamal Masud

Energy Storage Materials, 2023, 54, 98
DOI: 10.1016/j.ensm.2022.10.007

Microstructure regulation of carbon nitrides for electrochemical nitrogen fixation

Xiaoyu Li, Yutong Yang, Bin Yue, Jianhua Lin, Quanli Hu, Peihe Li, Yushuang Liu, Limei Duan, Quan Zhuang, Yin Wang and Jinghai Liu

Electrochimica Acta, 2023, 466, 143056
DOI: 10.1016/j.electacta.2023.143056

Application of transition metal doped M-W18O49 in catalysis

Duojia REN, Wenxia SHI, Huixiang WANG, Jianghong WU, Wenting LÜ, Ping WANG and Baoliang LÜ

Journal of Fuel Chemistry and Technology, 2025, 53, 1444
DOI: 10.1016/S1872-5813(25)60550-0

Oxygen-vacancy-mediated photocatalytic activity of antimony molybdenum oxide toward green ammonia synthesis

Botong Liu, Ling Huang, Terence Musho, Chih-Jung Chen, Chung-Li Dong, Chaoyun Tang, Alhassan Yasin, Yulei Wang, Hui Yang, Joeseph Bright, Peng Zheng, Ru-Shi Liu and Nianqiang Wu

Chem Catalysis, 2025, 5, 101337
DOI: 10.1016/j.checat.2025.101337

Two-Dimensional Layered SnO2 Nanosheets for Ambient Ammonia Synthesis

Guangzhe Li, Yaoguang Yu, Zhefei Pan and Liang An

ACS Appl. Energy Mater., 2020, 3, 6735
DOI: 10.1021/acsaem.0c00858

Are Catalyst Impurities Being Overlooked in Electrochemical Nitrogen Reduction to Ammonia?

Jinchao Wang, Árni Björn Höskuldsson, Ása Hanifpour, Helga Dögg Flosadóttir and Egill Skúlason

ACS Energy Lett., 2026, 11, 2365
DOI: 10.1021/acsenergylett.5c03955

Boron doping and high curvature in Bi nanorolls for promoting photoelectrochemical nitrogen fixation

Fuchun Xu, Fangfang Wu, Kaili Zhu, Zeping Fang, Dongmei Jia, Yikang Wang, Gan Jia, Jingxiang Low, Wei Ye, Zhongti Sun, Peng Gao and Yujie Xiong

Applied Catalysis B: Environmental, 2021, 284, 119689
DOI: 10.1016/j.apcatb.2020.119689

Overview of emerging catalytic materials for electrochemical green ammonia synthesis and process

Venkata Thulasivarma Chebrolu, Daehee Jang, Gokana Mohana Rani, Chaeeun Lim, Kijung Yong and Won Bae Kim

Carbon Energy, 2023, 5
DOI: 10.1002/cey2.361

Recent Advances on Transition‐Metal‐Based Layered Double Hydroxides Nanosheets for Electrocatalytic Energy Conversion

Yuchen Wang, Man Zhang, Yaoyu Liu, Zhikeng Zheng, Biying Liu, Meng Chen, Guoqing Guan and Kai Yan

Advanced Science, 2023, 10
DOI: 10.1002/advs.202207519

Controllable Electrocatalytic to Photocatalytic Conversion in Ferroelectric Heterostructures

Lin Ju, Yandong Ma, Xin Tan and Liangzhi Kou

J. Am. Chem. Soc., 2023, 145, 26393
DOI: 10.1021/jacs.3c10271

Influence of lanthanum on morphology and electrochemical performance of nano‐platinum‐based catalytic membrane electrode

Yanwei Liu, Yanting Zhao, Yan Li and Bin Yang

Surface & Interface Analysis, 2019, 51, 1033
DOI: 10.1002/sia.6689

Robust Active Site Design of Single-Atom Catalysts for Electrochemical Ammonia Synthesis

Lance Kavalsky and Venkatasubramanian Viswanathan

J. Phys. Chem. C, 2020, 124, 23164
DOI: 10.1021/acs.jpcc.0c06692

Progress in electrolyte regulation to enhance nitrogen reduction reaction

Qin Li, Xuguang Liu and Meiling Wang

Chemical Engineering Journal, 2024, 496, 154217
DOI: 10.1016/j.cej.2024.154217

Computational Study of Double Transition Metal Atom Anchored on Graphdiyne Monolayer for Nitrogen Electroreduction

Li‐Gang Hu, Hong‐Juan Wang and Yaqiong Su

ChemPhysChem, 2022, 23
DOI: 10.1002/cphc.202200149

A photoelectrochemical cell with Z-scheme CdS/self-doped TiO2 nanotube arrays heterojunction photoanode for enhanced ammonia synthesis

Jianglin Tu, Dingman Zhang, Zhefei Pan, Liang An and Rong Chen

Electrochimica Acta, 2025, 544, 147709
DOI: 10.1016/j.electacta.2025.147709

Scalable fabrication of Janus WSSe/WS₂ heterostructures as ultrasensitive detection platform for electrochemical ammonia products by surface-enhanced raman spectroscopy (SERS)

Yu-Ren Peng, Tianyi Zhang, Tilo H. Yang, Shin-Yi Tang, Shih-Ming He, Pei-Husan Wang, Tzi-Yi Yang, Hung-Ti Chen, Shih-Syuan Huang, Yuan-Chun Chen, Hao-Chung Kuo, Jing Kong and Yu-Lun Chueh

Chemical Engineering Journal, 2025, 522, 166830
DOI: 10.1016/j.cej.2025.166830

TM3 (TM = V, Fe, Mo, W) single-cluster catalyst confined on porous BN for electrocatalytic nitrogen reduction

Shuaishuai Gao, Zuju Ma, Chengwei Xiao, Zhitao Cui, Wei Du, Xueqin Sun, Qiaohong Li, Rongjian Sa and Chenghua Sun

Journal of Materials Science & Technology, 2022, 108, 46
DOI: 10.1016/j.jmst.2021.08.052

Controlled-potential electrolysis for evaluating molecular electrocatalysts

Sriram Katipamula, Navar M. White and Kate M. Waldie

Chem Catalysis, 2023, 3, 100561
DOI: 10.1016/j.checat.2023.100561

Feasibility of N2 Reduction on the V Anchored 1T−MoS2 Monolayer: A Density Functional Theory Study

Lei Yang, Fengxiang Chen, Erhong Song, Zhifei Yuan and Beibei Xiao

ChemPhysChem, 2020, 21, 1235
DOI: 10.1002/cphc.202000147

Engineered wettability-gradient porous structure enabling efficient water manipulation in regenerative fuel cells

Zhefei Pan, Lizhen Wu, Fengjia Xie, Zhewei Zhang, Zhen Zhao, Oladapo Christopher Esan, Xuming Zhang, Rong Chen and Liang An

Energy and AI, 2024, 17, 100400
DOI: 10.1016/j.egyai.2024.100400

Synthesis and Characterization of a Highly Electroactive Composite Based on Au Nanoparticles Supported on Nanoporous Activated Carbon for Electrocatalysis

Giulia Moggia, Saskia Hoekx, Nick Daems, Sara Bals and Tom Breugelmans

ChemElectroChem, 2023, 10
DOI: 10.1002/celc.202300293

Greatly Enhanced Electrocatalytic Nitrogen Reduction by Efficient S-Doped Sb ₂O ₃ Nanorods: Significance of Sulfur Doping

Shihai Cao, Zhen Guan, Yanchao Feng, Huiya Wang, Rui Liu and Keqiang Ding

SSRN Journal, 2021
DOI: 10.2139/ssrn.3970635

Vacancy–engineered coordination cavities in graphene–supported TM–Nx single–atom catalysts for nitrogen reduction

Shuxin Kuai, Meiyan Wang and Jing–yao Liu

Electrochimica Acta, 2026, 547, 147885
DOI: 10.1016/j.electacta.2025.147885

Recent Advances in Electrochemical Synthesis of Ammonia through Nitrogen Reduction under Ambient Conditions

Jia Wang, Silong Chen, Zijian Li, Guangkai Li and Xien Liu

ChemElectroChem, 2020, 7, 1067
DOI: 10.1002/celc.201901967

Rational Design of Single-Atom Catalysts for Enhanced Electrocatalytic Nitrogen Reduction Reaction

Sakshi Agarwal, Ritesh Kumar, Rakesh Arya and Abhishek K. Singh

J. Phys. Chem. C, 2021, 125, 12585
DOI: 10.1021/acs.jpcc.1c00742

Modulation effect in adjacent dual metal single atom catalysts for electrochemical nitrogen reduction reaction

Xiaonan Zheng, Yang Liu, Yu Yan, Xiaoxiao Li and Yuan Yao

Chinese Chemical Letters, 2022, 33, 1455
DOI: 10.1016/j.cclet.2021.08.102

In Situ Fragmented Bismuth Nanoparticles for Electrocatalytic Nitrogen Reduction

Dazhi Yao, Cheng Tang, Laiquan Li, Bingquan Xia, Anthony Vasileff, Huanyu Jin, Yanzhao Zhang and Shi‐Zhang Qiao

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202001289

Nanostructured Fe-doped La_0.3Sr_0.7TiO₃_-δ/Ce_0.8Gd_0.18Ca_0.02O_2-δ nanocomposite for electrocatalytic ammonia synthesis from humid N₂

Ibrahim A. Amar and Abubaker A. Sharif

JNanoR, 2025, 90, 69
DOI: 10.4028/p-OAZQ3l

Review of recent research work on CeO2-based electrocatalysts in liquid-phase electrolytes

Guilong Lu, Haiyan Zheng, Junjun Lv, Ge Wang and Xiubing Huang

Journal of Power Sources, 2020, 480, 229091
DOI: 10.1016/j.jpowsour.2020.229091

Rational Design of Hydroxyl‐Rich Ti3C2Tx MXene Quantum Dots for High‐Performance Electrochemical N2 Reduction

Zhaoyong Jin, Chuangwei Liu, Zaichun Liu, Jingrui Han, Yanfeng Fang, Yaqian Han, Yusheng Niu, Yuping Wu, Chenghua Sun and Yuanhong Xu

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202000797

Recent Progress on Titanium Sesquioxide: Fabrication, Properties, and Applications

Yangyang Li, Yangyu Zhu, Mingzheng Wang, Mingwen Zhao, Junmin Xue, Jingsheng Chen, Tom Wu and Scott A. Chambers

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202203491

Dealloyed Air- and Water-Sensitive Nanoporous Metals and Metalloids for Emerging Energy Applications

Jintao Fu, Samuel S. Welborn and Eric Detsi

ACS Appl. Energy Mater., 2022, 5, 6516
DOI: 10.1021/acsaem.2c00405

Ambient Ammonia Electrosynthesis: Current Status, Challenges, and Perspectives

Xian‐Wei Lv, Chen‐Chen Weng and Zhong‐Yong Yuan

ChemSusChem, 2020, 13, 3061
DOI: 10.1002/cssc.202000670

Computational Screening of First-Row Transition-Metal Based Alloy Catalysts─Ligand Induced N2 Reduction Reaction Selectivity

Arunendu Das, Shyama Charan Mandal, Akhil S. Nair and Biswarup Pathak

ACS Phys. Chem Au, 2022, 2, 125
DOI: 10.1021/acsphyschemau.1c00021

Oxygen vacancies engineering in electrocatalysts nitrogen reduction reaction

Haijiang Zhu, Chao Wang, Yuling He, Yi Pu, Peiwen Li, Liang He, Xianglan Huang, Wu Tang and Hui Tang

Front. Chem., 2022, 10
DOI: 10.3389/fchem.2022.1039738

In Situ Derived Bi Nanoparticles Confined in Carbon Rods as an Efficient Electrocatalyst for Ambient N2 Reduction to NH3

Fengyi Wang, Longcheng Zhang, Ting Wang, Fang Zhang, Qian Liu, Haitao Zhao, Baozhan Zheng, Juan Du and Xuping Sun

Inorg. Chem., 2021, 60, 7584
DOI: 10.1021/acs.inorgchem.1c01130

Highly Efficient Photoelectrochemical Synthesis of Ammonia Using Plasmon-Enhanced Black Silicon under Ambient Conditions

Bo Wang, Li Yao, Guangqing Xu, Xinyi Zhang, Dongmei Wang, Xia Shu, Jun Lv and Yu-Cheng Wu

ACS Appl. Mater. Interfaces, 2020, 12, 20376
DOI: 10.1021/acsami.0c00881

Perspectives on electrochemical nitrogen fixation catalyzed by two-dimensional MXenes

Tiezhu Guo, Di Zhou and Chuanfang (John) Zhang

Materials Reports: Energy, 2022, 2, 100076
DOI: 10.1016/j.matre.2021.100076

Recent Progress in 2D Catalysts for Photocatalytic and Electrocatalytic Artificial Nitrogen Reduction to Ammonia

Guoqiang Zhang, Yongliang Li, Chuanxin He, Xiangzhong Ren, Peixin Zhang and Hongwei Mi

Advanced Energy Materials, 2021, 11
DOI: 10.1002/aenm.202003294

One-dimensional biomass-based carbon nanotubes loaded with MoS2 as catalysts for the electrocatalytic nitrogen reduction reaction

Shengyan Wang, Jiansheng Tian, Abulikemu Abulizi and Kenji Okitsu

Materials Science in Semiconductor Processing, 2024, 177, 108368
DOI: 10.1016/j.mssp.2024.108368

Single-atom catalysts boost nitrogen electroreduction reaction

Yanling Zhai, Zhijun Zhu, Chengzhou Zhu, Kyle Chen, Xueji Zhang, Jing Tang and Jun Chen

Materials Today, 2020, 38, 99
DOI: 10.1016/j.mattod.2020.03.022

Metal-free photocatalyst for nitrogen fixation under visible light based on COF/g-C3N4/ CNT nanocomposite

Hao Luo, Jiaxin Yan, Yiwei Shan, Jianwen Zhou, Jun Yu, Bruno Boury, Hui Wu, He Xiao, Liulian Huang, Zhanhui Yuan and Lihui Chen

Journal of Environmental Chemical Engineering, 2022, 10, 107713
DOI: 10.1016/j.jece.2022.107713

2D Metal Phosphorous Trichalcogenides (MPCh3) for Sustainable Energy Storage and Conversion: Nanoarchitectonics and Advanced Applications

Honglei Wang, Pengfei Cheng, Bing Wu, Yong Yan, Peter Schaaf, Zdenek Sofer and Dong Wang

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202407432

High‐Efficiency Electrochemical Nitrogen Fixation by Noble‐Metal‐Free Metallic Glasses

Xue Chen, Xin‐Jie Peng, Dong‐Dong Xiao, Yi‐Tao Sun, Kai‐Ling Zhou, Xiao‐Yong Yang, Yong‐Zheng Zhang, Wei‐Hua Wang, Zhen Lu and Hai‐Yang Bai

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202503400

MXenes and their derivatives as nitrogen reduction reaction catalysts: recent progress and perspectives

Tahta Amrillah, Angga Hermawan, Vani Novita Alviani, Zhi Wei Seh and Shu Yin

Materials Today Energy, 2021, 22, 100864
DOI: 10.1016/j.mtener.2021.100864

An emerging direct monolayer δ-AlP3: High stability, desirable carrier mobility, NO2-sensitive sensing performance, and superior catalytic properties toward the nitrogen reduction reaction

Qiang Zhang, Xian Wang, Fuchun Zhang and Jianyang Zhou

Applied Surface Science, 2022, 591, 153191
DOI: 10.1016/j.apsusc.2022.153191

Ultrathin MoS2 Nanosheets for Electrocatalytic N2-To-NH3 Fixation Under Ambient Conditions

Yanmei Liao, Weijun Ye, Yinghong Zhu and Lianbang Wang

International Journal of Electrochemical Science, 2020, 15, 11555
DOI: 10.20964/2020.11.71

Green ammonia could produce climate-friendly ways to store energy and fertilize farms

Stephen Ornes

Proc. Natl. Acad. Sci. U.S.A., 2021, 118
DOI: 10.1073/pnas.2119584118

Electrochemical N2 Reduction to Ammonia Using Single Au/Fe Atoms Supported on Nitrogen-Doped Porous Carbon

Sudhir K. Sahoo, Julian Heske, Markus Antonietti, Qing Qin, Martin Oschatz and Thomas D. Kühne

ACS Appl. Energy Mater., 2020, 3, 10061
DOI: 10.1021/acsaem.0c01740

Excited-State Hole-Transfer from CdSe Quantum Dots to a Self-Assembled Pd(II) Nanocage Functionalized with Ferrocenes

Austin B. Gilbert, Udani Wijethunga, Karoline E. García-Pedraza, David F. Watson and Timothy R. Cook

J. Phys. Chem. C, 2025, 129, 17132
DOI: 10.1021/acs.jpcc.5c03906

Reduction of Dinitrogen via 2,3′-Bipyridine-Mediated Tetraboration

Longfei Li, Zeyu Wu, Huajie Zhu, Gregory H. Robinson, Yaoming Xie and Henry F. Schaefer

J. Am. Chem. Soc., 2020, 142, 6244
DOI: 10.1021/jacs.0c00409

Advancements in Non‐Noble Metal Based Plasmonic Materials for Sustainable Nitrogen Photofixation

Dev Kumar Thapa and Soumava Biswas

Advanced Sustainable Systems, 2025, 9
DOI: 10.1002/adsu.202400954

Ambient Electrochemical N2 Reduction to NH3 on Nitrogen and Phosphorus Co‐doped Porous Carbon with Trace Iron in Alkaline Electrolytes

Pengfei Song, Hao Wang, Xuemei Cao, Na Liu, Qian Wang and Rongmin Wang

ChemElectroChem, 2020, 7, 212
DOI: 10.1002/celc.201901786

Recent Advances in Tuning of Carbon-Based Nanostructure Surfaces Toward Electrochemical Nitrogen Reduction Reaction: Inquiry to Insights

Y. Anjali, Rijo Rajeev, B. Manoj, Tom Cherian and Anitha Varghese

Top Curr Chem (Z), 2025, 383
DOI: 10.1007/s41061-025-00521-z

Membrane electrode assembly: Another technical roadmap for lithium-mediated nitrogen reduction?

Ying Hou and Dehui Deng

Joule, 2023, 7, 1682
DOI: 10.1016/j.joule.2023.07.019

Computational Evaluation of Electrocatalytic Nitrogen Reduction on TM Single-, Double-, and Triple-Atom Catalysts (TM = Mn, Fe, Co, Ni) Based on Graphdiyne Monolayers

Dongwei Ma, Zaiping Zeng, Liangliang Liu, Xiaowei Huang and Yu Jia

J. Phys. Chem. C, 2019, 123, 19066
DOI: 10.1021/acs.jpcc.9b05250

Preparation and NRR application of transition metal nanosheets on carbon nanofiber membranes

Shengmei Huang, Meng Zhang and Yi-Tao Liu

J. Phys.: Conf. Ser., 2021, 1948, 012222
DOI: 10.1088/1742-6596/1948/1/012222

Pathways of the Electrochemical Nitrogen Reduction Reaction: From Ammonia Synthesis to Metal-N2 Batteries

Sebastian Cyril Jesudass, Subramani Surendran, Joon Young Kim, Tae-Yong An, Gnanaprakasam Janani, Tae-Hoon Kim, Jung Kyu Kim and Uk Sim

Electrochem. Energy Rev., 2023, 6
DOI: 10.1007/s41918-023-00186-6

A discrete regenerative fuel cell mediated by ammonia for renewable energy conversion and storage

Zhefei Pan, Yun Liu, Abdullah Tahir, Oladapo Christopher Esan, Jie Zhu, Rong Chen and Liang An

Applied Energy, 2022, 322, 119463
DOI: 10.1016/j.apenergy.2022.119463

Recent advances of MXene as promising catalysts for electrochemical nitrogen reduction reaction

Jie Sun, Wenhan Kong, Zhaoyong Jin, Yaqian Han, Liangyu Ma, Xiaoteng Ding, Yusheng Niu and Yuanhong Xu

Chinese Chemical Letters, 2020, 31, 953
DOI: 10.1016/j.cclet.2020.01.035

Optimizing Nitrogen Reduction Reaction on Nitrides: A Computational Study on Crystallographic Orientation

Matthías Gudmundsson, Viktor Ellingsson, Egill Skúlason and Younes Abghoui

Top Catal, 2022, 65, 252
DOI: 10.1007/s11244-021-01485-2

Scalable ammonia synthesis on the modified crystal structure of Cu3PS4 electrocatalyst

Mokyeon Cho, HyungKuk Ju, Sooan Bae, Sungyool Bong and Jaeyoung Lee

Electrochimica Acta, 2024, 507, 145166
DOI: 10.1016/j.electacta.2024.145166

Fe2Mo3O8/XC-72 electrocatalyst for enhanced electrocatalytic nitrogen reduction reaction under ambient conditions

Guohua Liu, Lijuan Niu, Zhixue Ma, Li An, Dan Qu, Dandan Wang, Xiayan Wang and Zaicheng Sun

Nano Res., 2022, 15, 5940
DOI: 10.1007/s12274-022-4262-1

Ag Cluster‐Modified K0.5Na0.5NbO3 Piezocatalyst for Enhanced Electrochemical Dinitrogen Reduction Reaction

Benedict Witulski, Naina Goyal, David Patrun, Fabio Pires, Ziyaad Aytuna, Hamed Alaei, Olav Schiemann and Sanjay Mathur

Adv Eng Mater, 2025, 27
DOI: 10.1002/adem.202500764

Potential-dependent insights into the origin of high ammonia yield rate on copper surface via nitrate reduction: A computational and experimental study

Yangge Guo, Nannan Sun, Liuxuan Luo, Xiaojing Cheng, Xueying Chen, Xiaohui Yan, Shuiyun Shen and Junliang Zhang

Journal of Energy Chemistry, 2024, 96, 272
DOI: 10.1016/j.jechem.2024.04.039

Carbon nanomaterials: Synthesis, properties and applications in electrochemical sensors and energy conversion systems

Govindhan Maduraiveeran and Wei Jin

Materials Science and Engineering: B, 2021, 272, 115341
DOI: 10.1016/j.mseb.2021.115341

Recent advances in metal–organic frameworks and their derivatives for electrocatalytic nitrogen reduction to ammonia

Hongming He, Hao-Ming Wen, Hong-Kai Li and Han-Wen Zhang

Coordination Chemistry Reviews, 2022, 471, 214761
DOI: 10.1016/j.ccr.2022.214761

Refining the Spectroscopic Detection Technique: A Pivot in the Electrochemical Ammonia Synthesis

Ashmita Biswas, Bikram Ghosh and Ramendra Sundar Dey

Langmuir, 2023, 39, 3810
DOI: 10.1021/acs.langmuir.3c00201

Oxygen and Nitrogen Vacancies in a BiOBr/g-C3N4 Heterojunction for Sustainable Solar Ammonia Fertilizer Synthesis

Lei Zhang, Min Jiang, Hao Tian, Sixiao Liu, Xiaoyu Zhou, Hang Liu, Shaojie Gan, Shuya Che, Zhang Chen, Yuan Li, Tianyi Wang, Guoxiu Wang and Chengyin Wang

ACS Sustainable Chem. Eng., 2024, 12, 2028
DOI: 10.1021/acssuschemeng.3c07070

A recent review on photochemical and electrochemical nitrogen reduction to ammonia: Strategies to improve NRR selectivity and faradaic efficiency

Mohammed Ismael and Michael Wark

Applied Materials Today, 2024, 39, 102253
DOI: 10.1016/j.apmt.2024.102253

Hierarchical NbS2/MoS2-Carbon Nanofiber Electrode for Highly Efficient and Stable Hydrogen Evolution Reaction at All Ranges of pH

Paulraj Gnanasekar, Kugalur Shanmugam Ranjith, Palanisamy Manivel, Young-Kyu Han and Jeganathan Kulandaivel

ACS Appl. Energy Mater., 2020, 3, 6717
DOI: 10.1021/acsaem.0c00856

S-Doped Sb2O3 Nanorods for Electrocatalytic Nitrogen Reduction

Shihai Cao, Zhen Guan, Yanchao Feng, Huiya Wang, Rui Liu and Keqiang Ding

ACS Appl. Nano Mater., 2022, 5, 3591
DOI: 10.1021/acsanm.1c04177

Efficient Electrocatalytic N2fixation Over Bc3n2monolayer: A Computational Screening of Single-Atom Catalysts

Chaozheng He, Kun Xie, Long Lin, Jinrong Huo, Chenxu Zhao and Lixin Li

SSRN Journal, 2022
DOI: 10.2139/ssrn.4066356

Plasmonic chemistry for sustainable ammonia production

Arsha Choudhary, Anubhab Halder, Pooja Aggarwal and Vishal Govind Rao

Commun Mater, 2024, 5
DOI: 10.1038/s43246-024-00510-7

Electrified Conversion of Contaminated Water to Value: Selective Conversion of Aqueous Nitrate to Ammonia in a Polymer Electrolyte Membrane Cell

Sorin Bunea, Kevin Clemens and Atsushi Urakawa

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202102180

Computational Design of Two-Dimensional Boron-Containing Compounds as Efficient Metal-free Electrocatalysts toward Nitrogen Reduction Independent of Heteroatom Doping

Wei Nong, Haikuan Liang, Shihan Qin, Yan Li and Chengxin Wang

ACS Appl. Mater. Interfaces, 2020, 12, 50505
DOI: 10.1021/acsami.0c15872

Metal–Organic Frameworks for Photo/Electrocatalysis

Junkuo Gao, Qing Huang, Yuhang Wu, Ya-Qian Lan and Banglin Chen

Adv Energy and Sustain Res, 2021, 2
DOI: 10.1002/aesr.202100033

Recent advances in electrocatalytic conversion of nitrates into high-value products

Yuhao Qian, Jiabao Lv, Xuting Liu, Zhifu Qi and Angjian Wu

Journal of Energy Chemistry, 2024, 99, 50
DOI: 10.1016/j.jechem.2024.07.033

High temperature induced S vacancies in natural molybdenite for robust electrocatalytic nitrogen reduction

Mingzhu You, Shasha Yi, Xinghui Hou, Zhaowu Wang, Haipeng Ji, Liying Zhang, Yu Wang, Zongtao Zhang and Deliang Chen

Journal of Colloid and Interface Science, 2021, 599, 849
DOI: 10.1016/j.jcis.2021.03.160

Recent progress of iron-based electrocatalysts for nitrogen reduction reaction

Tianyi Wang, Zhongyuan Guo, Xiaoli Zhang, Qinye Li, Aimin Yu, Chengzhang Wu and Chenghua Sun

Journal of Materials Science & Technology, 2023, 140, 121
DOI: 10.1016/j.jmst.2022.07.063

Shedding Light on the Role of Chemical Bond in Catalysis of Nitrogen Fixation

Ming Cheng, Chong Xiao and Yi Xie

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202007891

Metal–organic framework derived nanomaterials for electrocatalysis: recent developments for CO2 and N2 reduction

Chanderpratap Singh, Subhabrata Mukhopadhyay and Idan Hod

Nano Convergence, 2021, 8
DOI: 10.1186/s40580-020-00251-6

Recent progress in electrochemical synthesis of carbon-free hydrogen carrier ammonia and ammonia fuel cells: A review

Feng Du, Wei Sun, Hui Luo and Chang Ming Li

Materials Reports: Energy, 2022, 2, 100163
DOI: 10.1016/j.matre.2022.100163

Anionic Biopolymer Assisted Preparation of MoO2@C Heterostructure Nanoparticles with Oxygen Vacancies for Ambient Electrocatalytic Ammonia Synthesis

Yueyao Du, Zhifeng He, Fangwei Ma, Yuchen Jiang, Jiafeng Wan, Guang Wu and Yifu Liu

Inorg. Chem., 2021, 60, 4116
DOI: 10.1021/acs.inorgchem.1c00218

Computational Insight into Defective Boron Nitride Supported Double-Atom Catalysts for Electrochemical Nitrogen Reduction

Rong Cao, Jie-Zhen Xia and Qi Wu

Catalysts, 2022, 12, 1404
DOI: 10.3390/catal12111404

Regenerative Electrocatalytic Redox Cycle of Copper Sulfide for Sustainable NH3 Production under Ambient Conditions

Hee Soo Kim, Jihyun Choi, Jimin Kong, Hansung Kim, Sung Jong Yoo and Hyun S. Park

ACS Catal., 2021, 11, 435
DOI: 10.1021/acscatal.0c03985

Modulating electronic structure via heterojunction engineering for enhanced electrocatalytic nitrogen fixation on FeS2/Bi2S3

Xin Wang, Xinhao Li, Abing Guo, Weiping Luo and Weijun Yang

Journal of Alloys and Compounds, 2025, 1014, 178680
DOI: 10.1016/j.jallcom.2025.178680

Atomic interface regulation of rare-marth metal single atom catalysts for energy conversion

Ziheng Zhan, Zhiyi Sun, Zihao Wei, Yaqiong Li, Wenxing Chen, Shenghua Li and Siping Pang

Nano Res., 2024, 17, 3493
DOI: 10.1007/s12274-023-6287-5

Electrocatalytic ammonia synthesis catalyzed by mesoporous nickel oxide nanosheets loaded with Pt nanoparticles

Wei Xiong, Min Zhou, Hao Li, Zhao Ding, Da Zhang and Yaokang Lv

Chinese Journal of Catalysis, 2022, 43, 1371
DOI: 10.1016/S1872-2067(21)63877-9

Interfacial Engineering of SeO Ligands on Tellurium Featuring Synergistic Functionalities of Bond Activation and Chemical States Buffering toward Electrocatalytic Conversion of Nitrogen to Ammonia

Gong Zhang, Hang Xu, Yang Li, Chao Xiang, Qinghua Ji, Huijuan Liu, Jiuhui Qu and Jinghong Li

Advanced Science, 2019, 6
DOI: 10.1002/advs.201901627

Surface Engineered Single‐atom Systems for Energy Conversion

Yutang Yu, Zijian Zhu and Hongwei Huang

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202311148

Nanostructured Metal Borides for Energy‐Related Electrocatalysis: Recent Progress, Challenges, and Perspectives

Zonghua Pu, Tingting Liu, Gaixia Zhang, Xianhu Liu, Marc. A. Gauthier, Zhangxing Chen and Shuhui Sun

Small Methods, 2021, 5
DOI: 10.1002/smtd.202100699

Recent progress in advanced catalysts for electrochemical nitrogen reduction reaction to ammonia

Yan Hong, Qi Wang, Ziwang Kan, Yushuo Zhang, Jing Guo, Siqi Li, Song Liu and Bin Li

Chinese Journal of Catalysis, 2023, 52, 50
DOI: 10.1016/S1872-2067(23)64504-8

Nanohybrid photocatalysts with ZnIn2S4 nanosheets encapsulated UiO-66 octahedral nanoparticles for visible-light-driven hydrogen generation

Xinxin Peng, Lin Ye, Yichun Ding, Luocai Yi, Chi Zhang and Zhenhai Wen

Applied Catalysis B: Environmental, 2020, 260, 118152
DOI: 10.1016/j.apcatb.2019.118152

Theoretical Study on the Efficient Electrocatalytic N2 Reduction Reaction of Bimetallic Single Atom Embedded in Phthalocyanine

Lingxiao Jiao and Ling Guo

Catal Lett, 2023, 153, 1916
DOI: 10.1007/s10562-022-04106-z

A novel solar system for photothermal-assisted electrocatalytic nitrate reduction reaction to ammonia

Haiyang Xu, Le Zhang, ShengJie Wei, Xuan Tong, Yue Yang and Xu Ji

Renewable Energy, 2024, 221, 119707
DOI: 10.1016/j.renene.2023.119707

Perovskite Type ABO3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects

Muhammad Humayun, Zhishan Li, Muhammad Israr, Abbas Khan, Wei Luo, Chundong Wang and Zongping Shao

Chem. Rev., 2025, 125, 3165
DOI: 10.1021/acs.chemrev.4c00553

Hydrogen spillover in alkaline solutions for effective nitrogen fixation

Chang Ning Sun, Yan Bin Qu, Zhi Li Wang and Qing Jiang

Chemical Engineering Journal, 2023, 471, 144589
DOI: 10.1016/j.cej.2023.144589

PdAgCu Alloy Nanoparticles Integrated on Three-Dimensional Nanoporous CuO for Efficient Electrocatalytic Nitrogen Reduction under Ambient Conditions

Liting Yang, Firdoz Shaik, Fangjie Pang and Weiqing Zhang

Langmuir, 2020, 36, 5112
DOI: 10.1021/acs.langmuir.0c00228

A No-Sweat Strategy for Graphene-Macrocycle Co-assembled Electrocatalyst toward Oxygen Reduction and Ambient Ammonia Synthesis

Ashmita Biswas, Subhajit Sarkar, Manisha Das, Navpreet Kamboj and Ramendra Sundar Dey

Inorg. Chem., 2020, 59, 16385
DOI: 10.1021/acs.inorgchem.0c02176

Strategies for enhancing the catalytic activity and electronic conductivity of MOFs-based electrocatalysts

Peiyun Zhou, Junjun Lv, Xiubing Huang, Yunfeng Lu and Ge Wang

Coordination Chemistry Reviews, 2023, 478, 214969
DOI: 10.1016/j.ccr.2022.214969

g-C3N4 encapsulated ZrO2 nanofibrous membrane decorated with CdS quantum dots: A hierarchically structured, self-supported electrocatalyst toward synergistic NH3 synthesis

Jun Song, Jin Dai, Peng Zhang, Yitao Liu, Jianyong Yu and Bin Ding

Nano Res., 2021, 14, 1479
DOI: 10.1007/s12274-020-3206-x

Porous and Partially Dehydrogenated Fe2+‐Containing Iron Oxyhydroxide Nanosheets for Efficient Electrochemical Nitrogen Reduction Reaction (ENRR)

Lulu Jia, Hairong Xue, Fang Xian, Yoshiyuki Sugahara, Nobuyuki Sakai, Jingbo Nan, Yusuke Yamauchi, Takayoshi Sasaki and Renzhi Ma

Small, 2023, 19
DOI: 10.1002/smll.202303221

Design of Single‐Atom Catalysts for E lectrocatalytic Nitrogen Fixation

Yuanyuan Yu, Xiaoxiao Wei, Wangqian Chen, Guangfu Qian, Changzhou Chen, Shuangfei Wang and Douyong Min

ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202301105

Direct Synthesis of Ammonia from N2 and H2O on Different Iron Species Supported on Carbon Nanotubes using a Gas‐Phase Electrocatalytic Flow Reactor

Shiming Chen, Siglinda Perathoner, Claudio Ampelli, Hua Wei, Salvatore Abate, Bingsen Zhang and Gabriele Centi

ChemElectroChem, 2020, 7, 3028
DOI: 10.1002/celc.202000514

Gold-Modified Mo2C Nanoparticles Supported on Nitrogen-Doped Carbon Nanotubes for Electrochemical Nitrogen Fixation

Jiali Lv, Taiping Hu, Wei Zhang, Wenyi Li, Zhenfei Tian, Yixing Ye, Jun Liu, Kai Dai, Pengfei Li, Haimin Zhang and Changhao Liang

ACS Appl. Nano Mater., 2022, 5, 7382
DOI: 10.1021/acsanm.2c00379

Exposure of Definite Palladium Facets Boosts Electrocatalytic Nitrogen Fixation at Low Overpotential

Huan Zhao, Dan Zhang, Hongdong Li, Wenjing Qi, Xueke Wu, Yi Han, Wenwen Cai, Zuochao Wang, Jianping Lai and Lei Wang

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202002131

Nanocarbon for Energy Material Applications: N2 Reduction Reaction

Gabriele Centi and Siglinda Perathoner

Small, 2021, 17
DOI: 10.1002/smll.202007055

Plasmonics for Chemical Transformation: From Fundamentals to the Cutting‐Edge Applications

Dev Kumar Thapa and Soumava Biswas

ChemPhysChem, 2025, 26
DOI: 10.1002/cphc.202401102

Recent advances in transition metal electrocatalysts for effective nitrogen reduction reaction under ambient conditions

Li An, Zhaoyan Zhang, Guohua Liu, Wenning Liu, Yajie Fu, Dan Qu, Yichang Liu, Pu Hu and Zaicheng Sun

EcoEnergy, 2024, 2, 229
DOI: 10.1002/ece2.39

Recent Progress in Electrochemical Nitrogen Reduction on Transition Metal Nitrides

Xiaoju Yang, Bingjun Xu, Jingguang G. Chen and Xuan Yang

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202201715

Role of Lewis acidity and optimum contribution of cobalt and iron on the adsorption and electrochemical reduction of N2 to NH3

Vineet Mishra, Shanmugam Ramasamy, Deep Lata Singh, Merlin P and Ranga Rao Gangavarapu

Catalysis Today, 2025, 445, 115054
DOI: 10.1016/j.cattod.2024.115054

Understanding the Interplay Between Pore Structure and Ionic Liquid Interaction on the Gas Uptake of Microporous Carbons

Merve Ayyildiz, Kai Hetze, Konstantin Schutjajew, Purushottam Poudel, Renzo M. Paulus, Felix H. Schacher, Jan Dellith, Ulrich S. Schubert and Martin Oschatz

Small, 2025, 21
DOI: 10.1002/smll.202501928

Electrochemical synthesis of ammonia: Progress and challenges

Tingting Wu, Wenjun Fan, Yang Zhang and Fuxiang Zhang

Materials Today Physics, 2021, 16, 100310
DOI: 10.1016/j.mtphys.2020.100310

Tailored Metal‐Porphyrin Based Molecular Electrocatalysts for Enhanced Artificial Nitrogen Fixation to Green Ammonia

Giorgia Salerno, Ottavia Bettucci, Norberto Manfredi, Luca Stendardo, Eleonora Veronese, Pierangelo Metrangolo and Alessandro Abbotto

Global Challenges, 2024, 8
DOI: 10.1002/gch2.202300345

Controllable synthesis of intercalated γ-Bi2MoO6/graphene nanosheet composites for high performance NO2 gas sensor at room temperature

Lang He, He Lv, Laifeng Ma, Wenna Li, Jiaqi Si, Muhammad Ikram, Mohib Ullah, Hongyuan Wu, Ruihong Wang and Keying Shi

Carbon, 2020, 157, 22
DOI: 10.1016/j.carbon.2019.10.011

Synergistic Electrocatalytic Nitrogen Reduction Enabled by Confinement of Nanosized Au Particles onto a Two-Dimensional Ti3C2 Substrate

Dan Liu, Gong Zhang, Qinghua Ji, Youyu Zhang and Jinghong Li

ACS Appl. Mater. Interfaces, 2019, 11, 25758
DOI: 10.1021/acsami.9b02511

Sulfur vacancies in ultrathin cobalt sulfide nanoflowers enable boosted electrocatalytic activity of nitrogen reduction reaction

Chen Li, Ruizhi Xu, Shuangxiu Ma, Yuhua Xie, Konggang Qu, Haifeng Bao, Weiwei Cai and Zehui Yang

Chemical Engineering Journal, 2021, 415, 129018
DOI: 10.1016/j.cej.2021.129018

Enhanced electrocatalytic nitrogen reduction reaction performance by interfacial engineering of MOF-based sulfides FeNi2S4/NiS hetero-interface

Peng-Yu Liu, Ke Shi, Wei-Zhe Chen, Rui Gao, Zhi-Liang Liu, Haigang Hao and Yan-Qin Wang

Applied Catalysis B: Environmental, 2021, 287, 119956
DOI: 10.1016/j.apcatb.2021.119956

Advancing electrocatalyst discovery through the lens of data science: State of the art and perspectives

Xue Jia, Tianyi Wang, Di Zhang, Xuan Wang, Heng Liu, Liang Zhang and Hao Li

Journal of Catalysis, 2025, 447, 116162
DOI: 10.1016/j.jcat.2025.116162

Charge transfer and vacancy engineering of Fe2O3 nanoparticle catalysts for highly selective N2 reduction towards NH3 synthesis

Fuhao Jin, Hanqing Yin, Ru Feng, Wei Niu, Wanting Zhang, Jingquan Liu, Aijun Du, Wenrong Yang and Zhen Liu

Journal of Colloid and Interface Science, 2023, 647, 354
DOI: 10.1016/j.jcis.2023.05.108

Tackling the Activity and Selectivity Challenges of Electrocatalysts toward the Nitrogen Reduction Reaction via Atomically Dispersed Biatom Catalysts

Xiangyu Guo, Jinxing Gu, Shiru Lin, Shengli Zhang, Zhongfang Chen and Shiping Huang

J. Am. Chem. Soc., 2020, 142, 5709
DOI: 10.1021/jacs.9b13349

Highly exfoliated NiPS3 nanosheets as efficient electrocatalyst for high yield ammonia production

Balaraman Vedhanarayanan, Cheng-chau Chiu, Jakub Regner, Zdenek Sofer, K.C. Seetha Lakshmi, Jeng-Yu Lin and Tsung-Wu Lin

Chemical Engineering Journal, 2022, 430, 132649
DOI: 10.1016/j.cej.2021.132649

Advancements in electrocatalytic nitrogen reduction to ammonia

Jie Hou, Bin Liu, Wenjing Zheng, Yaling Wang, Guangqun Cao and Shengliang Hu

Chinese Chemical Letters, 2026, 112689
DOI: 10.1016/j.cclet.2026.112689

One-step synthesis of N, P co-doped porous carbon electrocatalyst for highly efficient nitrogen fixation

Sijia Zhao, Jin Wang, Peng Wang, Shuang Wang and Jinping Li

Nano Res., 2022, 15, 1779
DOI: 10.1007/s12274-021-3722-3

Recent progress in Pd based electrocatalysts for electrochemical nitrogen reduction to ammonia

Shehman Assad, Tayyeba Tariq, Muhammad Zaeem Idrees, Abdul Mannan Butt, Khush Bakhat and Umair Shamraiz

Journal of Electroanalytical Chemistry, 2023, 931, 117174
DOI: 10.1016/j.jelechem.2023.117174

Prediction of single-boron anchored on MXene catalysts for high-efficient electrocatalytic nitrogen reduction reaction

Ning Zhang, Mei-yan Wang and Jing-Yao Liu

Molecular Catalysis, 2022, 531, 112658
DOI: 10.1016/j.mcat.2022.112658

High throughput computational screening of tantalum based small metal clusters for nitrogen fixation

Venkata Surya Kumar Choutipalli, Sai Saravanan Ambi Venkataramanan and Venkatesan Subramanian

Inorganica Chimica Acta, 2022, 530, 120700
DOI: 10.1016/j.ica.2021.120700

Molybdenum-based materials for electrocatalytic nitrogen reduction reaction

Xu Guo, Xin Wan and Jianglan Shui

Cell Reports Physical Science, 2021, 2, 100447
DOI: 10.1016/j.xcrp.2021.100447

Interface hydrophobic tunnel engineering: A general strategy to boost electrochemical conversion of N2 to NH3

Cheng Du, Chenglong Qiu, Zhongying Fang, Ping Li, Yijing Gao, Jianguo Wang and Wei Chen

Nano Energy, 2022, 92, 106784
DOI: 10.1016/j.nanoen.2021.106784

In-situ generation of ZnS nanoparticles in quasi-MOFs for efficient eNRR

Zijing Liu, Yanwei Xing, Peng Wang, Shuang Wang and Jinping Li

Molecular Catalysis, 2023, 547, 113419
DOI: 10.1016/j.mcat.2023.113419

Recent Advances in Single‐Atom Catalyst for Solar Energy Conversion: A Comprehensive Review and Future Outlook

Saad Mehmood, Saddam Sk, B. Moses Abraham, Mohsen Ahmadipour, Ujjwal Pal and Joydeep Dutta

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202418602

Photoinduced Charge Separation via the Double-Electron Transfer Mechanism in Nitrogen Vacancies g-C3N5/BiOBr for the Photoelectrochemical Nitrogen Reduction

Mingxia Li, Qiujun Lu, Meiling Liu, Peng Yin, Cuiyan Wu, Haitao Li, Youyu Zhang and Shouzhuo Yao

ACS Appl. Mater. Interfaces, 2020, 12, 38266
DOI: 10.1021/acsami.0c11894

Promotion of electrocatalytic nitrogen reduction reaction on N-doped porous carbon with secondary heteroatoms

Jin-Tao Ren, Chang-Ying Wan, Tian-Yao Pei, Xian-Wei Lv and Zhong-Yong Yuan

Applied Catalysis B: Environmental, 2020, 266, 118633
DOI: 10.1016/j.apcatb.2020.118633

Advances in rare earth catalysts for small molecule electrosynthesis

Junfeng Du, Jing Yu, Chaohui Guan, Tao Chen, Fei Yao, Shuai Zhang and Haibin Chu

Journal of Rare Earths, 2026, 44, 491
DOI: 10.1016/j.jre.2025.02.009

Electroreduction of Nitrogen on Pd, Rh, and PdRh Catalysts: An Online Mass Spectrometry Study

Rodrigo Gomes de Araujo, Caio Eduardo Canin de França and Joelma Perez

Reactions, 2025, 6, 44
DOI: 10.3390/reactions6030044

Two-dimensional transition metal dichalcogenides for electrocatalytic nitrogen fixation to ammonia: Advances, challenges and perspectives. A mini review

Liangyu Ma, Yijun Li, Yuanhong Xu, Jie Sun, Jie Liu, Tianming Wu, Xiaoteng Ding and Yusheng Niu

Electrochemistry Communications, 2021, 125, 107002
DOI: 10.1016/j.elecom.2021.107002

Theoretical Insights on Au‐based Bimetallic Alloy Electrocatalysts for Nitrogen Reduction Reaction with High Selectivity and Activity

Jun‐Lin Shi, Shi‐Qin Xiang, Dai‐Jian Su, Xiaohong Liu, Wei Zhang and Liu‐Bin Zhao

ChemSusChem, 2021, 14, 4525
DOI: 10.1002/cssc.202101462

Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen

Sangmin Kim, Florian Loose and Paul J. Chirik

Chem. Rev., 2020, 120, 5637
DOI: 10.1021/acs.chemrev.9b00705

Electrochemistry in Carbon‐based Quantum Dots

Xiaoteng Ding, Yusheng Niu, Gong Zhang, Yuanhong Xu and Jinghong Li

Chemistry An Asian Journal, 2020, 15, 1214
DOI: 10.1002/asia.202000097

Recent progress in noble metal electrocatalysts for nitrogen-to-ammonia conversion

Xufeng Rao, Minmin Liu, Meifang Chien, Chihiro Inoue, Jiujun Zhang and Yuyu Liu

Renewable and Sustainable Energy Reviews, 2022, 168, 112845
DOI: 10.1016/j.rser.2022.112845

Computational Screening Single-Atom Catalysts Supported on g-CN for N2 Reduction: High Activity and Selectivity

Huan Niu, Xiting Wang, Chen Shao, Zhaofu Zhang and Yuzheng Guo

ACS Sustainable Chem. Eng., 2020, 8, 13749
DOI: 10.1021/acssuschemeng.0c04401

Redox Mediators in Homogeneous Co-electrocatalysis

Amelia G. Reid and Charles W. Machan

J. Am. Chem. Soc., 2023, 145, 2013
DOI: 10.1021/jacs.2c10033

A comprehensive review on electrochemical green ammonia synthesis: From conventional to distinctive strategies for efficient nitrogen fixation

C.R. Santhosh and Ravi Sankannavar

Applied Energy, 2023, 352, 121960
DOI: 10.1016/j.apenergy.2023.121960

CuCo2S4 integrated multiwalled carbon nanotube as high-performance electrocatalyst for electroreduction of nitrogen to ammonia

Hongwei Li, Ting-Ting Li, Jinjie Qian, Yan Mei and Yue-Qing Zheng

International Journal of Hydrogen Energy, 2020, 45, 14640
DOI: 10.1016/j.ijhydene.2020.03.198

Dual Activation of N2 and CO2 toward N–O Coupling by Single Copper Ions

Qiuhao Yi, Chaonan Cui, Demiao Ma and Zhixun Luo

Inorg. Chem., 2025, 64, 4082
DOI: 10.1021/acs.inorgchem.4c05483

Fundamentals, rational catalyst design, and remaining challenges in electrochemical NO reduction reaction

Angga Hermawan, Vani Novita Alviani, Wibisono and Zhi Wei Seh

iScience, 2023, 26, 107410
DOI: 10.1016/j.isci.2023.107410

Control of Photocarrier Separation and Recombination at Bismuth Oxyhalide Interface for Nitrogen Fixation

Yanyan Zhao, Si Zhou, Jijun Zhao, Yi Du and Shi Xue Dou

J. Phys. Chem. Lett., 2020, 11, 9304
DOI: 10.1021/acs.jpclett.0c02480

Atomically dispersed metal sites in COF-based nanomaterials for electrochemical energy conversion

Yaqi Cao, Wenchao Peng, Yang Li, Fengbao Zhang, Yuanzhi Zhu and Xiaobin Fan

Green Energy & Environment, 2023, 8, 360
DOI: 10.1016/j.gee.2021.11.005

Oxygen Vacancies of Cr-Doped CeO2 Nanorods That Efficiently Enhance the Performance of Electrocatalytic N2 Fixation to NH3 under Ambient Conditions

Hongtao Xie, Huanbo Wang, Qin Geng, Zhe Xing, Wei Wang, Jiayin Chen, Lei Ji, Le Chang, Zhiming Wang and Jian Mao

Inorg. Chem., 2019, 58, 5423
DOI: 10.1021/acs.inorgchem.9b00622

P‐Block Metal‐Based Electrocatalysts for Nitrogen Reduction to Ammonia: A Minireview

Shaoquan Li, Yingnan Wang, Yue Du, Xiao‐Dong Zhu, Jian Gao, Yong‐Chao Zhang and Gang Wu

Small, 2023, 19
DOI: 10.1002/smll.202206776

Porous framework materials for energy & environment relevant applications: A systematic review

Yutao Liu, Liyu Chen, Lifeng Yang, Tianhao Lan, Hui Wang, Chenghong Hu, Xue Han, Qixing Liu, Jianfa Chen, Zeming Feng, Xili Cui, Qianrong Fang, Hailong Wang, Libo Li, Yingwei Li, Huabin Xing, Sihai Yang, Dan Zhao and Jinping Li

Green Energy & Environment, 2024, 9, 217
DOI: 10.1016/j.gee.2022.12.010

Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation

Yi‐Tao Liu, Di Li, Jianyong Yu and Bin Ding

Angewandte Chemie, 2019, 131, 16591
DOI: 10.1002/ange.201908415

Defect Engineering on CeO2‐Based Catalysts for Heterogeneous Catalytic Applications

Chunming Yang, Yuxuan Lu, Le Zhang, Zhijie Kong, Tianyi Yang, Li Tao, Yuqin Zou and Shuangyin Wang

Small Structures, 2021, 2
DOI: 10.1002/sstr.202100058

Billiard Catalysis at Ti3C2 MXene/MAX Heterostructure for Efficient Nitrogen Fixation

Kun Ba, Dongdong Pu, Xiaoyong Yang, Tong Ye, Jinhang Chen, Xirui Wang, Taishi Xiao, Tao Duan, Yangye Sun, Binghui Ge, Ping Zhang, Ziqi Liang and Zhengzong Sun

Applied Catalysis B: Environmental, 2022, 317, 121755
DOI: 10.1016/j.apcatb.2022.121755

Electro-synthesis of Ammonia from Dilute Nitric Oxide on a Gas Diffusion Electrode

Seonjeong Cheon, Won June Kim, Dong Yeon Kim, Youngkook Kwon and Jong-In Han

ACS Energy Lett., 2022, 7, 958
DOI: 10.1021/acsenergylett.1c02552

Electrocatalytic ammonia synthesis on Fe@MXene catalyst as cathode of intermediate-temperature proton-conducting solid oxide cell

Fukai Wang, Yanan Wang, Linzhe Li, Zichen Li, Weimin Zhang, Zhiwei Xue, Dong Liu, Xiuxia Meng, Claudia Li, Jaka Sunarso, Shaomin Liu and Naitao Yang

International Journal of Hydrogen Energy, 2023, 48, 17677
DOI: 10.1016/j.ijhydene.2023.01.256

Solvent‐Mediated Synthesis of Functional Powder Materials from Deep Eutectic Solvents for Energy Storage and Conversion: A Review

Rongrong Deng, Mingyuan Gao, Bo Zhang and Qibo Zhang

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202303707

Incorporating Pd into Cu‐Coordinated Metal‐Organic Frameworks to Promote N2 Electrochemical Reduction into Ammonia

Hao Huang, Qiaoxi Liu, Qingpeng Cheng, Maolin Zhang and Jialei Liu

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202201114

Advances and challenges in designing MXene quantum dots for sensors

Yonghua Cheng, Bowen Jiang, Somboon Chaemchuen, Francis Verpoort and Zongkui Kou

Carbon Neutralization, 2023, 2, 213
DOI: 10.1002/cnl2.47

Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

Flávio Figueira and Filipe A. Almeida Paz

C, 2021, 7, 47
DOI: 10.3390/c7020047

Recent Advances in Application of Graphitic Carbon Nitride‐Based Catalysts for Photocatalytic Nitrogen Fixation

Lei Zhang, Shaoqi Hou, Tianyi Wang, Sixiao Liu, Xiaochun Gao, Chengyin Wang and Guoxiu Wang

Small, 2022, 18
DOI: 10.1002/smll.202202252

Nanocrystalline CeMo2O8 Catalyst for Electroreduction of N2 to NH3

Meera Sebastian, Subrata Das and Nishanth Karimbintherikkal Gopalan

ACS Appl. Nano Mater., 2024, 7, 4199
DOI: 10.1021/acsanm.3c05719

In Situ Formation of FeNi Nanoparticles on Polypyrrole Hydrogel for Efficient Electrocatalytic Nitrate Reduction to Ammonia

Lixia Li, Paihao Yan, Qinkai Guo, Dongxu Zhang, Chunliang Mao, Quan Yuan, Hongtao Sun, Mingze Liu, Yanhong Liu and Baodong Mao

Molecules, 2025, 30, 1271
DOI: 10.3390/molecules30061271

Recent advances in high performance Fe-based catalysts for electrocatalytic nitrogen reduction to ammonia: A review

Abdulmalik Aminu, Janah Shaya, Maguy Abi Jaoude, Bilal Masood Pirzada, Ibrahim Yildiz and Ahsanulhaq Qurashi

Nano Research Energy, 2026, 5, e9120183
DOI: 10.26599/NRE.2025.9120183

Sustained Solar-Powered Electrocatalytic H2 Production by Seawater Splitting Using Two-Dimensional Vanadium Disulfide

Paulraj Gnanasekar, Mathan Kumar Eswaran, Gayathri Palanichamy, Tien Khee Ng, Udo Schwingenschlögl, Boon S. Ooi and Jeganathan Kulandaivel

ACS Sustainable Chem. Eng., 2021, 9, 8572
DOI: 10.1021/acssuschemeng.1c01909

Design of high-entropy alloy catalysts for nitrogen-containing molecule electroreduction

Minghao Li, Rujia Zou, Pengpeng Qiu and Wei Luo

Sci. China Mater., 2026
DOI: 10.1007/s40843-025-3902-0

Research Progress and Perspectives on Active Sites of Photo- and Electrocatalytic Nitrogen Reduction

Ya-Ge Liu, Meng Tian, Jiawei Hou and Hai-Ying Jiang

Energy Fuels, 2022, 36, 11323
DOI: 10.1021/acs.energyfuels.2c01390

Rational design of FeS2 microspheres as high-performance catalyst for electrooxidation of hydrazine

Jie Sun, Chuangwei Liu, Wenhan Kong, Jie Liu, Liangyu Ma, Song Li and Yuanhong Xu

Journal of Materials Science & Technology, 2022, 110, 161
DOI: 10.1016/j.jmst.2021.08.063

Recent Progress of Vacancy Engineering for Electrochemical Energy Conversion Related Applications

Zexing Wu, Ying Zhao, Wei Jin, Baohua Jia, Jie Wang and Tianyi Ma

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202009070

The VN3 embedded graphane with the improved selectivity for nitrogen fixation

B.B. Xiao, L. Yang, L.B. Yu, E.H. Song and Q. Jiang

Applied Surface Science, 2020, 513, 145855
DOI: 10.1016/j.apsusc.2020.145855

Computational prediction and experimental evaluation of nitrate reduction to ammonia on rhodium

Yangge Guo, Xiyang Cai, Shuiyun Shen, Guofeng Wang and Junliang Zhang

Journal of Catalysis, 2021, 402, 1
DOI: 10.1016/j.jcat.2021.08.016

Boosting Faradaic Efficiency in Electrochemical Nitrogen Reduction with a Trimetallic CuSnAu@NF Electrocatalyst for Sustainable Ammonia Synthesis

Hamed Mohtasham, Seyed Jalal Sajjadi, Keivan Akhtari, Delnia Bahari and Abdollah Salimi

ACS Appl. Mater. Interfaces, 2025, 17, 67882
DOI: 10.1021/acsami.5c17558

Theoretical Screening of Single-Atom-Embedded MoSSe Nanosheets for Electrocatalytic N2 Fixation

Lei Li, Baihai Li, Qiuyan Guo and Bo Li

J. Phys. Chem. C, 2019, 123, 14501
DOI: 10.1021/acs.jpcc.9b02657

Fabrication of an Au25‐Cys‐Mo Electrocatalyst for Efficient Nitrogen Reduction to Ammonia under Ambient Conditions

Yuan Tan, Lei Yan, Chuanqi Huang, Wenna Zhang, Haifeng Qi, Leilei Kang, Xiaoli Pan, Yijun Zhong, Yong Hu and Yunjie Ding

Small, 2021, 17
DOI: 10.1002/smll.202100372

Cerium Zirconium Solid Solution with High Faradaic Efficiency for Electrochemical Nitrogen Reduction Reaction under Ambient Condition

Xiang Wu, Xiaobo He, Zhichun Li and Fengxiang Yin

ChemElectroChem, 2021, 8, 3875
DOI: 10.1002/celc.202101060

Single, double, and triple transition metal atoms embedded in defective V3C2O2 for nitrogen reduction reaction: A DFT study

Jin Wan, Yanwei Wang, Wu Tian, Huijuan Zhang and Yu Wang

Applied Surface Science, 2021, 569, 151020
DOI: 10.1016/j.apsusc.2021.151020

Strategies to achieve effective nitrogen activation

Bin Chang, Huabin Zhang, Shuhui Sun and Gaixia Zhang

Carbon Energy, 2024, 6
DOI: 10.1002/cey2.491

Sulfur‐Bridged Iron and Molybdenum Catalysts for Electrocatalytic Ammonia Synthesis

Xiaojiao Yuan and J. R. Galán‐Mascarós

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202402361

Sulfur defect-rich WS2−x nanosheet electrocatalysts for N2 reduction

Liangyu Ma, Wenhan Kong, Mengli Liu, Zhaoyong Jin, Yaqian Han, Jie Sun, Jie Liu, Yuanhong Xu and Jinghong Li

Sci. China Mater., 2021, 64, 1910
DOI: 10.1007/s40843-020-1572-3

N2 reduction using single transition-metal atom supported on defective WS2 monolayer as promising catalysts: A DFT study

Xinguo Ma, Jisong Hu, Mingkun Zheng, Di Li, Hui Lv, Hua He and Chuyun Huang

Applied Surface Science, 2019, 489, 684
DOI: 10.1016/j.apsusc.2019.05.022

Electrochemical synthesis of ammonia in molten salts

Jiarong Yang, Wei Weng and Wei Xiao

Journal of Energy Chemistry, 2020, 43, 195
DOI: 10.1016/j.jechem.2019.09.006

Metal Alloys‐Structured Electrocatalysts: Metal–Metal Interactions, Coordination Microenvironments, and Structural Property–Reactivity Relationships

Chengdong Yang, Yun Gao, Tian Ma, Mingru Bai, Chao He, Xiancheng Ren, Xianglin Luo, Changzhu Wu, Shuang Li and Chong Cheng

Advanced Materials, 2023, 35
DOI: 10.1002/adma.202301836

Effects of AuCuB Catalysts with Porous Nanostructures on Electrosynthesis of Ammonia

Ziqiang Wang, Jinhua Niu, You Xu, Liang Wang, Hongjing Wang and Huazhang Liu

ACS Sustainable Chem. Eng., 2020, 8, 12588
DOI: 10.1021/acssuschemeng.0c03970

Activating Nitrogen for Electrochemical Ammonia Synthesis via an Electrified Transition-Metal Dichalcogenide Catalyst

Taylor J. Aubry, Jacob M. Clary, Elisa M. Miller, Derek Vigil-Fowler and Jao van de Lagemaat

J. Phys. Chem. C, 2024, 128, 7063
DOI: 10.1021/acs.jpcc.3c08230

Achievements, Challenges, and Perspectives on Nitrogen Electrochemistry for Carbon‐Neutral Energy Technologies

Xiaoxuan Yang, Shreya Mukherjee, Thomas O'Carroll, Yang Hou, Meenesh R. Singh, Joseph A. Gauthier and Gang Wu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202215938

MXene-Derived Quantum Dots for Energy Conversion and Storage Applications

Bishnupad Mohanty, Lopamudra Giri and Bikash Kumar Jena

Energy Fuels, 2021, 35, 14304
DOI: 10.1021/acs.energyfuels.1c01923

Ammonia Synthesis at Ambient Conditions via Electrochemical Atomic Hydrogen Permeation

Davide Ripepi, Riccardo Zaffaroni, Herman Schreuders, Bart Boshuizen and Fokko M. Mulder

ACS Energy Lett., 2021, 6, 3817
DOI: 10.1021/acsenergylett.1c01568

Pulsed Electrocatalysis Enabling High Overall Nitrogen Fixation Performance for Atomically Dispersed Fe on TiO2

Mingxia Guo, Long Fang, Linlin Zhang, Mingzhu Li, Meiyu Cong, Xiping Guan, Chuanwei Shi, ChunLei Gu, Xia Liu, Yong Wang and Xin Ding

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202217635

Mechanistic Insights into Electrocatalytic Nitrogen Reduction Reaction on the Pd‐W Heteronuclear Diatom Supported on C2N Monolayer: Role of H Pre‐Adsorption

Zeyun Zhang and Xuefei Xu

Energy & Environ Materials, 2023, 6
DOI: 10.1002/eem2.12348

Ag (111) surface for ambient electrolysis of nitrogen to ammonia

Jin-Rong Huo, Jia Wang, Hou-Yong Yang and Chao-Zheng He

J Mol Model, 2021, 27
DOI: 10.1007/s00894-020-04628-6

Structural engineering and operando characterization of advanced catalysts for electrochemical nitrogen reduction reaction

Muhammad Yasir, Zhiliang Zhao, Yongming Hu, Xinyi Zhang and Haunting Wang

Nano Energy, 2025, 135, 110693
DOI: 10.1016/j.nanoen.2025.110693

ZnO monolayer supported single atom catalysts for efficient nitrogen electroreduction to ammonia

Saifei Yuan, Hao Ren, Guodong Meng, Wen Zhao, Houyu Zhu and Wenyue Guo

Applied Surface Science, 2021, 555, 149682
DOI: 10.1016/j.apsusc.2021.149682

Metallization of hydrogen by intercalating ammonium ions in metal fcc lattices at lower pressure

Zhongyu Wan and Ruiqin Zhang

Applied Physics Letters, 2022, 121
DOI: 10.1063/5.0127365

Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation

Yi‐Tao Liu, Di Li, Jianyong Yu and Bin Ding

Angew Chem Int Ed, 2019, 58, 16439
DOI: 10.1002/anie.201908415

Vacancy and N dopants facilitated Ti3+ sites activity in 3D Ti3-xC2Ty MXene for electrochemical nitrogen fixation

Yacheng Shi and Yang Liu

Applied Catalysis B: Environmental, 2021, 297, 120482
DOI: 10.1016/j.apcatb.2021.120482

Boosting electrocatalytic nitrogen reduction to ammonia in alkaline media

Guangzhe Li, He Lin, Zhefei Pan, Yun Liu and Liang An

Int J Energy Res, 2021, 45, 19634
DOI: 10.1002/er.6996

Valence engineering at the interface of MoS2/Mo2C heterostructure for bionic nitrogen reduction

Tong Ye, Kun Ba, Xiaoyong Yang, Taishi Xiao, Yangye Sun, Hanqi Liu, Can Tang, Binghui Ge, Ping Zhang, Tao Duan and Zhengzong Sun

Chemical Engineering Journal, 2023, 452, 139515
DOI: 10.1016/j.cej.2022.139515

Metal-Encapsulated Boron Nitride Nanocages for Solar-Driven Nitrogen Fixation

Xiaowei Yang, Si Zhou, Shiliang Huang and Jijun Zhao

J. Phys. Chem. C, 2020, 124, 23798
DOI: 10.1021/acs.jpcc.0c07968

Effects of hydrophobic layer on selective electrochemical nitrogen fixation of self-supporting nanoporous Mo4P3 catalyst under ambient conditions

Lin Xiao, Shengli Zhu, Yanqin Liang, Zhaoyang Li, Shuilin Wu, Shuiyuan Luo, Chuntao Chang and Zhenduo Cui

Applied Catalysis B: Environmental, 2021, 286, 119895
DOI: 10.1016/j.apcatb.2021.119895

Sustainable Ammonia Production Processes

Seyedehhoma Ghavam, Maria Vahdati, I. A. Grant Wilson and Peter Styring

Front. Energy Res., 2021, 9
DOI: 10.3389/fenrg.2021.580808

Hierarchical hybrid of tungsten nitride nanosheets integrated with nitrogen-doped carbon for efficiently electrocatalytical nitrogen fixation

Jing Wang, Hui Liufu, Jing Chen, Milin Chen, Ziyi Huang, Lin Ma, Xian Wang, Yanjie Xi, Yihan Gao, Ying Wang and Liying Zhang

Inorganic Chemistry Communications, 2025, 176, 114325
DOI: 10.1016/j.inoche.2025.114325

Adsorption and catalytic activation of N2 molecule on iron dimer supported by different two-dimensional carbon-based substrates: A computational study

Fan He, Zhongxu Wang, Shuquan Wei and Jingxiang Zhao

Applied Surface Science, 2020, 506, 144943
DOI: 10.1016/j.apsusc.2019.144943

Electrochemical Nitrogen Reduction to Ammonia at Ambient Condition on the (111) Facets of Transition Metal Carbonitrides

Atef Iqbal, Egill Skulason and Younes Abghoui

ChemPhysChem, 2024, 25
DOI: 10.1002/cphc.202300991

Sustainable electrosynthesis of sulfur-containing chemical feedstocks

Khoa H. Ly and Inez M. Weidinger

Nat. Synth, 2023, 2, 705
DOI: 10.1038/s44160-023-00336-0

Tuning Active Sites and Energy Band Structure of Nanowire-Based W18O49 via Co-Doping for Efficient Photocatalytic Nitrogen Fixation

Chuhan Huang, Guanying Liu, Zhehui Zhang, Qian Cheng, Jiajun Wang, Lianming Zhao, Fazle Subhan, Xiaohan Liu, Youhe Wang and Zifeng Yan

ACS Appl. Nano Mater., 2025, 8, 21404
DOI: 10.1021/acsanm.5c03793

Efficient electrocatalytic N2 fixation over BC3N2 monolayer: A computational screening of single-atom catalysts

Chaozheng He, Ye Shen, Long Lin, Kun Xie, Songshan Gao and Yaowei Liu

Molecular Catalysis, 2025, 577, 114931
DOI: 10.1016/j.mcat.2025.114931

Fe foam supported FeVO 4 nanoparticles for electrochemical nitrogen fixation at ambient conditions

Abdulmalik Aminu, Bilal Masood Pirzada, Shamraiz Hussain Talib, Janah Shaya, Ibrahim Yildiz, Sharmarke Mohamed and Ahsanulhaq Qurashi

Nano Research Energy, 2025, 4, e9120161
DOI: 10.26599/NRE.2025.9120161

Construction of a 2D/2D g-C3N5/NiCr-LDH Heterostructure to Boost the Green Ammonia Production Rate under Visible Light Illumination

Bharati Debnath, Sk Mujaffar Hossain, Anustup Sadhu, Saideep Singh, Vivek Polshettiwar and Satishchandra Ogale

ACS Appl. Mater. Interfaces, 2022, 14, 37076
DOI: 10.1021/acsami.2c03758

Applications of high-entropy MOFs and their derivatives

Anaer Husile, Zhenlu Wang and Jingqi Guan

Coordination Chemistry Reviews, 2025, 533, 216546
DOI: 10.1016/j.ccr.2025.216546

Recent advances in vacancy engineering of metal‐organic frameworks and their derivatives for electrocatalysis

Yuhang Wu, Yuwen Li, Junkuo Gao and Qichun Zhang

SusMat, 2021, 1, 66
DOI: 10.1002/sus2.3

The surface engineering of MOF-derived titanium oxide–carbon multifunctional composite catalyst for efficient electrochemical nitrogen reduction

Yuxiang Li, Yi Liang, Heen Li, Bo Wang, Huanhuan You, Yuanzhe Wang, Yunpeng Cao, Wenjing Dai and Faming Gao

Applied Surface Science, 2021, 570, 151257
DOI: 10.1016/j.apsusc.2021.151257

Theoretical screening of single transition-metal atoms anchored Janus MoSSe monolayers as efficient electrocatalysts for nitrogen fixation

Jia-Xing Guo, Shao-Yi Wu, Chun-Yu Yao, Rong-Gang Tian and Shun-Ping Shi

Fuel, 2024, 374, 132474
DOI: 10.1016/j.fuel.2024.132474

Metal based catalysts for electrocatalytic nitrogen cycling

Lin Yang, Zhangyi Li, Zhonghui Gao, Jiamin Zhu, Yanqin Liang, Hui Jiang, Zhaoyang Li, Wence Xu, Hao Wang, Zhenduo Cui and Shengli Zhu

Journal of Alloys and Compounds, 2026, 1050, 185640
DOI: 10.1016/j.jallcom.2025.185640

Enhanced Electrochemical Reduction of N2 to Ammonia over Pyrite FeS2 with Excellent Selectivity

Hao Du, Changzhu Yang, Wenhong Pu, Lingyu Zeng and Jianyu Gong

ACS Sustainable Chem. Eng., 2020, 8, 10572
DOI: 10.1021/acssuschemeng.0c03675

Theoretical Study on P-coordinated Metal Atoms Embedded in Arsenene for the Conversion of Nitrogen to Ammonia

Ruofei Song, Jian Yang, Mingyuan Wang, Zhenzhen Shi, Xiaopeng Zhu, Xiangzhao Zhang, Minghua He, Guiwu Liu, Guanjun Qiao and Ziwei Xu

ACS Omega, 2021, 6, 8662
DOI: 10.1021/acsomega.1c00581

Iron tris(phosphine)-borane, -carbon, and -silane complexes in catalytic N2 reduction

Siqi Yu and Michael B. Hall

Journal of Organometallic Chemistry, 2026, 1052, 124101
DOI: 10.1016/j.jorganchem.2026.124101

Advance of Single‐Atom Catalysts Confined into Pristine Metal‐Organic Frameworks and their Energy‐Related Applications

Qijie Mo, Chunying Chen, Sihong Li, Jiewei Liu, Li Zhang and Cheng‐Yong Su

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301753

Electron-rich Au nanocrystals/Co3O4 interface for enhanced electrochemical nitrate reduction into ammonia

Maolin Zhang, Kepeng Song, Chen Liu, Zedong Zhang, Wen-Qing He, Hao Huang and Jialei Liu

Journal of Colloid and Interface Science, 2023, 650, 193
DOI: 10.1016/j.jcis.2023.06.073

“Giant” Nitrogen Uptake in Ionic Liquids Confined in Carbon Pores

Ipek Harmanli, Nadezda V. Tarakina, Markus Antonietti and Martin Oschatz

J. Am. Chem. Soc., 2021, 143, 9377
DOI: 10.1021/jacs.1c00783

Synergistic ultra-high activity of double B doped graphyne for electrocatalytic nitrogen reduction

Baotao Kang, Yuan Yuan, Yipin Lv, Hongqi Ai and Jin Yong Lee

Chemical Engineering Journal, 2022, 428, 131318
DOI: 10.1016/j.cej.2021.131318

Insight into the d–p Orbital Hybridization of Ru and B Dispersed g‐C3N4 Catalysts for Nitrogen Reduction Reaction

Ji Zhang, Daojun Liu, Aimin Yu, Dongsheng Li, Songlin Zhou and Chenghua Sun

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400034

Surface hydrophobic modification of MXene to promote the electrochemical conversion of N2 to NH3

Xu Wang, Rui Zhang, Chaoqun Ma, Wei Yan, Yanjiao Wei, Jian Tian, Min Ma, Qing Li and Minhua Shao

Journal of Energy Chemistry, 2023, 87, 439
DOI: 10.1016/j.jechem.2023.08.043

The modulation of catalytic active site and support to construct high-efficiency ZnS/NC-X electrocatalyst for nitrogen reduction

Peng Wang, Sijia Zhao, Zijing Liu, Caiyun Han, Shuang Wang and Jinping Li

Nano Res., 2022, 15, 7903
DOI: 10.1007/s12274-022-4442-z

Recent Advances in Metal‐Organic Framework‐Based Nanomaterials for Electrocatalytic Nitrogen Reduction

Bo Han, Jiawei Liu, Carmen Lee, Chade Lv and Qingyu Yan

Small Methods, 2023, 7
DOI: 10.1002/smtd.202300277

Photocatalysis for Sustainable Nitrogen Fixation: Fundamentals, Catalyst Design, Nanoarchitectonics, Applications, and Future Prospects

Manisha Sharma, Ashish Kumar, Devanshu Sajwan, Kamlesh Kumari, Bhagyashree Priyadarshini Mishra and Venkata Krishnan

Advanced Sustainable Systems, 2025, 9
DOI: 10.1002/adsu.202400903

Enhancing Nitrogen Reduction Reaction through Formation of 2D/2D Hybrid Heterostructures of MoS2@rGO

Joyce B. Matsoso, Nikolas Antonatos, Lukáš Dekanovský, Roussin Lontio Fomekong, Joshua D. Elliot, Diego Gianolio, Vlastimil Mazánek, Catherine Journet and Zdeněk Sofer

ACS Appl. Mater. Interfaces, 2024, 16, 24514
DOI: 10.1021/acsami.4c00719

Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)

Wanqing Song, Caixia Xiao, Jia Ding, Zechuan Huang, Xinyi Yang, Tao Zhang, David Mitlin and Wenbin Hu

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202301477

Recent Progress in Electrocatalytic Glycerol Oxidation

Linfeng Fan, Bowen Liu, Xi Liu, Nangan Senthilkumar, Genxiang Wang and Zhenhai Wen

Energy Tech, 2021, 9
DOI: 10.1002/ente.202000804

Facile Construction of CuFe‐Based Metal Phosphides for Synergistic NOx−Reduction to NH3 and Zn‐Nitrite Batteries in Electrochemical Cell

Guoqiang Wang, Chuanjun Wang, Xinxin Tian, Qiang Li, Shenjie Liu, Xiuying Zhao, Geoffrey I.N. Waterhouse, Xin Zhao, Xiaoqing Lv and Jing Xu

Small, 2024, 20
DOI: 10.1002/smll.202311439

Water flooding behavior in flow cells for ammonia production via electrocatalytic nitrogen reduction

Zhefei Pan, Farhan Khalid, Abdullah Tahir, Oladapo Christopher Esan, Jie Zhu, Rong Chen and Liang An

Fundamental Research, 2022, 2, 757
DOI: 10.1016/j.fmre.2021.09.001

In Situ Growth of Nitrogen-Doped Carbon-Coated γ-Fe2O3 Nanoparticles on Carbon Fabric for Electrochemical N2 Fixation

Yan Li, Yan Kong, Yang Hou, Bin Yang, Zhongjian Li, Lecheng Lei and Zhenhai Wen

ACS Sustainable Chem. Eng., 2019, 7, 8853
DOI: 10.1021/acssuschemeng.9b00852

Fundamentals and catalyst designs of solar photo-thermo-catalytic ammonia synthesis under mild conditions: A critical review

Rong Ma, Mengqi Lv, Donghui Li, Jing Zhang, Chonghao Ding, Xiaoying Feng, Huili Cheng, Yu Zhao, Ning Li, Chenchen Feng, Chunlei Li and Jie Sun

International Journal of Hydrogen Energy, 2026, 220, 154065
DOI: 10.1016/j.ijhydene.2026.154065

Efficient Ambient Electrocatalytic Ammonia Synthesis by Nanogold Triggered via Boron Clusters Combined with Carbon Nanotubes

Xue Zhao, Ziqiong Yang, Artem V. Kuklin, Glib V. Baryshnikov, Hans Ågren, Xiaohai Zhou and Haibo Zhang

ACS Appl. Mater. Interfaces, 2020, 12, 42821
DOI: 10.1021/acsami.0c11487

Two-dimensional transition metal borides as highly efficient N2 fixation catalysts

Siyun Qi, Yingcai Fan, Lanling Zhao, Weifeng Li and Mingwen Zhao

Applied Surface Science, 2021, 536, 147742
DOI: 10.1016/j.apsusc.2020.147742

Constructing Asymmetric Polarization Sites on MoOx Cluster for Efficient Electrochemical N2 Reduction

Yuxi Ren, Hang Xiao, Wei Liu, Ben Chong, Honghui Ou and Guidong Yang

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202509701

New insights into mechanisms on electrochemical N2 reduction reaction driven by efficient zero-valence Cu nanoparticles

Xiaoxi Guo, Wencai Yi, Fengli Qu and Limin Lu

Journal of Power Sources, 2020, 448, 227417
DOI: 10.1016/j.jpowsour.2019.227417

Engineering 3D Printed Structures Towards Electrochemically Driven Green Ammonia Synthesis: A Perspective

Akshay Kumar K. Padinjareveetil, Juan V. Perales‐Rondon and Martin Pumera

Adv Materials Technologies, 2023, 8
DOI: 10.1002/admt.202202080

Elucidating Mechanistic Origin of the Catalytic Activity of the Fe(111) Surface and Nanoclusters toward the Electrochemical Nitrogen Reduction Reaction

Arunendu Das, Akhil S. Nair and Biswarup Pathak

J. Phys. Chem. C, 2020, 124, 20193
DOI: 10.1021/acs.jpcc.0c05776

Electrocatalytic Ammonia Synthesis Using a Fe@Mxene Catalyst as Cathode of High-Temperature Proton-Conducting Solid Oxide Cell

Naitao Yang, Linzhe Li, Zhiwei Xue, Xiuxia Meng, Jinjin Zhang, Claudia Li, Fangyong Yu and Jaka Sunarso

SSRN Journal, 2022
DOI: 10.2139/ssrn.4113738

Conversion of dinitrogen to ammonia by rhenium doped graphyne

Chong Wang and Chen Guo

International Journal of Hydrogen Energy, 2021, 46, 33409
DOI: 10.1016/j.ijhydene.2021.07.184

Pulsed Electrocatalysis Enabling High Overall Nitrogen Fixation Performance for Atomically Dispersed Fe on TiO2

Mingxia Guo, Long Fang, Linlin Zhang, Mingzhu Li, Meiyu Cong, Xiping Guan, Chuanwei Shi, ChunLei Gu, Xia Liu, Yong Wang and Xin Ding

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202217635

Carbon-Based Single-Atom Nanocatalysts for Electrochemical Energy Applications

Zhengming Hao and Yan Li

ACS Appl. Nano Mater., 2024, 7, 26468
DOI: 10.1021/acsanm.4c00522

Surface hydrophobic modification enhanced catalytic performance of electrochemical nitrogen reduction reaction

Lijuan Niu, Ziwen Liu, Guohua Liu, Mengxuan Li, Xupeng Zong, Dandan Wang, Li An, Dan Qu, Xiaoming Sun, Xiayan Wang and Zaicheng Sun

Nano Res., 2022, 15, 3886
DOI: 10.1007/s12274-021-4015-6

Achievements, Challenges, and Perspectives on Nitrogen Electrochemistry for Carbon‐Neutral Energy Technologies

Xiaoxuan Yang, Shreya Mukherjee, Thomas O'Carroll, Yang Hou, Meenesh R. Singh, Joseph A. Gauthier and Gang Wu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202215938

An oxygen-vacancy-rich polyoxometalate-aided Ag-based heterojunction electrocatalyst for nitrogen fixation

Xinyu Chen, Cong-Cong Zhao, Jing Ren, Bo Li, Qianqian Liu, Wei Li, Fan Yang, Siqi Lu, YuFei Zhao, Li-Kai Yan and Hong-Ying Zang

Chinese Journal of Catalysis, 2024, 62, 209
DOI: 10.1016/S1872-2067(24)60046-X

A Review of Transition Metal Nitride-Based Catalysts for Electrochemical Nitrogen Reduction to Ammonia

So Young Park, Youn Jeong Jang and Duck Hyun Youn

Catalysts, 2023, 13, 639
DOI: 10.3390/catal13030639

A Two‐Step Electrochemical Conversion of Nitric Oxide to Ammonia on Defective Copper Foam Catalyst

Jaganathan Jayakumar and Raghuram Chetty

ChemCatChem, 2026, 18
DOI: 10.1002/cctc.202501417